5/ Cho 16,8g iron tác dụng với 196g dung dịch H2SO4 20%.
a) Tính thể tích khí bay ra (đkc).
b) Tính nồng độ % của các chất trong dung dịch sau phản ứng.
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\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
1 1 1 1
0,3 0,3 0,3 0,3
\(n_{Mg}=\dfrac{7,2}{24}=0,3\left(mol\right)\)
a). \(n_{H2}=\dfrac{0,3.1}{1}=0,3\left(mol\right)\)
⇒\(V_{H2}=n.22,4=0,3.22,4=6,72\left(l\right)\)
b). \(80ml=0,08l\)
\(n_{H2SO4}=\dfrac{0,3.1}{1}=0,3\left(mol\right)\)
→\(C_M=\dfrac{n}{V}=\dfrac{0,3}{0,08}=3,75\left(M\right)\)
c). \(n_{MgSO4}=\dfrac{0,3.1}{1}=0,3\left(mol\right)\)
\(V_{MgSO4}=n.22,4=0,3.22,4=6,72\left(l\right)\)
→\(C_M=\dfrac{n}{V}=\dfrac{0,3}{6,72}=0,04\left(M\right)\)
d). \(MgSO_4+Ba\left(OH\right)_2\rightarrow Mg\left(OH\right)_2+BaSO_4\downarrow\)
1 1 1 1
0,3 0,3 0,3
\(n_{BaSO4\uparrow}=\dfrac{0,3.1}{1}\)=0,3(mol)
→\(m_{BaSO4\downarrow}=n.M=0,3.233=69,9\left(g\right)\)
\(n_{Ba\left(OH\right)_2}=\dfrac{0,3.1}{1}\)=0,3(mol)
\(\rightarrow V_{ddBa\left(OH\right)_2}=\dfrac{n}{C_M}=\dfrac{0,3}{1,6}=0,1875\left(l\right)\)
mH2SO4=9,8g=>nH2SO4=0,1mol
nFe=0,15mol
PTHH: Fe+H2SO4=> FeSO4+H2
0,15:0,1 => n Fe dư theo N H2SO4
p/ư: 0,1<-0,1-------->0,1--->0,1
=> V H2=0,1.22,4=2,24ml
mFeSO4=0,1.152=15,2g
mdd FeSO4= 8,4+49-0,1.2=57,2g
( theo định luật bảo toàn khối lượng)
=> C%FeSO4=\(\frac{15,2}{57,2}.100=26,6\%\)
a/ \(n_{KOH}=0,2.1=0,2\left(mol\right);n_{H_2SO_4}=0,3.1=0,3\left(mol\right)\)
PTHH: 2KOH + H2SO4 → K2SO4 + 2H2O
Mol: 0,2 0,1 0,1
Ta có: \(\dfrac{0,2}{2}< \dfrac{0,3}{1}\) ⇒ KOH hết, H2SO4 dư
b/ \(m_{H_2SO_4dư}=\left(0,3-0,1\right).98=19,6\left(g\right)\)
c/ Vdd sau pứ = 0,2 + 0,3 = 0,5 (l)
d/ \(C_{M_{ddK_2SO_4}}=\dfrac{0,1}{0,5}=0,2M\)
\(C_{M_{ddH_2SO_4dư}}=\dfrac{0,3-0,1}{0,5}=0,4M\)
\(a,PTHH:Na_2CO_3+2HCl\rightarrow2NaCl+H_2O+CO_2\uparrow\\ b,n_{Na_2CO_3}=\dfrac{15,9}{106}=0,15\left(mol\right)\\ \Rightarrow n_{HCl}=0,3\left(mol\right)\\ \Rightarrow m_{CT_{HCl}}=0,3\cdot36,5=10,95\left(g\right)\\ \Rightarrow C\%_{HCl}=\dfrac{10,95}{200}\cdot100\%=5,475\%\\ c,n_{CO_2}=0,15\left(mol\right)\\ \Rightarrow V_{CO_2\left(đkc\right)}=0,15\cdot24,79=3,7185\left(l\right)\\ d,m_{CO_2}=0,15\cdot44=6,6\left(g\right)\\ n_{NaCl}=0,3\left(mol\right);n_{H_2O}=0,15\left(mol\right)\\ \Rightarrow\left\{{}\begin{matrix}m_{CT_{NaCl}}=0,3\cdot58,5=17,55\left(g\right)\\m_{H_2O}=0,15\cdot18=2,7\left(g\right)\end{matrix}\right.