Bài 1

Bài 5

Fe + 2CH₃COOH \(\rightarrow\) (CH₃COO)₂Fe + H₂(1)

nCH₃COOH = \(\dfrac{4,5}{60}=0,075mol\)

a) THeo pt: n(CH₃COO)₂Fe = \(\dfrac{1}{2}.nCH_3COOH=0,0375mol\)

=> m = 6,525g

c) Theo pt (1) nH₂ = 1/2nCH₃COOH = 0,0375 mol

2H₂ + O₂ \(\xrightarrow[]{t^o}\) 2H₂O

Theo pt: nO₂ = 0,5nH₂ = 0,01875mol

=> VO₂ = 0,42 lít

=> Vkk = 0,42.5 = 2,1 lít

a) \(n_{\left(CH_3COO\right)_2Mg}=\dfrac{7,1}{142}=0,05\left(mol\right)\)

PTHH: 2CH₃COOH + Mg --> (CH₃COO)₂Mg + H₂

                  0,1<----------------------0,05------->0,05

=> V_H2 = 0,05.22,4 = 1,12 (l)

b) \(C_{M\left(dd.CH_3COOH\right)}=\dfrac{0,1}{0,025}=4M\)

\(a,n_{\left(CH_3COO\right)_2Mg}=\dfrac{7,1}{142}=0,05\left(mol\right)\)

PTHH: \(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\uparrow\)

                        0,1<----------------0,05-------------->0,05

\(\rightarrow V_{H_2}=0,05.22,4=1,12\left(l\right)\\ b,C\%_{CH_3COOH}=\dfrac{0,1.60}{100}.100\%=6\%\)

\(c,n_{C_2H_5OH}=\dfrac{6,9}{46}=0,15\left(mol\right)\)

PTHH: \(CH_3COOH+C_2H_5OH\xrightarrow[H_2SO_{4\left(đặc\right)}]{t^o}CH_3COOC_2H_5+H_2O\)

bđ          0,1                 0,15

pư          0,1                 0,1

spư         0                     0,05                          0,1

\(\rightarrow m_{este}=0,1.80\%.88=7,04\left(g\right)\)

a) 

\(n_{Zn}=\dfrac{16,25}{65}=0,25\left(mol\right)\)

PTHH: Zn + H₂SO₄ --> ZnSO₄ + H₂

         0,25-->0,25------------->0,25

=> V_H2 = 0,25.22,4 = 5,6 (l)

b) \(C_{M\left(dd.H_2SO_4\right)}=\dfrac{0,25}{0,3}=\dfrac{5}{6}M\)

c) \(n_{Fe_2O_3}=\dfrac{32}{160}=0,2\left(mol\right)\)

PTHH: Fe₂O₃ + 3H₂ --t^o--> 2Fe + 3H₂O

Xét tỉ lệ: \(\dfrac{0,2}{1}>\dfrac{0,25}{3}\) => Fe₂O₃ dư, H₂ hết

PTHH: Fe₂O₃ + 3H₂ --t^o--> 2Fe + 3H₂O

           \(\dfrac{0,25}{3}\) <--0,25----->\(\dfrac{0,5}{3}\)

=> \(m=32-\dfrac{0,25}{3}.160+\dfrac{0,5}{3}.56=28\left(g\right)\)

PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)

đb:       0,25

a) số mol của Zn là: \(n_{Zn}=\dfrac{m_{Zn}}{M_{Zn}}=\dfrac{16,25}{65}=0,25\left(mol\right)\)

Theo PTHH, ta có: \(n_{H_2}=\dfrac{0,25\cdot1}{1}=0,25\left(mol\right)\)

Thể tích của H₂ ở đktc là: \(V_{H_2\left(đktc\right)}=n_{H_2}\cdot22,4=0,25\cdot22,4=5,6\left(l\right)\)

2 câu còn lại mk chịu

\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)

PT: \(Fe+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Fe+H_2\)

a, Theo PT: \(n_{CH_3COOH}=2n_{Fe}=0,2\left(mol\right)\Rightarrow m_{CH_3COOH}=0,2.60=12\left(g\right)\)

\(\Rightarrow m_{ddCH_3COOH}=\dfrac{12}{10\%}=120\left(g\right)\)

\(n_{H_2}=n_{Fe}=0,1\left(mol\right)\Rightarrow V_{H_2}=0,1.22,4=2,24\left(l\right)\)

b, Theo PT: \(n_{\left(CH_3COO\right)_2Fe}=n_{Fe}=0,1\left(mol\right)\)

Ta có: m _{dd sau pư} = 5,6 + 120 - 0,1.2 = 125,4 (g)

\(\Rightarrow C\%_{\left(CH_3COO\right)_2Fe}=\dfrac{0,1.174}{125,4}.100\%\approx13,88\%\)

Ta có: \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)

PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)

____0,1______0,2_____0,1____0,1 (mol)

a, \(C_{M_{HCl}}=\dfrac{0,2}{0,15}=\dfrac{4}{3}\left(M\right)\)

\(V_{H_2}=0,1.22,4=2,24\left(l\right)\)

b, \(FeCl_2+2NaOH\rightarrow2NaCl+Fe\left(OH\right)_2\)

Theo PT: \(n_{NaOH}=2n_{FeCl_2}=0,2\left(mol\right)\)

\(\Rightarrow V_{NaOH}=\dfrac{0,2}{2}=0,1\left(l\right)\)

`Zn + H_2 SO_4 -> ZnSO_4 + H_2`

`0,25`     `0,25`                             `0,25`      `(mol)`

`n_[Zn]=[16,25]/65=0,25(mol)`

`a)V_[H_2]=0,25.22,4=5,6(l)`

`b)C_[M_[H_2 SO_4]]=[0,25]/[0,3]~~0,8(M)`

`c)`

`H_2 + 3Fe_2 O_3` $\xrightarrow{t^o}$ `2Fe_3 O_4 + H_2 O`

`1/15`         `0,2`               `2/15`                          `(mol)`

`n_[Fe_2 O_3]=32/160=0,2(mol)`

Ta có:`[0,25]/1 > [0,2]/3`

   `=>H_2` dư

`=>m_[Fe_3 O_4]=2/15 . 232~~30,93(g)`

Vậy đáp án câu c là bao nhiu vây ak

\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\\a, PTHH:Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ b,n_{H_2}=n_{H_2SO_4}=n_{Fe}=0,2\left(mol\right)\\ V_{H_2\left(đkc\right)}=0,2.24,79=4,958\left(l\right)\\ c,C_{MddH_2SO_4}=\dfrac{0,2}{0,4}=0,5\left(M\right)\)

a) n_HCl = 0,25.0,2 = 0,05 (mol)

PTHH: Mg + 2HCl --> MgCl₂ + H₂

                     0,05-->0,025->0,025

=> V_H2 = 0,025.22,4 = 0,56 (l)

b) \(C_{M\left(MgCl_2\right)}=\dfrac{0,025}{0,25}=0,1M\)