b, PTHH: 3Fe + 2O₂ \(\underrightarrow{t^o}\) Fe₃O₄

Số nguyên tử Fe : Số phân tử O₂ : Số phân tử Fe₃O₄ là 3 : 2: 1

b, Công thức khối lượng:

m_Fe + m_O2 = m_Fe3O4

=> m_Fe3O4 = m_Fe + m_O2 = 1,68 + 0,64 = 2,32 ( g )

Bài 1:

PT: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)

a, Ta có: \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)

\(n_{O_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

Xét tỉ lệ: \(\dfrac{0,1}{3}< \dfrac{0,1}{2}\), ta được O₂ dư.

Theo PT: \(n_{O_2\left(pư\right)}=\dfrac{2}{3}n_{Fe}=\dfrac{1}{15}\left(mol\right)\)

\(\Rightarrow n_{O_2\left(dư\right)}=0,1-\dfrac{1}{15}=\dfrac{1}{30}\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}m_{O_2\left(dư\right)}=\dfrac{1}{30}.32\approx1,067\left(g\right)\\V_{O_2\left(dư\right)}=\dfrac{1}{30}.2,24\approx0,746\left(l\right)\end{matrix}\right.\)

b, Theo PT: \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=\dfrac{1}{30}\left(mol\right)\)

\(\Rightarrow m_{Fe_3O_4}=\dfrac{1}{30}.232\approx7,733\left(g\right)\)

Bài 2:

PT: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)

a, Ta có: \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)

Theo PT: \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=\dfrac{1}{15}\left(mol\right)\)

\(\Rightarrow m_{Fe_3O_4}=\dfrac{1}{15}.232\approx15,467\left(g\right)\)

b, Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=\dfrac{2}{15}\left(mol\right)\)

\(\Rightarrow V_{O_2}=\dfrac{2}{15}.22,4\approx2,9867\left(l\right)\)

c, PT: \(2N_2+5O_2\underrightarrow{t^o}2N_2O_5\)

Ta có: \(n_{N_2}=\dfrac{2,8}{28}=0,1\left(mol\right)\)

Xét tỉ lệ: \(\dfrac{0,1}{2}>\dfrac{\dfrac{2}{15}}{5}\), ta được N₂ dư.

Theo PT: \(n_{N_2O_5}=\dfrac{2}{5}n_{O_2}=\dfrac{4}{75}\left(mol\right)\)

\(\Rightarrow m_{N_2O_5}=\dfrac{4}{75}.108=5,76\left(g\right)\)

Bạn tham khảo nhé!

Bài 1 : 

\(n_{Fe}=\dfrac{5.6}{56}=0.1\left(mol\right)\)

\(n_{O_2}=\dfrac{2.24}{224}=0.1\left(mol\right)\)

     \(3Fe+2O_2\underrightarrow{t^0}Fe_3O_4\)

\(Bđ:0.1......0.1\)

\(Pư:0.1.......\dfrac{1}{15}...\dfrac{1}{30}\)

\(Kt:0........\dfrac{1}{30}....\dfrac{1}{30}\)

\(V_{O_2\left(dư\right)}=\dfrac{1}{30}\cdot22.4=0.747\left(l\right)\)

\(m_{Fe_3O_4}=\dfrac{1}{30}\cdot232=7.73\left(g\right)\)

Bài 2 : 

\(n_{Fe}=\dfrac{11.2}{56}=0.2\left(mol\right)\)

\(3Fe+2O_2\underrightarrow{t^0}Fe_3O_4\)

\(0.2.......0.3.......\dfrac{1}{15}\)

\(V_{O_2}=0.3\cdot22.4=6.72\left(l\right)\)

\(m_{Fe_3O_4}=\dfrac{1}{15}\cdot232=15.47\left(g\right)\)

\(n_{N_2}=\dfrac{2.8}{28}=0.1\left(mol\right)\)

\(2N_2+5O_2\underrightarrow{t^0}2N_2O_5\)

\(0.12......0.3........0.12\)

\(m_{N_2O_5}=0.12\cdot108=12.96\left(g\right)\)

a) \(3Fe+2O_2-t^o->Fe_3O_4\)

b) \(n_{Fe}=\frac{5,6}{56}=0,1\left(mol\right)\)

Theo pthh : \(n_{Fe_3O_4}=\frac{1}{3}n_{Fe_3O_4}=\frac{0,1}{3}\left(mol\right)\)

=> \(m_{Fe_3O_4}=232\cdot\frac{0,1}{3}\approx7,73\left(g\right)\)

c) Theo pthh : \(n_{O2\left(pứ\right)}=\frac{2}{3}n_{Fe}=\frac{0,2}{3}\left(mol\right)\)

=> \(n_{O2\left(can.dung\right)}=\frac{0,2}{3}\div100\cdot120=0,08\left(mol\right)\)

=> \(V_{O2\left(can.dung\right)}=0,08\cdot22,4=1,792\left(l\right)\)

a)

\(3Fe + 2O_2 \xrightarrow{t^o} Fe_3O_4\)

b)

Ta có :

\(n_{Fe} = \dfrac{8,4}{56} = 0,15(mol)\\ n_{O_2} = \dfrac{96}{32} = 3(mol)\)

Ta thấy : \(\dfrac{n_{Fe}}{3} = 0,05 < \dfrac{n_{O_2}}{2} = 1,5\) do đó O₂ dư.

