Cho 340 g dd Silver Nitrate AgNO3 10% tác dụng vừa đủ với dd HCl 7,3%.
a/ Tính khối lượng dung dịch HCl cần dùng.
b/ Tính khối lượng kết tủa thu được.
c/ Tính nồng độ % của dung dịch thu được sau phản ứng.
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\(n_{Al2O3}=\dfrac{10,2}{102}=0,1\left(mol\right)\)
Pt : \(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O|\)
1 6 2 3
0,1 0,6 0,1
a) \(n_{HCl}=\dfrac{0,1.6}{1}=0,6\left(mol\right)\)
\(m_{HCl}=0,6.36,5=21,9\left(g\right)\)
\(m_{ddHCl}=\dfrac{21,9.100}{10}=219\left(g\right)\)
b) \(n_{AlCl3}=\dfrac{0,6.2}{6}=0,2\left(mol\right)\)
⇒ \(m_{AlCl3}=0,2.133,5=26,7\left(g\right)\)
c) \(m_{ddspu}=10,2+219=229,2\left(g\right)\)
\(C_{AlCl3}=\dfrac{26,7.100}{229,2}=11,65\)0/0
Chúc bạn học tốt
nAl2O3=10.2:102=0.1(mol)
PTHH:Al2O3+6HCl->2AlCl3+3H2O
theo pthh:nHCl:nAl2O3=6->nHCl=6*0.1=0.6(mol)
mHCl=0.6*36.5=21.9(g)
mdd HCl=21.9*100:14.6=150(g)
theo pthh:nAlCl3:nAl2O3=2->nAlCl3=0.1*2=0.2(mol)
mAlCl3=0.2*133.5=26.7(g)
mdd sau phản ứng:10.2+150=160.2
Câu 1:
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, \(n_{Zn}=\dfrac{16,25}{65}=0,25\left(mol\right)\)
\(n_{H_2}=n_{Zn}=0,25\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,25.24,79=6,1975\left(l\right)\)
c, \(n_{HCl}=2n_{Zn}=0,5\left(mol\right)\)
\(\Rightarrow m_{HCl}=0,5.36,5=18,25\left(g\right)\)
\(\Rightarrow m_{ddHCl}=\dfrac{18,25}{10\%}=182,5\left(g\right)\)
d, \(n_{ZnCl_2}=n_{Zn}=0,25\left(mol\right)\)
\(\Rightarrow C\%_{ZnCl_2}=\dfrac{0,25.136}{16,25+182,5-0,25.2}.100\%\approx17,15\%\)
Câu 2:
a, \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)
c, \(n_{NaOH}=\dfrac{40}{40}=1\left(mol\right)\)
Theo PT: \(n_{H_2SO_4}=\dfrac{1}{2}n_{NaOH}=0,5\left(mol\right)\)
\(\Rightarrow V_{H_2SO_4}=\dfrac{0,5}{2}=0,25\left(l\right)\)
d, \(n_{Na_2SO_4}=\dfrac{1}{2}n_{NaOH}=0,5\left(mol\right)\)
\(\Rightarrow C_{M_{Na_2SO_4}}=\dfrac{0,5}{0,25}=2\left(M\right)\)
a) K2CO3 + 2HCl --> 2KCl + CO2 + H2O
b) \(n_{K_2CO_3}=\dfrac{13,8}{138}=0,1\left(mol\right)\)
PTHH: K2CO3 + 2HCl --> 2KCl + CO2 + H2O
______0,1----->0,2------>0,2--->0,1
=> VCO2 = 0,1.22,4 = 2,24 (l)
c) mHCl = 0,2.36,5 = 7,3 (g)
\(m_{ddHCl}=\dfrac{7,3.100}{7,3}=100\left(g\right)\)
d) mKCl = 0,2.74,5 = 14,9 (g)
mdd sau pư = 13,8 + 100 - 0,1.44 = 109,4 (g)
=> \(C\%\left(KCl\right)=\dfrac{14,9}{109,4}.100\%=13,62\%\)
a, \(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\)
\(FeCl_3+3KOH\rightarrow3KCl+Fe\left(OH\right)_{3\downarrow}\)
\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)
Theo PT: \(n_{HCl}=6n_{Fe_2O_3}=0,6\left(mol\right)\)
\(\Rightarrow m_{HCl}=0,6.36,5=21,9\left(g\right)\)
b, \(n_{Fe\left(OH\right)_3}=n_{FeCl_3}=2n_{Fe_2O_3}=0,2\left(mol\right)\)
\(\Rightarrow m_{Fe\left(OH\right)_3}=0,2.107=21,4\left(g\right)\)
\(n_{KOH}=3n_{FeCl_3}=0,6\left(mol\right)\)
\(\Rightarrow C_{M_{KOH}}=\dfrac{0,6}{0,2}=3\left(M\right)\)
\(n_{FeCl_3}=\dfrac{48,75}{162,5}=0,3(mol)\\ 3NaOH+FeCl_3\to Fe(OH)_3\downarrow+3NaCl\\ \Rightarrow n_{Fe(OH)_3}=0,3(mol);n_{NaOH}=n_{NaCl}=0,9(mol)\\ a,m_{Fe(OH)_3}=0,3.107=32,1(g)\\ b,m_{dd_{NaOH}}=\dfrac{0,9.40}{10\%}=360(g)\\ c,C\%_{NaCl}=\dfrac{0,9.58,5}{360+48,75-32,1}.100\%=13,98\%\\ \)
\(d,2Fe(OH)_3+3H_2SO_4\to Fe_2(SO_4)_3+6H_2O\\ \Rightarrow n_{H_2SO_4}=0,45(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,45.98}{20\%}=220,5(g)\\ \Rightarrow V_{dd_{H_2SO_4}}=\dfrac{220,5}{1,14}=193,42(ml)\)
nAgNO3= (100.17%)/170=0,1(mol)
nHCl= (300.3,65%)/36,5=0,3(mol)
a) PTHH: AgNO3 + HCl -> AgCl + HNO3
Ta có: 0,1/1 < 0,3/1
=> AgNO3 hết, HCl dư, tính theo nAgNO3
Ta có: nAgCl= nHNO3= nHCl(p.ứ)= nAgNO3= 0,1(mol)
=>m(kt)=mAgCl= 143,5.0,1= 14,35(g)
b) mHCl(dư)= (0,3- 0,1).36,5=7,3(g)
mHNO3= 63.0,1= 6,3(g)
mddsau= mddAgNO3 + mddHCl - mAgCl= 100+300- 14,35= 385,65(g)
=>C%ddHCl(dư)= (7,3/385,65).100= 1,893%
C%ddHNO3= (6,3/385,65).100=1,634%
a)
$AgNO_3 + HCl \to AgCl + HNO_3$
Theo PTHH :
$n_{AgCl} = n_{HCl} = n_{AgNO_3} = \dfrac{340.10\%}{170} =0,2(mol)$
$m_{dd\ HCl} = \dfrac{0,2.36,5}{7,3\%} = 100(gam)$
b)
$m_{AgCl} = 0,2.143,5 = 28,7(gam)$
c)
$m_{dd\ sau\ pư} = 340 + 100 -28,7 = 411,3(gam)$
$n_{HNO_3} = n_{AgNO_3} = 0,2(mol)$
$\Rightarrow C\%_{HNO_3} = \dfrac{0,2.63}{411,3}.100\% = 3,06\%$