Cho 8,125 gam kẽm vào dung dịch axit clohidric nồng độ 0,5M.
a. Tính thể tích dung dịch axit clohiđric đã phản ứng?
b. Tính thể tích khí sinh ra (đktc)?
c. Tính nồng độ dung dịch muối thu được (coi thể tích dung dịch không thay đổi)?
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\(n_{Fe}=\dfrac{36,4}{56}=0,65\left(mol\right)\)
PTHH: Fe + 2HCl ---> FeCl2 + H2
0,65->1,3----->0,65--->0,65
=> \(\left\{{}\begin{matrix}a,V_{ddHCl}=\dfrac{1,3}{0,5}=2,6\left(l\right)\\b,V_{H_2}=0,65.22,4=14,56\left(l\right)\end{matrix}\right.\)
c, \(C_{M\left(FeCl_2\right)}=\dfrac{0,65}{2,6}=0,25M\)
\(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\\ a.Mg+2HCl\rightarrow MgCl_2+H_2\\ n_{H_2}=n_{MgCl_2}=n_{Mg}=0,2\left(mol\right)\\ V_{H_2\left(đktc\right)}=0,2.22,4=4,48\left(l\right)\\ b.n_{HCl}=0,2.2=0,4\left(mol\right)\\ m_{ddHCl}=\dfrac{0,4.36,5.100}{7,3}=200\left(g\right)\\ c.m_{ddsau}=4,8+200-0,2.2=204,4\left(g\right)\\ C\%_{ddMgCl_2}=\dfrac{0,2.95}{204,4}.100\approx9,295\%\\ d.V_{ddHCl}=\dfrac{200}{1,05}=\dfrac{4000}{21}\left(ml\right)=\dfrac{4}{21}\left(l\right)\\ C_{MddHCl}=\dfrac{0,4}{\dfrac{4}{21}}=2,1\left(M\right)\)
`a)PTHH:`
`Zn + 2HCl -> ZnCl_2 + H_2`
`0,02` `0,02` `0,02` `(mol)`
`n_[Zn]=[1,3]/65=0,02(mol)`
`b)V_[H_2]=0,02.22,4=0,448(l)`
`c)C%_[ZnCl_2]=[0,02.136]/[1,3+50-0,02.2].100~~5,31%`
\(n_{Zn}=\dfrac{1,3}{65}=0,02\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,02 0,04 0,02 0,02 ( mol )
\(V_{H_2}=0,02.22,4=0,448\left(l\right)\)
\(C\%_{ZnCl_2}=\dfrac{0,02.136}{1,3+50-0,02.2}.100=5,3\%\)
a) pt: 2Al + 6HCl \(\rightarrow\) 2AlCl3 + 3H2
nAl = \(\dfrac{5,4}{27}=0,2mol\)
Theo pt: nH2 = \(\dfrac{3}{2}nAl=0,3mol\)
=> VH2 = 0,3.22,4 = 6,72lit
c) nHCl = 3nAl = 0,6mol
=> mHCl = 21,9g
=> C% = \(\dfrac{21,9}{200}.100\%=10,95\%\)
d) Bảo toàn khối lượng
mdung dich muối = mAl + mHCl - mH2
= 5,4 + 200 - 0,3.2 = 204,8g
Theo pt:nAlCl3 = nAl = 0,2mol
=> mAlCl3 = 0,2.133,5 = 26,7g
=> C%dd muối = \(\dfrac{26,7}{204,8}.100\%=13,03\%\)
e) H2 + CuO \(\xrightarrow[]{t^o}\) Cu + H2O
nCu = nH2 = 0,3mol
=> mCu = 0,3.64 = 19,2g
a, \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
PTHH: Zn + 2HCl ---> ZnCl2 + H2
0,1--->0,2------->0,1----->0,1
VH2 = 0,1.22,4 = 2,24 (l)
b, \(C_{M\left(HCl\right)}=\dfrac{0,2}{0,2}=1M\)
c, \(C_{M\left(ZnCl_2\right)}=\dfrac{0,1}{0,2}=0,5M\)
a, \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
\(m_{HCl}=100.14,6\%=14,6\left(g\right)\Rightarrow n_{HCl}=\dfrac{14,6}{36,5}=0,4\left(mol\right)\)
Xét tỉ lệ: \(\dfrac{0,1}{1}< \dfrac{0,4}{2}\), ta được HCl dư.
Theo PT: \(n_{H_2}=n_{Zn}=0,1\left(mol\right)\Rightarrow V_{H_2}=0,1.22,4=2,24\left(l\right)\)
b, Theo PT: \(\left\{{}\begin{matrix}n_{HCl\left(pư\right)}=2n_{Zn}=0,2\left(mol\right)\\n_{ZnCl_2}=n_{Zn}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{HCl\left(dư\right)}=0,4-0,2=0,2\left(mol\right)\)
Ta có: m dd sau pư = 6,5 + 100 - 0,1.2 = 106,3 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,1.136}{106,3}.100\%\approx12,79\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,2.36,5}{106,3}.100\%\approx6,87\%\end{matrix}\right.\)
a)
$n_{Al} = \dfrac{8,1}{27} = 0,3(mol)$
$2Al + 6HCl \to 2AlCl_3 + 3H_2$
Theo PTHH :
$n_{H_2} = \dfrac{3}{2}n_{Al} = 0,45(mol)$
$V_{H_2} = 0,45.22,4 = 10,08(lít)$
b) $n_{HCl} = 3n_{Al} = 0,9(mol)$
$\Rightarrow m_{dd\ HCl} = \dfrac{0,9.36,5}{3,65\%} = 900(gam)$
c)
$m_{dd\ sau\ pư}= 8,1 + 900 - 0,45.2 = 907,2(gam)$
$n_{Al_2(SO_4)_3} = \dfrac{1}{2}n_{Al} = 0,15(mol)$
$C\%_{Al_2(SO_4)_3} = \dfrac{0,15.342}{907,2}.100\% = 5,65\%$
a) Zn + 2HCl → ZnCl2 + H2
b) n H2 = n Zn = 1,95/65 = 0,03(mol)
V H2 = 0,03.22,4 = 0,672(lít)
c) n ZnCl2 = n Zn = 0,03(mol)
=> m dd sau pư = 1,95 + 120 - 0,03.2 = 121,89(gam)
C% ZnCl2 = 0,03.136/121,89 .100% = 3,35%
a) nZn=0,03(mol)
PTHH: Zn + 2 HCl -> ZnCl2 + H2
nH2=nZnCl2=nZn=0,03(mol)
b) V(H2,đktc)=0,03.22,4=0,672(l)
c) mZnCl2=136.0,03=4,08(g)
mddA=mddZnCl2=1,95+ 120 - 0,03.2= 121,89(g)
=> C%ddZnCl2=(4,08/121,89).100=3,347%
\(a,n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\)
PTHH: Zn + 2HCl ---> ZnCl2 + H2
0,125->0,25----->0,125->0,125
\(\Rightarrow\left\{{}\begin{matrix}a,V_{ddHCl}=\dfrac{0,25}{0,5}=0,5\left(l\right)\\b,V_{H_2}=0,125.22,4=2,8\left(l\right)\\c,C_{M\left(ZnCl_2\right)}=\dfrac{0,125}{0,5}=0,25M\end{matrix}\right.\)