Đốt cháy hoàn toàn 4,48l khí butan trong không khí
a/Tính VO2, Vkk cần dùng, biết trong không khí, oxi chiếm 20% thể tích
b/Để có được lượng khí oxi bằng lượng oxi phản ứng trên người ta phải nung bao nhiêu gam KMnO4
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a, \(2Zn+O_2\underrightarrow{t^o}2ZnO\)
b, \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{1}{2}n_{Zn}=0,1\left(mol\right)\Rightarrow V_{O_2}=0,1.22,4=2,24\left(l\right)\)
\(\Rightarrow V_{kk}=5V_{O_2}=11,2\left(l\right)\)
c, \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
Theo PT: \(n_{KMnO_4}=2n_{O_2}=0,2\left(mol\right)\Rightarrow m_{KMnO_4}=0,2.158=31,6\left(g\right)\)
Theo gt ta có: $n_{H_2}=0,75(mol)$
a, $2H_2+O_2\rightarrow 2H_2O$
Ta có: $n_{O_2}=0,5.n_{H_2}=0,375(mol)\Rightarrow V_{O_2}=8,4(l)\Rightarrow V_{kk}=42(l)$
b, $2KMnO_4\rightarrow K_2MnO_4+MnO_2+O_2$
Ta có: $n_{KMnO_4}=2.n_{O_2}=0,75(mol)\Rightarrow m_{KMnO_4}=118,5(g)$
a)
\(2H_2 + O_2 \xrightarrow{t^o} 2H_2O\\ V_{O_2} = \dfrac{V_{H_2}}{2} = \dfrac{16,8}{2} = 8,4(lít)\\ V_{không\ khí} = \dfrac{8,4}{20\%} = 42(lít)\)
b)
\(n_{O_2} = \dfrac{8,4}{22,4} = 0,375(mol)\\ 2KMnO_4 \xrightarrow{t^o} K_2MnO_4 + MnO_2 + O_2\\ n_{KMnO_4} = 2n_{O_2} = 0,75(mol)\\ \Rightarrow m_{KMnO_4} = 0,75.158 = 118,5(gam)\\ 2KClO_3 \xrightarrow{t^o} 2KCl + 3O_2\\ n_{KClO_3} = \dfrac{2}{3}n_{O_2} = 0,25(mol)\\ \Rightarrow m_{KClO_3} = 0,25.122,5 = 30,625(gam)\)
a) \(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
PTHH: \(3Fe+2O_2\xrightarrow[]{t^o}Fe_3O_4\)
0,3--->0,2----->0,1
\(\Rightarrow m_{Fe_3O_4}=0,1.232=23,2\left(g\right)\)
b) \(V_{O_2}=0,2.22,4=4,48\left(l\right)\Rightarrow V_{kk}=4,48.5=22,4\left(l\right)\)
c) \(n_{O_2\left(hao,h\text{ụt}\right)}=0,2.10\%=0,02\left(mol\right)\)
\(\Rightarrow n_{O_2\left(t\text{ổng}\right)}=0,2+0,02=0,22\left(mol\right)\)
PTHH: \(2KMnO_4\xrightarrow[]{t^o}K_2MnO_4+MnO_2+O_2\)
0,44<------------------------------------0,22
\(\Rightarrow m_{KMnO_4}=0,44.158=69,52\left(g\right)\)
\(n_{H_2}\)=\(\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PTHH 2H2 +O2----to--->2H2O
0,2....0,1.................0,2
=>\(m_{H_2O}=0,2.18=3,6\left(g\right)\)
=>\(V_{O_2}=0,1.22,4=2,24\left(l\right)\)
=>Vkk=2,24.5=11,2(l)
\(n_{H_2} = \dfrac{4,48}{22,4} = 0,2(mol)\\ 2H_2 + O_2 \xrightarrow{t^o} 2H_2O\\ n_{H_2O} = n_{H_2} =0,2(mol) \Rightarrow m_{H_2O} = 0,2.18 = 3,6(gam)\\ n_{O_2} = \dfrac{1}{2}n_{H_2} = 0,1(mol)\\ \Rightarrow V_{O_2} = 0,1.22,4 = 2,24(lít)\\ \Rightarrow V_{không\ khí} = 5V_{O_2} = 2,24.5 = 11,2(lít) \)
a)
\(n_{CH_4}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)
PTHH: CH4 + 2O2 --to--> CO2 + 2H2O
0,5--->1
=> VO2 = 1.22,4 = 22,4 (l)
b)
VO2 = 22,4.2 = 44,8 (l)
=> Vkk = 44,8.5 = 224 (l)
4Al+3O2-to>2Al2O3
0,4----0,3---------0,2 mol
n Al2O3=\(\dfrac{20,4}{102}\)=0,2 mol
=>m Al=0,4.27=10,8g
=>VO2=0,3.22,4=6,72l
=>Vkk=6,72.5=33,6l
4Al + 3O2 ---> 2Al2O3
0,4 0,3 0,2
nAl2O3 = 20,4 / 102 = 0,2 ( mol )
=> mAl = 0,4 . 27 = 10,8 (g)
V O2 = 0,3.22,4 = 6,72(l)
Vkk = 6,72 . 5 = 33,6(l)
\(n_C=\dfrac{14,4}{44}=\dfrac{18}{55}\left(mol\right)\\ C+O_2\rightarrow\left(t^o\right)CO_2\\ n_{O_2}=n_C=n_{CO_2}=\dfrac{18}{55}\left(mol\right)\\ a,V_{O_2\left(đktc\right)}=\dfrac{18}{55}.22,4=\dfrac{2016}{275}\left(lít\right)\\ b,V_{kk}=\dfrac{100}{21}.\dfrac{2016}{275}=\dfrac{381}{11}\left(lít\right)\\ c,2KClO_3\rightarrow\left(t^o\right)2KCl+3O_2\\ n_{KClO_3\left(LT\right)}=\dfrac{2}{3}.n_{O_2}=\dfrac{2}{3}.\dfrac{18}{55}=\dfrac{12}{55}\left(mol\right)\\ \Rightarrow n_{KClO_3\left(TT\right)}=120\%.\dfrac{12}{55}=\dfrac{72}{275}\left(mol\right)\\ \Rightarrow m_{KClO_3}=122,5.\dfrac{72}{275}=\dfrac{1764}{55}\left(g\right)\)
a.\(n_{C_4H_{10}}=\dfrac{4,48}{22,4}=0,2mol\)
\(2C_4H_{10}+13O_2\rightarrow\left(t^o\right)8CO_2+10H_2O\)
0,2 1,3 ( mol )
\(V_{O_2}=1,3.22,4=29,12l\)
\(V_{kk}=29,12.5=145,6l\)
b.\(2KMnO_4\rightarrow\left(t^o\right)K_2MnO_4+MnO_2+O_2\)
2,6 1,3 ( mol )
\(m_{KMnO_4}=2,6.158=410,8g\)
\(n_{C_4H_{10}}=\dfrac{4,48}{22,4}=0,2\left(MOL\right)\\ pthh:2C_2H_{10}+13O_2\underrightarrow{t^o}8CO_2+10H_2O\)
0,2 1,3
=> \(V_{O_2}=1,3.22,4=29,12\left(l\right)\\ V_{kk}=29,12:20\%=145,6\left(l\right)\\ pthh:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
2,6 1,3
=> \(m_{KMnO_4}=2,6.158=410,8\left(g\right)\)