\(a.n_{HCl}=0,1.1=0,1\left(mol\right)\\ n_{H_2SO_4}=0,5.0,1=0,05\left(mol\right)\\ \left[HCl\right]=\dfrac{0,1}{0,1+0,1}=0,5\left(M\right)\\ \left[H_2SO_4\right]=\dfrac{0,05}{0,1+0,1}=0,25\left(M\right)\\ \left[H^+\right]=0,5+0,25.2=1\left(M\right)\\ \left[SO^{2-}_4\right]=\left[H_2SO_4\right]=0,25\left(M\right)\\ \left[Cl^-\right]=\left[HCl\right]=0,5\left(M\right)\)

\(b.BaCl_2+H_2SO_4\rightarrow BaSO_4\downarrow+2HCl\\ n_{BaSO_4}=n_{H_2SO_4}=0,05\left(mol\right)\\ m_{\downarrow}=m_{BaSO_4}=233.0,05=11,65\left(g\right)\)

\(n_{H^+}=n_{HNO_3}=V\)mol

\(n_{OH^-}=n_{NaOH}=0,5.0,2=0,1\) mol

\(H^++OH^-\rightarrow H_2O\)

0,1<--0,1

\(\Rightarrow n_{H^+}=V=0,1\)lít = 100 ml

\(NaOH+HNO_3\rightarrow NaNO_3+H_2O\)

0,1 -----> 0,1 ---------->0,1

\(NaNO_3\rightarrow Na^++NO_3^-\)

\(\Rightarrow\left[Na^+\right]=\left[NO_3^-\right]=\dfrac{0,1}{0,1+0,2}=0,33M\)

Tính C_M của chất nào vậy

\(n_{BaSO_4}=\frac{m}{M}=\frac{32,62}{233}=0,14mol\)

PTHH:

\(Ba\left(OH\right)_2+H_2SO_4\rightarrow BaSO_4+2H_2O\)

0,14 0,14 0,14 0,28 (mol)

Gọi \(V_{ddH_2SO_4}\)cần thêm là x

\(n_{H_2SO_4}=\frac{m}{M}=\frac{98}{98}=1mol\)

\(C^{\left(A\right)}_{M_{H_2SO_4}}=\frac{1}{1}=1M\)

\(n^{\left(A\right)}_{H2SO4}=C_M.V=1.x=xmol\)

\(n_{H2SO4}=C_M.V=2.0,4=0,8mol\)

\(C_{MX}=\frac{n}{V}=\frac{0,8+x}{0,4+x}\left(M\right)\)

\(n_X=C_{MX}.V\)

\(\Leftrightarrow0,14=\frac{0,8+x}{0,4+x}.0,1\)

\(\Leftrightarrow\frac{0,14}{0,1}=\frac{0,8+x}{0,4+x}\)

⇔0,08+0,1x=0,56+0,14x

⇔x=0,6(l)

Vậy cần thêm 0,6 l dung dịch

ban oi lam cau b di

1.

Theo đề bài ta có : \(\left\{{}\begin{matrix}nAl=\dfrac{0,54}{27}=0,02\left(mol\right)\\nH2SO4=\dfrac{120.4,9}{100.98}=0,06\left(mol\right)\end{matrix}\right.\)

PTHH :

\(2Al+3H2SO4->Al2\left(So4\right)3+3H2\uparrow\)

0,02mol...0,03mol.......0,01mol.............0,03mol

Theo PTHH ta có : nAl = \(\dfrac{0,02}{2}mol< nH2SO4=\dfrac{0,06}{2}mol=>nH2SO4\left(dư\right)\) ( tính theo nal)

=> VH2(đktc) = 0,03.22,4 = 6,72(l)

=> \(\left\{{}\begin{matrix}C\%ddH2SO4\left(dư\right)=\dfrac{\left(0,06-0,03\right).98}{0,54+120-0,03.2}.100\%\approx2,44\%\\C\%ddAl2\left(SO4\right)3=\dfrac{0,01.302}{0,54+120-0,03.2}.100\%\approx2,5\%\end{matrix}\right.\)

Theo đề bài ta có : nNa2O = \(\dfrac{15,5}{62}=0,25\left(mol\right)\)

a) PTHH :

\(Na2O+H2O->2NaOH\)

0,25mol....0,25mol.....0,5mol

b) Nồng độ mol dd A là :

CMddNaOH = 0,5/0,5 = 1(M)

c) PTHH :

\(2NaOH+H2SO4->Na2SO4+H2O\)

0,5mol.........0,25mol

=> mddH2SO4 = \(\dfrac{0,25.98}{20}.100=122,5\left(g\right)=>VddH2SO4=\dfrac{122,5}{1,14}\approx107,5\left(ml\right)\)

1.
nCO2=0,075mol

do dư KOH nên tạo ra muối trung hòa

nNa2CO3=nCO2=0,075mol

-->Cm=0,3M

2.
nCO2=0,5mol, nNaOH=4,0625mol

-->tạo muối Na2CO3 với số mol =nCO2=0,5mol

-->CmNa2CO3=1M

\(a)n_{Ba\left(OH\right)_2}=0,05\cdot0,2\cdot2=0,02mol\\ pH=1\Rightarrow\left[OH^-\right]=0,1M\Rightarrow n_{HCl}=0,1\cdot0,3=0,03mol\\ n_{Ba\left(OH\right)_2}+n_{HCl}=0,02+0,03=0,05mol\\ \Rightarrow C_M=\dfrac{0,05}{0,5}=0,1M\Rightarrow pH=1\)