\(b.n_{NaOH\left(tổng\right)}=0,4.0,5+\dfrac{100.1,33.20\%}{40}=0,865\left(mol\right)\\ \left[Na^+\right]=\left[OH^-\right]=\left[NaOH\left(sau\right)\right]=\dfrac{0,865}{0,4+0,1}=1,73\left(M\right)\\ c.n_{HCl}=0,05.0,12=0,006\left(mol\right)\\ n_{HNO_3}=0,15.0,1=0,015\left(mol\right)\\ \left[H^+\right]=\dfrac{0,006+0,015}{0,05+0,15}=0,105\left(M\right)\\ \left[NO^-_3\right]=\dfrac{0,015}{0,05+0,15}=0,075\left(M\right)\\ \left[Cl^-\right]=\dfrac{0,006}{0,05+0,15}=0,03\left(M\right)\)

\(d.n_{H_2SO_4}=0,4.0,05=0,02\left(mol\right)\\ n_{HCl}=0,35.0,2=0,07\left(mol\right)\\ \left[H^+\right]=\dfrac{0,02.2+0,07}{0,05+0,35}=0,275\left(M\right)\\ \left[SO^{2-}_4\right]=\dfrac{0,02}{0,05+0,35}=0,05\left(M\right)\\ \left[Cl^-\right]=\dfrac{0,07}{0,05+0,35}=0,175\left(M\right)\\ f.n_{KOH}=\dfrac{20.1,31.32\%}{56}=\dfrac{131}{875}\left(mol\right)\\ n_{Ba\left(OH\right)_2}=0,08.1=0,08\left(mol\right)\\ \left[OH^-\right]=\dfrac{\dfrac{131}{875}+0,08.2}{0,02+0,08}=\dfrac{542}{175}\left(M\right)\\ \left[Ba^{2+}\right]=\dfrac{0,08}{0,02+0,08}=0,8\left(M\right)\)

\(\left[K^+\right]=\dfrac{\dfrac{131}{875}}{0,02+0,08}=\dfrac{262}{175}\left(M\right)\)

n\(_{Ba\left(OH\right)_2}\)=0,05.0,05=0,0025mol

n\(_{HCl}\)=0,15.0,1=0,015mol

PTPU

Ba(OH)\(_2\)+ 2HCl->BaCl\(_2\) + H\(_2\)O

0,0025..........0,005.....0,0025.........0,0025(mol)

=>n\(_{HCl_{dư}}\)=0,01mol

C\(_{M_{HCl}}\)=0,01/0,2=0,05M

=>n\(_{BaCl_2}\)=0,0025mol

C\(_{M_{BaCl_2}}\)=0,0025/0,2=0,0125M

Câu 1 : 

\(n_{HCl}=\dfrac{7,3}{36,5}=0,2\left(mol\right)\)

\(n_{CaCO3}=\dfrac{15}{100}=0,15\left(mol\right)\)

Pt : \(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O|\)

           1              2               1          1         1

         0,15          0,2                       0,1

Lập tỉ số so sánh : \(\dfrac{0,15}{1}>\dfrac{0,2}{2}\)

                 ⇒ CaCO₃ dư , Hcl phản ứng hết

                 ⇒ Tính toán dựa vào số mol của Hcl

\(n_{CO2}=\dfrac{0,2.1}{2}=0,1\left(mol\right)\)

\(V_{CO2\left(dktc\right)}=0,1.22,4=2,24\left(l\right)\)

 Chúc bạn học tốt

bn coi lại đề

A là dd H2SO4, B là dd naoh

Đáp án B

n_H+ = n_HCl = 0,006

n_OH- = n_NaOH = 0,005

Khi pha trộn: H⁺ + OH^- → H₂O

=> n_{H+ dư} = 0,001

=> [H⁺] = 0,001/0,1 = 0,01 => pH = 2

Dd Y có HCl. → Ba(OH)₂ pư hết, HCl dư.

Ta có: \(n_{Ba\left(OH\right)_2}=0,3.0,05=0,015\left(mol\right)\)

\(n_{HCl\left(dư\right)}=0,01.\left(0,3+0,5\right)=0,008\left(mol\right)\)

PT: \(Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\)

______0,015___0,03_____0,015 (mol)

⇒ n_HCl = 0,03 + 0,008 = 0,038 (mol)
\(\Rightarrow b=C_{M_{HCl}}=\dfrac{0,038}{0,5}=0,076\left(M\right)\)

- Khi cô cạn dd thì HCl bay hơi hết, chất rắn khan là BaCl₂,

m _{cr khan} = m_BaCl2 = 0,015.208 = 3,12 (g)