Bài 1.Cho 15g hỗn hợp gồm Fe và Cu tác dụng hết với 200ml dung dịch HCl, thu được 3,36 lit khí.
a.Tính khối lượng mỗi kim loại trong hỗn hợp ban đầu.
b.Tính nồng độ mol CM của dung dịch HCl
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a, \(n_{H_2}=0,25\left(mol\right)\)
Bảo toàn e:
\(2n_{Zn}=2n_{H_2}\Rightarrow n_{Zn}=0,25\left(mol\right)\)
\(\Rightarrow m_{Zn}=16,25\left(g\right)\)
\(\Rightarrow m_{Cu}=13,75\left(g\right)\)
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
a_____2a______a____a (mol)
\(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
b_____2b_______b____b (mol)
Ta lập hệ phương trình: \(\left\{{}\begin{matrix}56a+24b=10,4\\a+b=\dfrac{6,72}{22,4}=0,3\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,2\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,1\cdot56}{10,4}\cdot100\%\approx53,85\%\\\%m_{Mg}=46,15\%\\C_{M_{FeCl_2}}=\dfrac{0,1}{0,2}=0,5\left(M\right)\\C_{M_{MgCl_2}}=\dfrac{0,2}{0,2}=1\left(M\right)\end{matrix}\right.\)
a) \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
____0,15<--0,3<--------------0,15
=> mFe = 0,15.56 = 8,4 (g)
=> \(\left\{{}\begin{matrix}\%Fe=\dfrac{8,4}{21,2}.100\%=39,62\%\\\%Cu=\dfrac{21,2-8,4}{21,2}.100\%=60,38\%\end{matrix}\right.\)
b) mHCl = 0,3.36,5 = 10,95(g)
=> \(m_{ddHCl}=\dfrac{10,95.100}{3,65}.100\%=300\left(g\right)\)
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)=n_{Fe}\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,2\left(mol\right)\\\%m_{Fe}=\dfrac{0,1\cdot56}{12}\cdot100\%\approx46,67\%\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{HCl}}=\dfrac{0,2}{0,2}=1\left(M\right)\\\%m_{Cu}=53,33\%\end{matrix}\right.\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
Cu không phản ứng
\(nH_2=nFe=\dfrac{2,24}{22,4}=0,1mol\)
\(\rightarrow mFe=0,1.56=5,6gam\)
\(\rightarrow\%mFe=\dfrac{5,6}{12}.100\%=46,\left(6\right)\%\)
\(\rightarrow\%mCu=100\%-46,\left(6\right)\%=53,\left(3\right)\%\)
c)
\(CM_{HCl}=\dfrac{0,1.2}{0,2}=1M\)
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, Ta có: \(n_{H_2}=\dfrac{22,4}{22,4}=1\left(mol\right)\)
Theo PT: \(n_{Zn}=n_{H_2}=1\left(mol\right)\Rightarrow m_{Zn}=1.65=65\left(g\right)\)
\(\Rightarrow m_{Cu}=80,5-65=15,5\left(g\right)\)
a)
Gọi $n_{CaCO_3} = a ; n_{MgCO_3} = b$
$\Rightarrow 100a + 84b = 4,68(1)$
$CaCO_3 + 2HCl \to CaCl_2 + CO_2 + H_2O$
$MgCO_3 + 2HCl \to MgCl_2 +C O_2 + H_2O$
$n_{CO_2} = a + b = 0,05(2)$
Từ (1)(2) suy ra a = 0,03 ; b = 0,02
$\%m_{CaCO_3} = \dfrac{0,03.100}{4,68}.100\% = 64,1\%$
$\%m_{MgCO_3} = 35,9\%$
$m_{CaCl_2} = 0,03.111 = 3,33(gam)$
$m_{MgCl_2} = 0,02.95 = 1,9(gam)$
b)
$n_{HCl} = 2n_{CO_2} = 0,1(mol)$
$C_{M_{HCl}} = \dfrac{0,1}{0,25} = 0,4M$
a) Fe + 2HCl --> FeCl2 + H2
b) \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
_____0,15<-0,3<----0,15<---0,15
\(\left\{{}\begin{matrix}\%Fe=\dfrac{0,15.56}{12}.100\%=70\%\%\\\%Cu=100\%-70\%=30\%\end{matrix}\right.\)
c) mHCl = 0,3.36,5 = 10,95 (g)
=> \(m_{dd}=\dfrac{10,95.100}{10}=109,5\left(g\right)\)
d) mdd = 12 + 109,5 - 0,15.2 = 121,2 (g)
\(C\%\left(FeCl_2\right)=\dfrac{0,15.127}{121,2}.100\%=15,718\%\)
Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
Theo PT: \(n_{HCl}=2n_{H_2}=0,2\left(mol\right)\Rightarrow C_{M_{HCl}}=\dfrac{0,2}{0,1}=2\left(M\right)\)
\(n_{Fe}=n_{H_2}=0,1\left(mol\right)\Rightarrow m_{Fe}=0,1.56=5,6\left(g\right)\)
\(\Rightarrow m_{Cu}=20-5,6=14,4\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{5,6}{20}.100\%=28\%\\\%m_{Cu}=72\%\end{matrix}\right.\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
\(n_{Fe}=n_{H_2}=\dfrac{3.36}{22.4}=0.15\left(mol\right)\)
\(\Rightarrow m_{Fe}=0.15\cdot56=8.4\left(g\right)\)
\(m_{Cu}=m_{hh}-m_{Fe}=15-8.4=6.6\left(g\right)\)
\(n_{HCl}=2n_{H_2}=0.15\cdot2=0.3\left(mol\right)\)
\(C_{M_{HCl}}=\dfrac{0.3}{0.2}=1.5\left(M\right)\)