CHo 200 g Na2CO3 nđ 5.3% t/d với 100 dd HCL nđ 73% thu V lít khí CO2 ở đktc và dd X
a) tính V lit CO2
b) Tính C% mỗi chất có trong dd X
c) Trung hòa dd X phải dùng lượng vùa đủ 100 ml dd NaOH nồng độ CM tính CM
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\(n_{Zn}=\dfrac{4,55}{65}=0,07(mol)\\ Zn+2HCl\to ZnCl_2+H_2\\ a,n_{HCl}=0,14(mol)\\ \Rightarrow C_{M_{HCl}}=\dfrac{0,14}{0,2}=0,7M\\ b,n_{H_2}=0,07(mol)\\ \Rightarrow V_{H_2}=0,07.22,4=1,568(l)\\ c,n_{ZnCl_2}=0,07(mol)\\ \Rightarrow m_{ZnCl_2}=0,07.136=9,52(g)\\ c,ZnCl_2+2AgNO_3\to 2AgCl\downarrow+Zn(NO_3)_2\)
\(m_{dd_{ZnCl_2}}=200.0,8+4,55-0,07.2=164,41(g)\\ n_{AgCl}=0,14(mol);n_{Zn(NO_3)_2}=0,07(mol)\\ \Rightarrow C\%_{Zn(NO_3)_2}=\dfrac{0,07.189}{164,41+200-0,14.143,5}.100\%=3,84%\)
\(n_{CO_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)
PT: \(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3+H_2O\)
Theo PT: \(n_{Ca\left(OH\right)_2}=n_{CaCO_3}=n_{CO_2}=0,25\left(mol\right)\)
a, \(C_{M_{Ca\left(OH\right)_2}}=\dfrac{0,25}{0,1}=2,5\left(M\right)\)
b, \(m_{CaCO_3}=0,25.100=25\left(g\right)\)
c, \(Ca\left(OH\right)_2+2HCl\rightarrow CaCl_2+2H_2O\)
Theo PT: \(n_{HCl}=2n_{Ca\left(OH\right)_2}=0,5\left(mol\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{0,5.36,5}{20\%}=91,25\left(g\right)\)
Ủa fen ơi, nFeCl2 sinh ra là 0,1 mol rồi còn tác dụng đủ sao được với Ba(OH)2 0,05 mol fen=)
\(n_{Fe}=a;n_{Cu}=b\\a. Fe+2HCl->FeCl_2+H_2\\ 2HCl+Ba\left(OH\right)_2->BaCl_2+2H_2O\\ b.m_{Fe}=56\cdot\dfrac{2,24}{22,4}=5,6g\\ \%m_{Fe}=\dfrac{5,6}{8,8}.100\%=63,64g\\ \%m_{Cu}=36,36\%\\ c.\sum n_{HCl}=0,2+2.0,1.0,5=0,3mol\\ x=\dfrac{0,3}{0,3}=1\left(M\right)\)
\(n_{K2O}=\dfrac{9,4}{94}=0,1\left(mol\right)\)
Pt : \(K_2O+H_2O\rightarrow2KOH|\)
1 1 2
0,1 0,2
a) \(n_{KOH}=\dfrac{0,1.2}{1}=0,2\left(mol\right)\)
200ml = 0,2l
\(C_{M_{ddKOH}}=\dfrac{0,2}{0,2}=1\left(M\right)\)
b) Pt : \(KOH+HCl\rightarrow KCl+H_2O|\)
1 1 1 1
0,1 0,1
\(n_{HCl}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
\(m_{HCl}=0,1.36,5=3,65\left(g\right)\)
\(m_{ddHCl}=\dfrac{3,65.100}{10}=36,5\left(g\right)\)
c) \(CO_2+2KOH\rightarrow K_2CO_3+H_2O|\)
1 2 1 1
0,05 0,1
\(n_{CO2}=\dfrac{0,1.1}{2}=0,05\left(mol\right)\)
\(V_{CO2\left(dktc\right)}=0,05.22,4=1,12\left(l\right)\)
Chúc bạn học tốt
`1)`
`n_{Al}={2,7}/{27}=0,1(mol)`
`2Al+3H_2SO_4->Al_2(SO_4)_3+3H_2`
`0,1->0,15->0,05->0,15(mol)`
`V_{dd\ H_2SO_4}={0,15}/1=0,15(l)=150(ml)`
`->V=150`
`V'=V_{H_2}=0,15.22,4=3,36(l)`
`C_{M\ X}=C_{M\ Al_2(SO_4)_3}={0,05}/{0,15}=1/3M`
`2)`
`n_{Fe}={2,8}/{56}=0,05(mol)`
`Fe+2HCl->FeCl_2+H_2`
`0,05->0,1->0,05->0,05(mol)`
`V_{dd\ HCl}={0,1}/1=0,1(l)=100(ml)`
`->V=100`
`V_{H_2}=0,05.22,4=1,12(l)`
`C_{M\ FeCl_2}={0,05}/{0,1}=0,5M`
\(n_{Na_2CO_3}=\dfrac{200.0,159}{106}=0,3mol\\ n_{BaCl_2}=\dfrac{200.0,208}{208}=0,2mol\\ a.Na_2CO_3+BaCl_2->2NaCl+BaCO_3\\ n_{Na_2CO_3}:1>n_{BaCl_2}:1\\ m_B=197.0,2=39,4g\\ Na_2CO_3+2HCl->2NaCl+H_2O+CO_2\\ V=\dfrac{2.0,1}{1}=0,2\left(L\right)=200\left(mL\right)\\ b.m_A=200+200-39,4=360,6g\\ C\%_{Na_2CO_3du}=\dfrac{106.0,1}{360,6}.100\%=2,94\%\\ C\%_{NaCl}=\dfrac{58,5.0,4}{360,6}.100\%=6,49\%\)
a)
\(Na_2CO_3+BaCl_2\rightarrow BaCO_3+2NaCl\)
0,2 <---------- 0,2 ------> 0,2 -----> 0,4
\(n_{Na_2CO_3}=\dfrac{200.15,9\%}{100\%}:106=0,3\left(mol\right)\)
\(n_{BaCl_2}=\dfrac{200.20,8\%}{100\%}:208=0,2\left(mol\right)\)
Do \(\dfrac{0,3}{1}>\dfrac{0,2}{1}\) nên \(Na_2CO_3\) dư sau phản ứng.
