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a, \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(n_{Fe}=n_{H_2}=0,15\left(mol\right)\Rightarrow m_{Fe}=0,15.56=8,4\left(g\right)\)
b, \(n_{Na_2O}=\dfrac{6,2}{62}=0,1\left(mol\right)\)
\(Na_2O+H_2O\rightarrow2NaOH\)
\(n_{NaOH}=2n_{Na_2O}=0,2\left(mol\right)\Rightarrow C_{M_{NaOH}}=\dfrac{0,2}{0,5}=0,4\left(M\right)\)
\(a,n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH:
\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
0,15 0,3 0,15 0,15
\(m_{Fe}=0,15.56=8,4\left(g\right)\)
\(a,n_{Na_2O}=\dfrac{6,2}{62}=0,1\left(mol\right)\)
PTHH :
\(Na_2O+H_2O\rightarrow2NaOH\)
0,1 0,1 0,2
\(C_{M\left(A\right)}=\dfrac{0,2}{0,5}=0,4\left(M\right)\)
\(n_{HCl}=\dfrac{44,8}{22,4}=2\)
\(\Rightarrow m_{HCl}=2.36,5=73g\)
=> \(C\%_{HCl}=\dfrac{73}{73+327}\times100\%=18,25\%\)
b.
\(n_{HCl}=\dfrac{250.18,25\%}{36,5}=1,25mol\)
\(n_{CaCO_3}=\dfrac{50}{100}=0,5mol\)
\(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)
\(n_{CaCl_2}=n_{CO_2}=0,5mol\)
\(n_{HClpu}=0,5.2=1mol\)
\(\Rightarrow n_{HCldu}=1,25-1=0,25\)
\(\Rightarrow m_{ddpu}=50+250-0,5.44=278g\)
\(C\%_{HCl}=\dfrac{0,25.36,5}{278}.100\%=3,28\%\)
\(C\%_{CaCl_2}=\dfrac{0,5.111}{278}.100\%=19,96\%\)
\(2Al + 6HCl \rightarrow 2AlCl_3 + 3H_2\)
\(n_{Al}= \dfrac{10,8}{27}=0,4 mol\)
\(n_{HCl}= 0,3 mol\)
\(2Al + 6HCl \rightarrow 2AlCl_3 + 3H_2\)
Trước PƯ: 0,4 0,3
PƯ: 0,1 0,3 0,1 0,15
Sau PƯ: 0,3 0 0,1 0,15
Đây là mình làm tắt, bạn nên làm bài hết dư này theo cách của bạn
Sau PƯ: dd X có AlCl3 (0,1 mol) và 0,15 mol H2
\(V= 0,15 . 22,4=3,36 l\)
\(m_{dd sau pư}= m_{Al pư} + m_{dd HCl} - m_{H_2}= 0,1 . 27 + 300 - 0,15. 2=302 , 4g\)
C% X=\(\dfrac{ 0,1 . 133,5}{302,4}\). 100%= 4,41%
a)
n O = 6,13.23,491%/16 = 0,09(mol)
=> n Al2O3 = 1/3 n O = 0,03(mol)
n H2 = 1,456/22,4 = 0,065(mol)
$H_2O \to OH^- + \dfrac{1}{2}H_2$
Suy ra: n OH = 2n H2 = 0,065.2 = 0,13(mol)
Al2O3 + 2OH- → 2AlO2- + H2O
0,03......0,06..........0,06.....................(mol)
DUng dịch G có :
AlO2- : 0,06
OH- : 0,13 - 0,06 = 0,07(mol)
Áp dụng CT :
n H+ = 4n AlO2- + n OH- - 3n Al(OH)3
<=> 0,16 = 0,06.4 + 0,07 - 3n Al(OH)3
<=> n Al(OH)3 = 0,05(mol)
<=> m = 0,05.78 = 3,9(gam)
Trong F :
m Na + m K + m Ba = m D - m Al2O3 = 6,13 - 0,03.102 = 3,07(gam)
n Cl = n HCl = 0,16(mol)
n Al3+ = 0,06 - 0,05 = 0,01(mol)
=> m chất tan = 3,07 + 0,16.35,5 + 0,01.27 = 9,02(gam)
a)\(n_{Fe}=\dfrac{14}{56}=0,25\left(mol\right)\)
PTHH: Fe + 2HCl → FeCl2 + H2
Mol: 0,25 0,5 0,25
b) \(C_{M_{ddHCl}}=\dfrac{0,5}{0,5}=1M\)
c) \(V_{H_2}=0,25.22,4=5,6\left(l\right)\)
PTHH: \(CaO+2HCl\rightarrow CaCl_2+H_2O\) (1)
\(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\uparrow\) (2)
a) Ta có: \(n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)=n_{CaCO_3}\)
\(\Rightarrow m_{CaCO_3}=0,2\cdot100=20\left(g\right)\) \(\Rightarrow\%m_{CaCO_3}=\dfrac{20}{25,6}\cdot100\%=78,125\%\)
\(\Rightarrow\%m_{CaO}=21,875\%\)
b) Theo 2 PTHH: \(\left\{{}\begin{matrix}n_{HCl\left(2\right)}=2n_{CaCO_3}=0,4mol\\n_{HCl\left(1\right)}=2n_{CaO}=2\cdot\dfrac{25,6-20}{56}=0,2mol\end{matrix}\right.\)
\(\Rightarrow\Sigma n_{HCl}=0,6mol\) \(\Rightarrow C\%_{HCl}=\dfrac{0,6\cdot36,5}{210\cdot1,05}\cdot100\%\approx9,93\%\)
\(FeS+2HCl\rightarrow FeCl_2+H_2S\)\(\uparrow\)
0.2 0.2
\(H_2S+4H_2O\rightarrow H_2SO_4+4H_2\)
0.2 0.2 0.8
a. \(n_{FeS}=\dfrac{17.6}{88}=0.2mol\)
\(mdd_{H_2SO_4}=m_X=m_{H_2S}+m_{H_2O}-m_{H_2}=0.2\times34+92.3-0.8\times2=97.5g\)
\(C\%_{H_2SO_4}=\dfrac{0.2\times98\times100}{97.5}=20,1\%\)
b. \(\dfrac{1}{2}dd_X\Rightarrow n_X=0.1mol\)
\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
0.2 0.1
\(mdd_{NaOH}=\dfrac{0.2\times40\times100}{20}=40g\)
a. \(n_{HCl}=\frac{44,8}{22,4}=2mol\)
\(\rightarrow m_{HCl}=2.36,5=73g\)
\(\rightarrow C\%_{HCl}=\frac{73.100}{73+327}=18,25\%\)
b. \(n_{CaCO_3}=\frac{50}{100}=0,5mol\)
\(n_{HCl}=\frac{250.18,25\%}{36,25}=1,25mol\)
PTHH: \(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)
Từ phương trình \(n_{CaCl_2}=n_{CO_2}=0,5mol\)
\(n_{HCl\text{pứ}}=0,5.2=1mol\)
\(\rightarrow n_{HCl\text{dư}}=1,25-1=0,25mol\)
\(n_{ddsaupu}=50+250-0,5.44=278g\)
\(\rightarrow C\%_{CaCl_2}=\frac{0,5.111.100}{278}=19,96\%\)
\(\rightarrow C\%_{HCl}=\frac{0,25.36,5.100}{278}=3,28\%\)