\\ m_{dd_{NaCl}}=15,9+200-2,7-6,6=206,6\left(g\right)\\ \Rightarrow C\%_{NaCl}=\dfrac{17,55}{206,6}\cdot100\%\approx8,49\%\)
\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
Pt : \(Fe+H_2SO_4\rightarrow FeSO_4+H_2|\)
1 1 1 1
0,1 0,1 0,1
a) \(n_{H2SO4}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
\(V_{ddH2SO4}=\dfrac{0,1}{2}=0,05\left(l\right)\)
b) \(n_{FeSO4}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)
\(C_{M_{FeSO4}}=\dfrac{0,1}{0,05}=2\left(M\right)\)
Chúc bạn học tốt
Ta có: \(n_{Mg}=\dfrac{9,6}{24}=0,4\left(mol\right)\)
a. PTHH: Mg + H2SO4 ---> MgSO4 + H2↑
Theo PT: \(n_{H_2}=n_{Mg}=0,4\left(mol\right)\)
=> \(V_{H_2}=0,4.22,4=8,96\left(lít\right)\)
b. Theo PT: \(n_{H_2SO_4}=n_{Mg}=0,4\left(mol\right)\)
=> \(m_{H_2SO_4}=0,4.98=39,2\left(g\right)\)
Ta có: \(C_{\%_{H_2SO_4}}=\dfrac{39,2}{m_{dd_{H_2SO_4}}}.100\%=10\%\)
=> \(m_{dd_{H_2SO_4}}=392\left(g\right)\)
c. Ta có: \(m_{H_2}=0,4.2=0,8\left(g\right)\)
=> \(m_{dd_{MgSO_4}}=9,6+392-0,8=400,8\left(g\right)\)
Theo PT: \(n_{MgSO_4}=n_{Mg}=0,4\left(mol\right)\)
=> \(m_{MgSO_4}=0,4.120=48\left(g\right)\)
=> \(C_{\%_{MgSO_4}}=\dfrac{48}{400,8}.100\%=11,98\%\)
Câu 1
\(a)PTHH:Mg+2HCl\rightarrow MgCl_2+H_2\\
b)200ml=0,2l\\
n_{HCl}=0,2.1=0,2mol\\
n_{H_2}=n_{MgCl_2}=\dfrac{1}{2}n_{H_2}=\dfrac{1}{2}\cdot0,2=0,1mol\\
V_{H_2}=0,1.24,79=2,479l\\
c)C_{M_{MgCl_2}}=\dfrac{0,1}{0,2}=0,5M\)
\(a)n_{Fe}=\dfrac{16,8}{56}=0,3mo\\ n_{H_2SO_4}=\dfrac{196.20}{100.98}=0,4mol\\ Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ \Rightarrow\dfrac{0,3}{1}< \dfrac{0,4}{1}\Rightarrow H_2SO_4.dư\\ n_{Fe}=n_{H_2SO_4}=n_{FeSO_4}=n_{H_2}=0,3mol\\ V_{H_2\left(đkc\right)}=0,3.24,79=7,437l\\ b)C_{\%FeSO_4}=\dfrac{0,2.152}{16,8+196-0,3.2}\cdot100=14,32\%\\ C_{\%H_2SO_4}=\dfrac{\left(0,4-0,3\right).98}{16,8+196-0,3.2}\cdot100=4,62\%\)