Dung dịch A: \(n_{Na_2CO_3}=0,3-0,2=0,1\left(mol\right);n_{NaCl}:0,4\left(mol\right)\)
Kết tủa B: \(BaCO_3\)
\(m_B=m_{BaCO_3}=0,2.197=39,4\left(g\right)\)
Dung dịch A td với HCl:
\(Na_2CO_3+2HCl\rightarrow2NaCl+H_2O+CO_2\)
0,1 ---------> 0,2
\(V=V_{HCl}=\dfrac{0,2}{1}=0,2\left(l\right)\)
b)
\(m_{dd}=m_{dd.Na_2CO_3}+m_{dd.BaCl_2}-m_{BaCO_3}=200+200-39,4=360,6\left(g\right)\)
\(C\%_{Na_2CO_3}=\dfrac{0,1.106.100\%}{360,6}=2,94\%\)
\(C\%_{NaCl}=\dfrac{0,4.58,5.100\%}{360,6}=6,49\%\)
\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
0,2-->0,4----->0,2------->0,2
a
\(V_{H_2}=0,2.22,4=4,48\left(l\right)\)
b
\(CM_{MgCl_2}=\dfrac{0,2}{0,2}=1M\)
c
\(MgCl_2+2NaOH\rightarrow Mg\left(OH\right)_2+2NaCl\)
0,2------>0,4
\(V_{dd.NaOH}=\dfrac{0,4}{2}=0,2\left(l\right)\)
Bài 1:
PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
Ta có: \(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,4\left(mol\right)\\n_{H_2}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{ddHCl}=\dfrac{0,4\cdot36,5}{14,6\%}=100\left(g\right)\\V_{H_2}=0,2\cdot22,4=4,48\left(l\right)\end{matrix}\right.\)
Bài 2:
PTHH: \(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)
Ta có: \(\left\{{}\begin{matrix}n_{KOH}=\dfrac{100\cdot11,2\%}{56}=0,2\left(mol\right)\\n_{H_2SO_4}=\dfrac{150\cdot9,8\%}{98}=0,15\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,2}{2}< \dfrac{0,15}{1}\) \(\Rightarrow\) H2SO4 còn dư, KOH p/ứ hết
\(\Rightarrow\left\{{}\begin{matrix}n_{K_2SO_4}=0,1\left(mol\right)\\n_{H_2SO_4\left(dư\right)}=0,05\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{K_2SO_4}=0,1\cdot174=17,4\left(g\right)\\m_{H_2SO_4\left(dư\right)}=0,05\cdot98=4,9\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd}=m_{ddKOH}+m_{ddH_2SO_4}=250\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{K_2SO_4}=\dfrac{17,4}{250}\cdot100\%=6,96\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{4,9}{250}\cdot100\%=1,96\%\end{matrix}\right.\)
mNa2CO3 = 10.6 g
nNa2CO3 = 0.1 mol
mHCl = 100*7.3/100= 73g
nHCl = 2 mol
Na2CO3 + 2HCl --> 2NaCl + CO2 + H2O
Bđ: 0.1________2
Pư : 0.1________0.2_____0.2____0.1
Kt : 0_________1.8______0.2____0.1
VCO2 = 2.24 l
mCO2 = 4.4g
mHCl dư = 65.7 g
mNaCl = 11.7 g
mdd sau phản ứng = 200 + 100 - 4.4 = 295.6 g
C%HCl dư = 22.22%
C%NaCl = 3.95%
OH- + H+ --> H2O
1.8___1.8
CM NaOH = 1.8/0.1 = 18M