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\(m_{CuO}=50.20\%=10\left(g\right)\)
\(n_{CuO}=\dfrac{10}{80}=0,125\left(mol\right)\)
\(m_{Fe_2O_3}=50-10=40\left(g\right)\)
\(n_{Fe_2O_3}=\dfrac{40}{160}=0,25\left(mol\right)\)
PTHH :
\(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
0,125 0,125 0,125
\(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
0,25 0,75 0,5
\(a,V_{H_2}=\left(0,75+0,125\right).22,4=19,6\left(l\right)\)
\(b,m_{Cu}=0,125.64=8\left(g\right)\)
\(m_{Fe}=0,5.56=28\left(g\right)\)
a.b.
\(\left\{{}\begin{matrix}n_{Fe_2O_3}=40.80\%=32g\\m_{CuO}=40-32=8g\end{matrix}\right.\)
\(\left\{{}\begin{matrix}n_{Fe_2O_3}=\dfrac{32}{160}=0,2mol\\n_{CuO}=\dfrac{8}{80}=0,1mol\end{matrix}\right.\)
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,1 0,1 0,1 ( mol )
\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\)
0,2 0,6 0,4 ( mol )
\(V_{H_2}=\left(0,1+0,6\right).22,4=15,68l\)
\(\left\{{}\begin{matrix}m_{Cu}=0,1.64=6,4g\\m_{Fe}=0,4.56=22,4g\end{matrix}\right.\)
\(\rightarrow\left\{{}\begin{matrix}\%m_{Cu}=\dfrac{6,4}{6,4+22,4}.100=22,22\%\\\%m_{Fe}=100\%-22,22\%=77,78\%\end{matrix}\right.\)
c.
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\) ( Cu không phản ứng với H2SO4 loãng )
0,4 0,4 ( mol )
\(V_{H_2}=0,4.22,4=8,96l\)
\(m_{CuO}=40.20\%=8\left(g\right)\)
\(n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\)
\(n_{Fe_2O_3}=\dfrac{40-8}{160}=0,2\left(mol\right)\)
PTHH:
\(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
0,1 0,1
\(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
0,2 0,6
\(V_{H_2}=\left(0,1+0,6\right).22,4=15,68\left(l\right)\)
$m_{Fe_2O_3} = 60.80\% = 48(gam) \Rightarrow n_{Fe_2O_3} = \dfrac{48}{160} = 0,3(mol)$
$m_{CuO} = 60 - 48 = 12(gam) \Rightarrow n_{CuO} = \dfrac{12}{80} = 0,15(mol)$
$Fe_2O_3 + 3H_2 \xrightarrow{t^o} 2Fe + 3H_2O$
$CuO + H_2 \xrightarrow{t^o} Cu + H_2O$
$n_{H_2} = 3n_{Fe_2O_3} + n_{CuO} = 1,05(mol)$
$V_{H_2} = 1,05.22,4 = 23,52(lít)$
Ta có:
\(m_{Fe_2O_3}\) = mhh. 80% = 25 . 80% = 20(g) => \(n_{Fe_2O_3}\) = \(\dfrac{m}{M}=\dfrac{20}{160}=0,125\left(mol\right)\)
=>\(m_{CuO}\) = mhh - mFe2O3 = 25 - 20 = 5(g) => \(n_{CuO}\) = \(\dfrac{m}{M}=\dfrac{5}{80}=0,0625\left(mol\right)\)
Ta có: \(\Sigma n_O=3nFe_2O_3+nCuO=3.0,125+0,0625=0,4375\left(mol\right)\)
PT:
\(H_2+O\rightarrow H_2O\)
\(\Rightarrow n_O=n_{H_2}=0,4375\left(mol\right)\)
\(\Rightarrow V_{H_2}=n.22,4=0,4375.22,4=9,8\left(l\right)\) \(\Rightarrow B\)
\(m_{Fe_2O_3}=\dfrac{80\cdot50}{100}=40\left(g\right)\)
\(m_{CuO}=50-40=10\left(g\right)\)
\(n_{Fe_2O_3}=\dfrac{40}{160}=0.25\left(mol\right)\)
\(n_{CuO}=\dfrac{10}{80}=0.125\left(mol\right)\)
\(Fe_2O_3+3H_2\underrightarrow{t^0}2Fe+3H_2O\)
\(CuO+H_2\underrightarrow{t^0}Cu+H_2O\)
\(n_{H_2}=3\cdot0.25+0.125=0.875\left(mol\right)\)
\(V_{H_2}=0.875\cdot22.4=19.6\left(l\right)\)
Chúc bạn học tốt <3