Cho 20 lit hỗn hợp khí methane và ethylen đi qua bình đựng 200 ml dd brom thu được
1,88 gam dibromoethane
a. Viết PTHH?
b. Tính thể tích mỗi khí trong hỗn hợp?
c. Tính thành phần trăm theo thể tích mỗi khí trong hỗn hợp?
d. Tính nồng độ dd brom cần dùng?
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a) \(n_{C_2H_4Br_2}=\dfrac{37,6}{188}=0,2\left(mol\right)\)
PTHH: C2H4 + Br2 ---> C2H4Br2
0,2<---0,2<------0,2
b) \(\left\{{}\begin{matrix}V_{C_2H_4}=0,2.24,79=4,958\left(l\right)\\V_{CH_4}=20-4,958=15,042\left(l\right)\end{matrix}\right.\)
c) \(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{4,958}{20}.100\%=24,79\%\\\%V_{CH_4}=100\%-24,79\%=75,21\%\end{matrix}\right.\)
d) \(V_{\text{dd}Br_2}=\dfrac{0,2}{0,2}=1\left(l\right)\)
a, \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
b, \(n_{C_2H_4Br_2}=\dfrac{37,6}{188}=0,2\left(mol\right)\)
\(n_{C_2H_4}=n_{C_2H_4Br_2}=0,2\left(mol\right)\Rightarrow V_{C_2H_4}=0,2.22,4=4,48\left(l\right)\)
\(\Rightarrow V_{CH_4}=20-4,48=15,52\left(l\right)\)
c, \(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{4,48}{20}.100\%=22,4\%\\\%V_{CH_4}=77,6\%\end{matrix}\right.\)
d, \(n_{Br_2}=n_{C_2H_4Br_2}=0,2\left(mol\right)\Rightarrow V_{ddBr_2}=\dfrac{0,2}{0,2}=1\left(l\right)\)
\(n_{Br_2}=\dfrac{4}{160}=0,025\left(mol\right);n_{hh}=\dfrac{2,8}{22,4}=0,125\left(mol\right)\)
PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
0,025<-0,125
\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,025}{0,125}.100\%=20\%\\\%V_{CH_4}=100\%-20\%=80\%\end{matrix}\right.\)
a)
\(n_{Br_2}=\dfrac{8}{160}=0,05\left(mol\right)\)
PTHH: C2H4 + Br2 --> C2H4Br2
0,05<--0,05
=> \(V_{C_2H_4}=0,05.22,4=1,12\left(l\right)\)
=> \(V_{CH_4}=4,48-1,12=3,36\left(l\right)\)
b) \(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{1,12}{4,48}.100\%=25\%\\\%V_{CH_4}=\dfrac{3,36}{4,48}.100\%=75\%\end{matrix}\right.\)
a) \(C_2H_4 + Br_2 \to C_2H_4Br_2\)
b)
\(n_{C_2H_4} = n_{Br_2} = \dfrac{5,6}{160} = 0,035(mol)\\ \%V_{C_2H_4} = \dfrac{0,035.22,4}{0,86}.100\% = 91,16\%\\ \%V_{CH_4} = 100\% - 91,16\% = 8,84\%\)
a)
Khí thoát ra: CH4
\(\%V_{CH_4} = \dfrac{6,72}{16,8}.100\% = 40\%\\ \%V_{C_2H_4} = 100\% - 40\% = 60\%\)
b)
\(n_{C_2H_4} = \dfrac{16,8-6,72}{22,4} = 0,45(mol)\\ C_2H_4 + Br_2 \to C_2H_4Br_2\\ n_{Br_2} = n_{C_2H_4} = 0,45(mol)\\ \Rightarrow C_{M_{Br_2}} = \dfrac{0,45}{2} = 0,225M\\ c) n_{C_2H_4Br_2} = n_{C_2H_4} = 0,45(mol)\\ \Rightarrow n_{C_2H_4Br_2} = 0,45.188 = 84,6(gam)\)
Bài 4:
a) n(hỗn hợp khí)= 16,8/22,4=0,75(mol)
- Khí thoát ra là khí CH4.
=> nCH4=6,72/22,4=0,3(mol)
nC2H4=0,75-0,3=0,45(mol)
- Số mol tỉ lệ thuận với thể tích.
%V(CH4)=%nCH4= (0,3/0,75).100=40%
=> %V(C2H4)=100% - 40%=60%
b) PTHH: C2H4 + Br2 -> C2H4Br2
nC2H4Br2= nBr2=nC2H4=0,45(mol)
=>VddBr2= 0,45/2=0,225(l)
c) mC2H4Br2=0,45. 188= 84,6(g)
a, \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
b, \(n_{C_2H_4Br_2}=\dfrac{1,88}{188}=0,01\left(mol\right)\)
Theo PT: \(n_{C_2H_4}=n_{C_2H_4Br_2}=0,01\left(mol\right)\Rightarrow V_{C_2H_4}=0,01.22,4=0,224\left(l\right)\)
\(\Rightarrow V_{CH_4}=20-0,224=19,776\left(l\right)\)
c, \(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,224}{20}.100\%=1,12\%\\\%V_{CH_4}=98,88\%\end{matrix}\right.\)
d, \(n_{Br_2}=n_{C_2H_4Br_2}=0,01\left(mol\right)\Rightarrow C_{M_{Br_2}}=\dfrac{0,01}{0,2}=0,05\left(M\right)\)