Theo PTHH :

\(n_{O_2\ pư} = \dfrac{2}{3}n_{Fe} = 0,1(mol)\\ \Rightarrow n_{O_2\ dư} = 3 - 0,1 = 2,9(mol)\\ \Rightarrow m_{O_2\ dư} = 92,8(gam)\)

c)

\(n_{Fe_3O_4} = \dfrac{1}{3}n_{Fe} = 0,05(mol)\\ \Rightarrow m_{Fe_3O_4} = 0,05.232 = 11,6(gam)\)

\(a)PTHH:FeCl_3+2O_2\xrightarrow[]{t^o}Fe_3O_4\)

mol                 1          2              1

mol

\(b)\)Số mol \(FeCl_3\) là: \(n_{FeCl_3}=\dfrac{m_{FeCl_3}}{M_{FeCl_3}}=\dfrac{8,4}{162,5}=0,052\left(mol\right)\)

Số mol \(O_2\) là: \(n_{O_2}=\dfrac{m_{O_2}}{M_{O_2}}=\dfrac{96}{32}=3\left(mol\right)\)

Lập tỉ lệ: \(\dfrac{1}{0,052}>\dfrac{2}{3}\Rightarrow FeCl_3dư\)

Số mol \(FeCl_3\) phản ứng là:

Từ PTHH\(\Rightarrow\) \(n_{FeCl_3}=\dfrac{0,052\times3}{3}=0,035\left(mol\right)\)

Số mol \(FeCl_3\) dư là: \(n_{FeCl_3dư}=n_{FeCl_3đầu}-n_{FeCl_3p/ứng}=0,052-0,035=0,018\left(mol\right)\)

Khối lượng \(FeCl_3\) dư là: \(m_{FeCl_3dư}=n_{FeCl_3dư}\times M_{FeCl_3}=0,018\times162,5=2,925\left(g\right)\)

a)

\(Zn + 2HCl \to ZnCl_2 + H_2\\ Fe_2O_3 + 6HCl \to 2FeCl_3 + 3H_2\)

Theo PTHH : \(n_{Zn} = n_{H_2} = \dfrac{6,72}{22,4} = 0,3(mol)\)

\(\Rightarrow n_{Fe_2O_3} = \dfrac{35,5-0,3.65}{160} = 0,1\\ \Rightarrow n_{HCl} = 2n_{Zn} + 6n_{Fe_2O_3} = 0,3.2 + 0,1.6 = 1,2(mol)\\ \Rightarrow m_{HCl} = 1,2.36,5 = 43,8(gam)\)

b)

\(CuO + H_2 \xrightarrow{t^o} Cu + H_2O\\ Fe_2O_3 + 3H_2 \xrightarrow{t^o} 2Fe + 3H_2O\)

Gọi \(n_{CuO} = a;n_{Fe_2O_3} = b\)

\(\left\{{}\begin{matrix}80a+160b=19,6\\a+3b=0,3\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}a=0,135\\b=0,055\end{matrix}\right.\)

Vậy : 

\(\left\{{}\begin{matrix}n_{Cu}=0,135\\n_{Fe}=0,055.2=0,11\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}m_{Cu}=0,135.64=8,64\left(gam\right)\\m_{Fe}=0,11.56=6,16\left(gam\right)\end{matrix}\right.\)

PTHH viết sai thế kia

a. \(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)

PTHH : 3Fe + 2O₂ -t^o> Fe₃O₄

             0,3        0,2        0,1

b. \(m_{Fe_3O_4}=0,1.232=23,2\left(g\right)\)

c. \(V_{O_2}=0,2.22,4=4,48\left(l\right)\)

a \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)

b \(\Rightarrow n_{Fe}=\dfrac{16,8}{56}=0,3mol\) \(\Rightarrow n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=0,1mol\Rightarrow m_{Fe_3O_4}=0,1\cdot232=2,32g\)

c \(\Rightarrow n_{O_2}=\dfrac{2}{3}n_{Fe}=0,2mol\Rightarrow V_{O_2}=0,2\cdot22,4=4,48l\)

                     3Fe + 2O₂ → Fe₃O₄

_{Theo pt   :          3            2              1          mol}

_{Theo đề bài :       0,2         0,3        0,2/3}

_a.

Ta có tỉ lệ \(\dfrac{0,2}{3}< \dfrac{0,3}{2}\) _{nên  Fe phản ứng hết , oxi dư số mol sắt từ thu được tính theo Fe}

b. nFe₃O₄ = 0,2/3 mol ==> m Fe₃O₄ = 0,2 /3 .232 = 15,47 gam

nFe = 16,8 : 56 = 0,3  (mol) 
pthh :3 Fe + 2O2 -t--> Fe3O4
           0,3--------------> 0,1 (mol) 
=> mFe3O4 =0,1 . 232 = 23,2(G) 
nH2 = 44,8 : 22,4 = 2 (g) 
pthh : Fe3O4 + H2 -t--> Fe + H2O
   LTL :  0,1 / 1  <  2 /1 
=> H2 du 
nH2 (pu) = nFe3O4 = 0,1 (mol) 
=> nH2 (d) = 2-0,1 = 1,9 (mol) 
mH2 (d) = 1,9 . 2 = 3,8 (g) 

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