Bài 9 : 

\(a) n_{Fe_2O_3} = \dfrac{3,2}{160}=0,02(mol)\\ Fe_2O_3 + 3H_2SO_4 \to Fe_2(SO_4)_3 + 3H_2O\\ n_{H_2SO_4} = 3n_{Fe_2O_3} = 0,06(mol)\\ m_{dd\ H_2SO_4} = \dfrac{0,06.98}{19,6\%} = 30(gam)\\ b) \text{Chất tan : } Fe_2(SO_4)_3\\ n_{Fe_2(SO_4)_3} = n_{Fe_2O_3} = 0,02(mol)\\ m_{Fe_2(SO_4)_3} = 0,02.400 =8(gam)\)

Bài 8 : 

\(n_{Al_2O_3} = \dfrac{2,04}{102} = 0,02(mol)\\ Al_2O_3 + 6HCl \to 2AlCl_3 + 3H_2O\\ n_{HCl} = 6n_{Al_2O_3} = 0,02.6 = 0,12(mol)\\ C_{M_{HCl}} = \dfrac{0,12}{0,2} =0,6M\)

Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

a. PTHH: \(Mg+2HCl--->MgCl_2+H_2\)

Theo PT: \(n_{Mg}=n_{H_2}=0,2\left(mol\right)\)

=> \(m_{Mg}=0,2.24=4,8\left(g\right)\)

Theo PT: \(n_{HCl}=2.n_{Mg}=2.0,2=0,4\left(mol\right)\)

=> \(m_{HCl}=0,4.36.5=14,6\left(g\right)\)

=> \(C_{\%_{HCl}}=\dfrac{14,6}{200}.100\%=7,3\%\)

b. Ta có: \(m_{dd_{MgCl_2}}=4,8+200=204,8\left(g\right)\)

Theo PT: \(n_{MgCl_2}=n_{Mg}=0,2\left(mol\right)\)

=> \(m_{MgCl_2}=0,2.95=19\left(g\right)\)

=> \(C_{\%_{MgCl_2}}=\dfrac{19}{204,8}.100\%=9,28\%\)

a)

$n_{HCl} = \dfrac{3,65}{36,5} = 0,1(mol)$
$CaCO_3 + 2HCl \to CaCl_2 + CO_2 + H_2O$

$n_{CaCO_3} = n_{CaCl_2} = n_{CO_2} = \dfrac{1}{2}n_{HCl} = 0,05(mol)$

$\%m_{CaCO_3} = \dfrac{0,05.100]{31,1}.100\% = 16,08\%$
$\%m_{Ba(NO_3)_2} = 100\% -16,08\% = 83,92\%$

b)

$m_{dd\ sau\ pư} = 31,1 + 96,1 - 0,05.44 = 125(gam)$
$C\%_{Ba(NO_3)_2} = \dfrac{31,1 - 0,05.100}{125}.100\% = 20,88\%$

$C\%_{CaCl_2} = \dfrac{0,05.111}{125}.100\% = 4,44\%$

a) 

\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

PTHH: Mg + 2HCl --> MgCl₂ + H₂

_____0,1<---0,2<-------0,1<---0,1

=> m_HCl = 0,2.36,5 = 7,3 (g)

=> \(m_{ddHCl}=\dfrac{7,3.100}{7,3}=100\left(g\right)\)

m_{dd sau pư} = 0,1.24 + 100 - 0,1.2 = 102,2 (g)

\(C\%\left(MgCl_2\right)=\dfrac{0,1.95}{102,2}.100\%=9,2955\%\)

b)

CTHH: A_aO_b

PTHH: \(A_aO_b+2bHCl->aACl_{\dfrac{2b}{a}}+bH_2O\)

____________0,2------->\(\dfrac{0,1a}{b}\)

=> \(\dfrac{0,1a}{b}\left(M_A+35,5.\dfrac{2b}{a}\right)=13,5\)

=> \(M_A=\dfrac{64b}{a}=\dfrac{2b}{a}.32\)

Nếu \(\dfrac{2b}{a}=1\) => M_A = 32 (L)

Nếu \(\dfrac{2b}{a}=2\) => M_A = 64(Cu)

\(n_{Na_2SO_3}=\dfrac{25,2}{126}=0,2(mol)\\ n_{HCl}=\dfrac{250.7,3\%}{100\%.36,5}=0,5(mol)\\ PTHH:Na_2SO_3+2HCl\to 2NaCl+H_2O+SO_2\uparrow\)

Vì \(\dfrac{n_{Na_2SO_3}}{1}<\dfrac{n_{HCl}}{2}\) nên \(HCl\) dư

\(a,n_{SO_2}=n_{Na_2SO_3}=0,2(mol)\\ \Rightarrow V_{SO_2}=0,2.22,4=4,48(l)\)

\(b,\) Chất tan trong dd sau phản ứng là \(NaCl\)

\(c,n_{NaCl}=2n_{Na_2SO_3}=0,4(mol)\\ \Rightarrow m_{NaCl}=0,4.58,5=23,4(g)\)

chất tan gồm HCl dư nữa e

Na2SO3+2HCl->2NaCl+H2O+SO2

0,201-------0,402------0,402---------------0.201

n Na2SO3=0,201 mol

m HCl=18,25 g

->n HCl=0,5 mol

=>HCl dư

=>VSO2=0,201.22,4=4,5024l

b)

mNaCl=\(\dfrac{0,402.58,5}{25,4+250-0,201.64}\).100=8,95%

m Hcl dư=\(\dfrac{0,098.36,5}{25,4+250-0,201.64}.100=1,36\%\)

Bài 19  :

\(a) n_{Al} = \dfrac{10,8}{27} = 0,4(mol)\\ 2Al + 3H_2SO_4 \to Al_2(SO_4)_3 + 3H_2\\ n_{H_2} = \dfrac{3}{2}n_{Al} = 0,6(mol)\\ V_{H_2} = 0,6.22,4 = 13,44(lít)\\ b) \text{Chất tan : }Al_2(SO_4)_3\\ n_{Al_2(SO_4)_3} = \dfrac{1}{2}n_{Al} = 0,2(mol)\\ m_{Al_2(SO_4)_3} = 0,2.342 = 68,4(gam)\)

Bài 18 : 

\(a) n_{HCl} = \dfrac{250.7,3\%}{36,5 } = 0,5(mol)\\ Zn + 2HCl \to ZnCl_2 + H_2\\ n_{H_2} = \dfrac{1}{2}n_{HCl} = 0,25(mol) \Rightarrow V_{H_2} = 0,25.22,4 = 5,6(lít)\\ b) \text{Chất tan : } ZnCl_2\\ n_{ZnCl_2} = n_{H_2} = 0,25(mol)\\ m_{ZnCl_2} = 0,25.136 = 34(gam)\)

Zn+2HCl->ZnCl2+H2

ZnO+2HCl->ZnCl2+H2O

nH2=0.2(mol)->nZn=0.2(mol).mZn=13(g)

mZnO=21.1-13=8.1(g)

nZnO=0.1(mol)

Tổng nHCl cần dùng:0.2*2+0.1*2=0.6(mol)

mHCl=21.9(g)

C%ddHCl=21.9:200*100=10.95%

n muối=0.2+.1=0.3(mol)

m muối=40.8(g)