Gọi nCH4 = a mol ; nC2H6 = b mol

có n hỗn hợp khí = \(\dfrac{10,08}{22,4}\) =0,45 mol ; nCO2 = \(\dfrac{14,56}{22,4}\) =0,65 mol

⇒ a + b = 0,45 (1)

BTNT với C , ta có nCO2 = nCH4 + 2nC2H6 ⇔ a +2b = 0,65 (2)

Từ (1) và (2) suy ra a= 0,25 ;b=0,2

⇒%VCH4 = \(\dfrac{0,25}{0,45}\) .100% =55,56% ; %VC2H6 = 44,44%

b)

CO2 + Ba(OH)2 ----> BaCO3 + H2O

0,65                              0,65                (mol)

⇒ a = 0,65.197 =128,05 gam

nhh khí = 5,6/22,4 = 0,25 (mol)

nBr2 = 16/160 = 0,1 (mol)

PTHH: C2H2 + 2Br2 -> C2H2Br4

Mol: 0,05 <--- 0,1

nCH4 = 0,25 - 0,05 = 0,2 (mol)

%VC2H2 = 0,05/0,25 = 20%

%VCH4 = 100% - 20% = 80%

PTHH: 

2C2H2 + 5O2 -> (t°) 4CO2 + 2H2O

0,05 ---> 0,125 ---> 0,1

CH4 + 2O2 -> (t°) CO2 + 2H2O

0,2 ---> 0,4 ---> 0,2

nCO2 = 0,2 + 0,1 = 0,3 (mol)

PTHH: Ca(OH)2 + CO2 -> CaCO3 + H2O

nCaCO3 = 0,3 (mol)

mCaCO3 = 0,3 . 100 = 30 (g)

sao anh gọi em là xoá bỏ :))

Gọi số mol CO, CH₄ là a, b (mol)

=> \(a+b=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)

\(n_{O_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

PTHH: 2CO + O₂ --t^o--> 2CO₂

              a--->0,5a

            CH₄ + 2O₂ --t^o--> CO₂ + 2H₂O

             b--->2b

=> 0,5a + 2b = 0,2

=> a = 0,2 (mol); b = 0,05 (mol)

=> \(\left\{{}\begin{matrix}\%V_{CO}=\dfrac{0,2}{0,25}.100\%=80\%\\\%V_{CH_4}=\dfrac{0,05}{0,25}.100\%=20\%\end{matrix}\right.\)

\(n_{hh}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\ n_{O_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\ 2CO+O_2\rightarrow\left(t^o\right)2CO_2\\ CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\\ Đặt:n_{CO}=a\left(mol\right);n_{CH_4}=b\left(mol\right)\left(a,b>0\right)\\ \Rightarrow\left\{{}\begin{matrix}a+b=0,25\\0,5a+2b=0,2\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,05\end{matrix}\right.\\ \Rightarrow\%V_{\dfrac{CO}{hh}}=\%n_{\dfrac{CO}{hh}}=\dfrac{a}{a+b}.100\%=\dfrac{0,2}{0,25}.100=80\%;\%V_{CH_4}=100\%-80\%=20\%\)

\(n_{Br_2}=\dfrac{16}{160}=0,1mol\Rightarrow n_{CH_2}=0,1mol\)

\(n_{hh}=\dfrac{5,6}{22,4}=0,25mol\)

\(\Rightarrow n_{CH_4}=0,25-0,1=0,15mol\)

\(\%V_{CH_2}=\dfrac{0,1}{0,25}\cdot100\%=40\%\)

\(\%V_{CH_4}=100\%-40\%=60\%\)

\(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)

\(CH_2+\dfrac{3}{2}O_2\underrightarrow{t^o}CO_2+H_2O\)

\(\Rightarrow\Sigma n_{CO_2}=0,15+0,1=0,25mol\)

\(BTC:n_{CO_2}=n_{CaCO_3}=0,25mol\)

\(\Rightarrow m_{\downarrow}=0,25\cdot100=25g\)

a, Ta có \(n_{CH_4}+n_{C_2H_4}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\left(1\right)\)

PT: \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)

\(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)

