$n_{CuO} = 0,2(mol)$

\(CuO+H_2SO_4\text{→}CuSO_4+H_2O\)

0,2               0,2            0,2                                        (mol)

$m_{dd\ H_2SO_4} = \dfrac{0,2.98}{20\%} = 98(gam)$
$m_{dd\ A}  =16 + 98 = 114(gam)$

Gọi $n_{CuSO_4.5H_2O} = a(mol)$

Sau khi tách tinh thể : 

$n_{CuSO_4} = 0,2 - a(mol)$
$m_{dd} = 114 - 250a(gam)$

Suy ra: 

$\dfrac{(0,2 - a).160}{114 - 250a} = \dfrac{17,4}{17,4 + 100}$
$\Rightarrow a = 0,1228(mol)$
$m = 0,1228.250 = 30,7(gam)$

a

\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)

0,2 -------------------->0,2

b

\(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)

Trước khi làm lạnh:

\(\left\{{}\begin{matrix}m_{CuSO_4}=0,2.160=32\left(g\right)\\m_{H_2O}=114-32=82\left(g\right)\end{matrix}\right.\)

Sau khi làm lạnh:

\(\left\{{}\begin{matrix}m_{CuSO_4}=32-\dfrac{30,71}{160+18n}.120\left(g\right)\\m_{H_2O}=82-\dfrac{30,71}{160+18n}.18n\left(g\right)\end{matrix}\right.\)

Có:

\(\left(82-\dfrac{30,71}{160+18n}.18n\right).17,4=\left(32-\dfrac{30,71}{160+18n}.120\right).100\)

=> n = 2

Công thức tinh thể CuSO₄.nH₂O: \(CuSO_4.2H_2O\)

\(em k0 hiểu ch0 này á anh sa0 mình lại lập đc cái phân s0 dd0 v anh \)

n CuO = 64/80 = 0,8(mol)

CuO + H2SO4 → CuSO4 + H2O

0,8..........0,8............0,8.................(mol)

m dd H2SO4 = 0,8.98/20% = 392 gam

=> mdd sau pư = m CuO + mdd H2SO4 = 64 + 392 = 456 gam

Gọi n CuSO4.5H2O = a(mol)

CuSO4 + 5H2O → CuSO4.5H2O

a................5a...................a............(mol)

Sau khi tách tinh thể: 

n CuSO4 = 0,8 - a(mol)

m dd = m dd sau pư - m CuSO4.5H2O = 456 - 250a(gam)

Suy ra :

C% = S/(S + 100).100%

<=> 160(0,8 - a)/(456 -250a) = 25/(25+100)

<=>a = 0,3345

=> m CuSO4.5H2O = 0,3345.250 = 83,625 gam

a) PTHH: \(SO_3+H_2O\rightarrow H_2SO_4\)

Ta có: \(n_{SO_3}=\dfrac{24}{80}=0,3\left(mol\right)=n_{H_2SO_4}\) \(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,3\cdot98}{20\%}=147\left(g\right)\)

\(\Rightarrow V_{ddH_2SO_4}=\dfrac{147}{1,14}\approx128,95\left(ml\right)\)

b) PTHH: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)

Theo PTHH: \(n_{Fe}=n_{H_2SO_4}=n_{H_2}=0,3\left(mol\right)=n_{FeSO_4}\)

\(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=0,3\cdot56=16,8\left(g\right)\\V_{H_2}=0,3\cdot24,76=7,428\left(l\right)\\m_{FeSO_4}=0,3\cdot152=45,6\left(g\right)\\m_{H_2}=0,3\cdot2=0,6\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{dd}=m_{Fe}+m_{ddH_2SO_4}-m_{H_2}=163,2\left(g\right)\)

\(\Rightarrow C\%_{FeSO_4}=\dfrac{45,6}{163,2}\cdot100\%\approx27,94\%\)

Đáp án B

Độ tan : \(S = \dfrac{20,7}{100}.100 = 20,7(gam)\)

Công thức tính số tan : S = \(\dfrac{m_{chất\ tan}}{m_{dung\ môi}}\)

S(CuSO4,200C)= (20,7.100)/100=20,7(g)

=> Chọn B

a)

$n_{Al} = 0,3(mol)$

$2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2$

Theo PTHH : 

$n_{H_2SO_4} = \dfrac{3}{2}n_{Al} = 0,45(mol)$
$m_{dd\ H_2SO_4} = \dfrac{0,45.98}{12,25\%} = 360(gam)$

b)

$n_{H_2} = n_{H_2SO_4} = 0,45(mol)$
$V_{H_2} = 0,45.22,4 = 10,08(lít)$

c)

$n_{Al_2(SO_4)_3} = 0,15(mol)$
$m_{dd\ sau\ pư} = 8,1 + 360 - 0,45.2 = 367,2(gam)$
$C\%_{Al_2(SO_4)_3} = \dfrac{0,15.342}{367,2}.100\% = 14\%$