a) PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)

                   a_____2a______a_____a      (mol)

                \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)

                    b_____3b_______b_____\(\dfrac{3}{2}\)b         (mol)

Ta lập HPT: \(\left\{{}\begin{matrix}56a+27b=36,1\\a+\dfrac{3}{2}b=\dfrac{21,28}{22,4}=0,95\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,5\\b=0,3\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=0,5\cdot56=28\left(g\right)\\m_{Al}=8,1\left(g\right)\end{matrix}\right.\)

b+c) Theo các PTHH: \(\left\{{}\begin{matrix}n_{HCl}=2a+3b=1,9\left(mol\right)\\n_{FeCl_2}=0,5\left(mol\right)\\n_{AlCl_3}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{HCl}}=\dfrac{1,9}{0,2}=9,5\left(M\right)\\C_{M_{FeCl_2}}=\dfrac{0,5}{0,2}=2,5\left(M\right)\\C_{M_{AlCl_3}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\end{matrix}\right.\)

a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

Gọi: \(\left\{{}\begin{matrix}n_{Zn}=x\left(mol\right)\\n_{Al}=y\left(mol\right)\end{matrix}\right.\) ⇒ 65x + 27y = 17,05 (1)

Ta có: \(n_{H_2}=\dfrac{9,52}{22,4}=0,425\left(mol\right)\)

Theo PT: \(n_{H_2}=n_{Zn}+\dfrac{3}{2}n_{Al}=x+\dfrac{3}{2}y=0,425\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Zn}=0,2\left(mol\right)\\n_{Al}=0,15\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{Zn}=0,2.65=13\left(g\right)\\m_{Al}=0,15.27=4,05\left(g\right)\end{matrix}\right.\)

b, Theo PT: \(\left\{{}\begin{matrix}n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\\n_{AlCl_3}=n_{Al}=0,15\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{ZnCl_2}}=\dfrac{0,2}{0,5}=0,4\left(M\right)\\C_{M_{AlCl_3}}=\dfrac{0,15}{0,5}=0,3\left(M\right)\end{matrix}\right.\)

c, Ta có: m _{dd HCl} = 1,05.500 = 525 (g)

m _{dd sau pư} = m_hh + m _{dd HCl} - m_H2 = 541,2 (g)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,2.136}{541,2}.100\%\approx5,03\%\\C\%_{AlCl_3}=\dfrac{0,15.133,5}{541,2}.100\%\approx3,7\%\end{matrix}\right.\)

\(n_{H2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Pt : \(Fe+2HCl\rightarrow FeCl_2+H_2|\)

        1          2            1           1

       0,2       0,4         0,2         0,2

      \(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O|\)

          1            6               2              3

         0,2         1,2            0,4

\(n_{Fe}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)

⇒ \(m_{Fe}=0,2.56=11,2\left(g\right)\)

\(m_{Fe2O3}=27,2-11,2=16\left(g\right)\)

⁰/₀Fe = \(\dfrac{11,2.100}{27,2}=41,18\)⁰/₀

⁰/₀Fe₂O₃ = \(\dfrac{16.100}{27,2}=58,82\)⁰/₀

b) Có : \(m_{Fe2O3}=16\left(g\right)\)

 \(n_{Fe2O3}=\dfrac{16}{160}=0,1\left(mol\right)\)

\(n_{HCl\left(tổng\right)}=0,4+1,2=1,6\left(mol\right)\)

\(V_{HCl}=\dfrac{1,6}{2}=0,8\left(l\right)\)

c) \(n_{FeCl2}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)

   \(n_{FeCl3}=\dfrac{1,2.2}{6}=0,4\left(mol\right)\)

  \(C_{M_{FeCl2}}=\dfrac{0,2}{0,8}=0,25\left(M\right)\)

  \(C_{M_{FeCl3}}=\dfrac{0,4}{0,8}=0,5\left(M\right)\)

 Chúc bạn học tốt

CuO + 2HCl -> CuCl₂ + H₂O (1)

Fe₂O₃ + 6HCl -> 2FeCl₃ + 3H₂O (2)

n_HCl=0,2.3,5=0,7(mol)

Đặt n_CuO=a

n_Fe2O3=b

Ta có hệ:

80a+160b=20

2a+6b=0,7

=>a=0,05;b=0,1

m_CuO=80.0,05=4(g)

m_Fe2O3=20-4=16(g)

Theo PTHH 1 và 2 ta có:

n_CuCl2=n_CuO=0,05(mol)

n_FeCl3=2n_Fe2O3=0,2(mol)

m_CuCl2=135.0,05=6,75(g)

m_FeCl3=162,5.0,2=32,5(g)

m_dd =20+200.1,1=240(g)

C% dd CuCl₂=6,72\240 .100%=2,8125%

C% dd FeCl₃= 32,5\240 .100%=13,54%