Theo PT: \(n_{O_2}=2n_{CH_4}+3n_{C_2H_4}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{CH_4}=0,05\left(mol\right)\\n_{C_2H_4}=0,1\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}V_{CH_4}=0,05.22,4=1,12\left(l\right)\\V_{C_2H_4}=0,1.22,4=2,24\left(l\right)\end{matrix}\right.\)

b, \(m_{CH_4}=0,05.16=0,8\left(g\right)\)

c, \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

Theo PT: \(n_{Br_2}=n_{C_2H_4}=0,1\left(mol\right)\Rightarrow V_{ddBr_2}=\dfrac{0,1}{1}=0,1\left(l\right)\)

\(m_{C_2H_4}=0,1.28=2,8\left(g\right)\)

\(\left\{{}\begin{matrix}n_{CH_4}=a\left(mol\right)\\n_{C_2H_4}=b\left(mol\right)\end{matrix}\right.\)\(\Rightarrow a + b = \dfrac{3,36}{22,4} = 0,15(1) \)

\(CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ C_2H_4 + 3O_2 \xrightarrow{t^o} 2CO_2 + 2H_2O\\ n_{CO_2} = a + 2b = \dfrac{4,48}{22,4} = 0,2(2)\)

Từ (1)(2) suy ra: a = 0,1 ; b = 0,05

Suy ra:

\(\%V_{CH_4} = \dfrac{0,1}{0,15}.100\% = 66,67\%\\ \%V_{C_2H_4} = 100\% - 66,67\% = 33,33\%\)

b)

\(C_2H_4 + Br_2 \to C_2H_4Br_2\\ n_{Br_2} = n_{C_2H_4} = 0,05(mol)\\ \Rightarrow m_{Br_2} = 0,05.160 = 8\ gam\)

Giả sử các khí được đo ở điều kiện sao cho 1 mol khí chiếm thể tích 1 lít

Gọi số mol CH₄, C₂H₆ là a, b (mol)

=> \(a+b=\dfrac{25}{1}=25\left(mol\right)\) (1)

\(n_{O_2}=\dfrac{95}{1}=95\left(mol\right)\)

PTHH: CH₄ + 2O₂ --t^o--> CO₂ + 2H₂O

             a---->2a---------->a

            2C₂H₆ + 7O₂ --t^o--> 4CO₂ + 6H₂O

              b------>3,5b-------->2b

=> \(\left\{{}\begin{matrix}n_{O_2\left(dư\right)}=95-2a-3,5b\left(mol\right)\\n_{CO_2}=a+2b\left(mol\right)\end{matrix}\right.\)

=> \(95-a-1,5b=\dfrac{60}{1}=60\)

=> a + 1,5b = 35 (2)

(1)(2) => a = 5; b = 20

=> \(\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{5}{25}.100\%=20\%\\\%V_{C_2H_6}=\dfrac{20}{25}.100\%=80\%\end{matrix}\right.\)

\(\overline{M}_A=\dfrac{5.16+20.30}{5+20}=27,2\left(g/mol\right)\)

\(\overline{M}_B=20,5.2=41\left(g/mol\right)\)

=> \(d_{A/B}=\dfrac{27,2}{41}\approx0,663\)

tỉ khối là 13 chứ

nX = 0,25

 n↓ = nAnkin = 0,25.20% = 0,05

=>M↓ = 147: C3H3Ag

->Ankin là C3H4 (0,05 mol)
nY = 0,2; nCO2 = 0,3 

=>Số C = nCO2/nY = 1,5

 Ankan là CH4
mY = mX – mC3H4 = 4,5

=>nH2O = \(\dfrac{4,5}{0,3.12}.\dfrac{1}{2}\) = 0,45
 nCH4 = nH2O – nCO2 = 0,15 và nCxH2x = nY – nCH4 = 0,05

nCO2 = 0,15.1 + 0,05x = 0,3

=>x = 3
=> Anken là C3H6

\(n_{O_2}=\dfrac{41,44}{22,4}.20\%=0,37(mol)\\ n_{H_2O}=\dfrac{4,68}{18}=0,26(mol)\)

Bảo toàn nguyên tố (O): \(n_{CO_2}=n_{O_2}=0,37(mol)\)

\(\Rightarrow V_{CO_2}=0,37.22,4=8,288(l)\)

BTKL: \(m_{hh}=m_{CO_2}+m_{H_2O}-m_{O_2}=0,37.44+4,68-0,37.32=9,12(g)\)