cho 1 khối lượng kim loại Iron(Fe) dư vào 150ml dd HCl. Sau phản ứng thu được 3,7185l khí (đkc)
a)Tính khối lượng kim loại đã tham gia phản ứng
b)Tính nồng độ mol của dd acid đã dùng
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Ta có: \(n_{H_2}=\dfrac{10,08}{22,4}=0,45\left(mol\right)\)
PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
_____0,3_____0,9______0,2____0,45 (mol)
a, mAl = 0,3.27 = 8,1 (g)
b, \(C_{M_{HCl}}=\dfrac{0,9}{0,15}=6\left(M\right)\)
Theo đề bài ta có : nH2 = 10,08/22,4 = 0,45 (mol)
a) PTHH :
Fe+2HCl−>FeCl2+H2↑
0,45mol->,9mol->0,45mol
b) khối lượng mạt sắt tham gia phản ứng là :
mFe = 0,45.56 = 25,2(g)
c)
nồng độ mol của dd HCl đã dùng là :
CMddHCl = 0,9/0,15 = 6(M)
\(n_{H_2}=\dfrac{V_{H_2}}{22,4}=\dfrac{3,36}{22,4}=0,15mol\)
a. PTHH: Fe + H2SO4 \(\rightarrow\) FeSO4 + H2
TL: 1 1 1 1
mol: 0,15 \(\leftarrow\) 0,15 \(\leftarrow\) 0,15 \(\leftarrow\) 0,15
\(b.m_{Fe}=n.M=0,15.56=8,4g\)
Đổi 150ml = 0,15 l
\(c.C_{MddH_2SO_4}=\dfrac{n}{V}=\dfrac{0,15}{0,15}=1M\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
x 3x x 1,5x
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
y 2y y y
\(\left\{{}\begin{matrix}27x+56y=22\\1,5x+y=\dfrac{17,92}{22,4}\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,4\\y=0,2\end{matrix}\right.\)
\(m_{Al}=0,4\cdot27=10,8g\)
\(m_{Fe}=22-10,8=11,2g\)
\(m_{HCl}=36,5\cdot\left(3x+2y\right)=36,5\cdot\left(3\cdot0,4+2\cdot0,2\right)=58,4g\)
\(m_{ddHCl}=\dfrac{m_{HCl}}{C\%}\cdot100\%=\dfrac{58,4}{25\%}\cdot100\%=233,6g\)
\(Đặt:n_{Al}=u\left(mol\right);n_{Fe}=v\left(mol\right)\left(u,v>0\right)\\ n_{H_2}=\dfrac{17,92}{22,4}=0,8\left(mol\right)\\ PTHH:Fe+2HCl\rightarrow FeCl_2+H_2\\ 2Al+6HCl\rightarrow2AlCl_3+3H_2\\ \Rightarrow\left\{{}\begin{matrix}27a+56u=22\\1,5a+u=0,8\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,4\\u=0,2\end{matrix}\right.\\ \Rightarrow m_{Al}=0,4.27=10,8\left(g\right);m_{Fe}=56.0,2=11,2\left(g\right)\\ n_{HCl}=2.0,8=1,6\left(mol\right)\\ m_{HCl}=1,6.36,5=58,4\left(g\right)\\ m_{ddHCl}=\dfrac{58,4.100}{25}=233,6\left(g\right)\)
a)
$Fe + H_2SO_4 \to FeSO_4 + H_2$
Theo PTHH :
$n_{Fe} = n_{H_2} = \dfrac{3,36}{22,4} = 0,15(mol)$
$m_{Fe} = 0,15.56 = 8,4(gam)$
b)
$n_{H_2SO_4} = n_{H_2} = 0,15(mol)$
$C_{M_{H_2SO_4}} = \dfrac{0,15}{0,05} = 3M$
c)
$n_{FeSO_4} = n_{H_2} = 0,15(mol)$
$C_{M_{FeSO_4}} = \dfrac{0,15}{0,05} = 3M$
a, \(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)
Theo PT: \(n_{Fe}=n_{FeCl_2}=n_{H_2}=0,3\left(mol\right)\Rightarrow m_{Fe}=0,3.56=16,8\left(g\right)\)
b, \(n_{HCl}=2n_{H_2}=0,6\left(mol\right)\Rightarrow C_{M_{HCl}}=\dfrac{0,6}{0,15}=4\left(M\right)\)
c, \(FeCl_2+2NaOH\rightarrow2NaCl+Fe\left(OH\right)_2\)
Theo PT: \(n_{NaOH}=2n_{FeCl_2}=0,6\left(mol\right)\)
\(\Rightarrow V_{NaOH}=\dfrac{0,6}{1}=0,6\left(l\right)=600\left(ml\right)\)
\(a.Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{Fe,pư}=n_{FeCl_2}=n_{H_2}=\dfrac{6,72}{22,4}=0,3mol\\ m_{Fe,pư}=0,3.56=16,8g\\ b.n_{HCl}=0,3.2=0,6mol\\ C_{M_{HCl}}=\dfrac{0,6}{0,15}=4M\\ c.2NaOH+FeCl_2\rightarrow Fe\left(OH\right)_2+2NaCl\\ n_{NaOH}=0,3.2=0,6mol\\ V_{ddNaOH}=\dfrac{0,6}{1}=0,6l=600ml\)
\(Đặt:n_{Mg}=a\left(mol\right);n_{Al}=b\left(mol\right)\left(a,b>0\right)\\ PTHH:Mg+2HCl\rightarrow MgCl_2+H_2\\ 2Al+6HCl\rightarrow2AlCl_3+3H_2\\ \Rightarrow\left\{{}\begin{matrix}24a+27b=5,1\\22,4a+22,4.1,5.b=5,6\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\\ a,\Rightarrow\%m_{Mg}=\dfrac{0,1.24}{5,1}.100\approx47,059\%\\ \Rightarrow\%m_{Al}\approx100\%-47,059\%\approx52,941\%\\ b,n_{HCl}=2.n_{H_2}=2.\left(0,1+0,1.1,5\right)=0,5\left(mol\right)\\ \Rightarrow V_{ddHCl}=\dfrac{0,5}{2}=0,25\left(l\right)\)
a)\(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
x 2x x x
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
y 3y y 1,5y
Ta có hệ:
\(\left\{{}\begin{matrix}24x+27y=5,1\\x+1,5y=\dfrac{5,6}{22,4}=0,25\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,1\end{matrix}\right.\)
\(\%m_{Mg}=\dfrac{0,1\cdot24}{5,1}\cdot100\%=47,06\%\)
\(\%m_{Al}=100\%-47,06\%=52,94\%\)
b)\(\Sigma n_{HCl}=2x+3y=2\cdot0,1+3\cdot0,1=0,5mol\)
\(V=\dfrac{n}{C_M}=\dfrac{0,5}{2}=0,25l=250ml\)
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
Ta có: \(n_{H_2}=\dfrac{3,7185}{22,4}\approx0,166\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{Fe}=0,166\left(mol\right)\\n_{HCl}=0,332\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=0,166\cdot56=9,296\left(g\right)\\C_{M_{HCl}}=\dfrac{0,332}{0,15}\approx2,21\left(M\right)\end{matrix}\right.\)
a, \(n_{H_2}=\dfrac{3,7185}{24,79}=0,15\left(mol\right)\)
PTHH: Fe + 2HCl → FeCl2 + H2
Mol: 0,15 0,3 0,15
\(m_{Fe}=0,15.56=8,4\left(g\right)\)
b, \(C_{M_{ddHCl}}=\dfrac{0,3}{0,15}=2M\)