a, Zn + 2HCl -> ZnCl₂ + H₂

H₂ + CuO -> Cu + H₂O

b, Zn ⁰   -> Zn⁺² +2e

0,05           ->      0,1

Cu⁺²  + 2e -> Cu⁰ 

            0,1   -> 0,05

• khối lượng Cu được tạo ra : m = 0,05 x 64 = 3,2 (g)
• Chất khử : kẽm
• Chất oxi hóa : đồng
• Do H⁺  sau phản ứng vẫn là H⁺ nên không tính

Zn+2HCl->ZnCl2+H2

0,05--------------------0,05

CuO+H2-to>Cu+H2O

          0,05----0,05

n Zn=\(\dfrac{3,25}{65}=0,05mol\)

=>n CuO=\(\dfrac{6}{80}=0,075mol\)

=>CuO dư

=>m Cu=0,05.64=3,2g

=>m CuO dư=0,025.80=2g

\(a,PTHH:\\ Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\left(1\right)\\ CuO+H_2\underrightarrow{t^o}Cu+H_2O\left(2\right)\\ b,n_{Zn}=\dfrac{3,25}{65}=0,05\left(mol\right)\\ Theo.pt\left(1\right):n_{H_2}=n_{Zn}=0,05\left(mol\right)\\ n_{CuO}=\dfrac{6}{80}=0,075\left(mol\right)\\ LTL.pt\left(2\right):0,075>0,05\Rightarrow CuO,dư\\ Theo.pt\left(2\right):n_{Cu}=n_{CuO\left(pư\right)}=n_{H_2}=0,05\left(mol\right)\\ m_{Cu}=0,05.64=3,2\left(g\right)\\ c,m_{CuO\left(dư\right)}=\left(0,075-0,05\right).80=2\left(g\right)\)

nMg = 4.8/24 = 0.2 (mol) 

Mg + 2HCl => MgCl2 + H2 

0.2.................................0.2

CuO + H2 -to-> Cu + H2O 

...........0.2..........0.2

mCu = 0.2*64 = 12.8 (g) 

a) PTHH: Mg +  2HCl -> MgCl2 + H2

0,2____________0,4___0,2___0,2(mol)

CuO + H2 -to-> Cu + H2O

0,2___0,2____0,2(mol)

b) =>mCu=0,2.64=12,8(g)

a) nAl=0,2(mol)

PTHH: 2 Al + 6 HCl ->  2 AlCl3 +  3 H2

H2 + CuO -to-> Cu + H2O

nAlCl3= nAl= 0,2(mol)

=> mAlCl3= 133,5. 0,2= 26,7(g)

b) nCu= nH2= 3/2 . 0,2=0,3(mol)

=> mCu= 0,3.64=19,2(g)

(Qua phản ứng nghe kì á, chắc tạo thành chứ ha)

<3

a ) Zn + 2HCl \(\rightarrow\)ZnCl₂ + H₂

H₂ + CuO \(\rightarrow^{t^o}\)Cu + H₂O

b ) n_Zn = \(\dfrac{3,25}{65}\)= 0,05 ( mol )

\(\Rightarrow\)\(n_{H_2}\)= n_Zn = 0,05 ( mol )

\(\Rightarrow\)n_Cu = \(n_{H_2}\)=0,05 ( mol )

\(\Rightarrow\)m_Cu = n x M = 0,05 x 64 =3,2 ( g )

Chất khử là : H₂

Chất oxi hóa là CuO

a) PT1: Zn + 2HCl -> ZnCl₂ + H₂\(\uparrow\)

PT2: CuO + H₂ -t⁰-> Cu + H₂O

b) n_Zn=m/M=3,25/65=0,05 (mol)

Từ PT1: n_Zn = n_H2=0,05 (mol)

lại có: n_H2 =n_Cu=0,05 (mol) ( PT2)

=> m_Cu=n.M=0,05.64=3,2(gam)

Chất khử : H₂

Chất oxi hóa: CuO

a) 

b) 

Theo phương trình : 

c) Chất rắn : 

CuO dư : 

a)\(n_{Al}=\dfrac{5,4}{27}=0,2mol\)

\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)

0,2         0,3             0,1              0,3

b)\(V_{H_2}=0,3\cdot22,4=6,72l\)

c)\(n_{CuO}=\dfrac{32}{80}=0,4mol\)

\(CuO+H_2\rightarrow Cu+H_2O\)

0,4       0,3       0,3

\(m_{Cu}=0,3\cdot64=19,2g\)

nAl = 5.4/27 = 0.2 (mol) 

2Al + 6HCl => 2AlCl3 + 3H2 

0.2.......0.6......................0.3

CM HCl = 0.6 / 0.4 = 1.5 (M) 

nCuO = 32/80 = 0.4 (mol) 

CuO + H2 -to-> Cu + H2O 

0.2.......0.2..........0.2 

Chất rắn : 0.2 (mol) CuO dư , 0.2 (mol) Cu 

%CuO =\(\dfrac{0,2.80}{0,2.80+0,2.64}\) 100% = 55.56%

%Cu = 44.44%

a) \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

b) \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)

Theo phương trình : \(n_{H_2}=\dfrac{3}{2}n_{Al}=0,3\left(mol\right)\)

\(\rightarrow V_{H_2}\left(đktc\right)=0,3.22,4=6,72\left(l\right)\)

c) Chất rắn : \(0,2\left(mol\right)\)

CuO dư : \(0,2\left(mol\right)Cu\)

\(\%CuO=\dfrac{0,2.80}{\left(0,2.80+0,2.64\right)}.100=55,56\%\)

\(\%Cu=44,44\%\)

\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\)

PTHH: 2Al + 6HCl ---> 2AlCl₃ + 3H₂

           0,1                                    0,15

=> V_H2 = 0,15.22,4 = 3,36 (l)

\(n_{CuO}=\dfrac{32}{80}=0,4\left(mol\right)\)

PTHH: CuO + H₂ --t^o--> Cu + H₂O

LTL: \(0,4>0,15\rightarrow\) CuO dư

Theo pthh: \(n_{CuO\left(pư\right)}=n_{Cu}=n_{H_2}=0,15\left(mol\right)\)

\(\rightarrow\left\{{}\begin{matrix}\%m_{Cu}=\dfrac{0,15.64}{0,15.64+\left(0,4-0,15\right).80}=32,43\%\\\%m_{CuO}=100\%-32,43\%=67,57\%\end{matrix}\right.\)

a. \(2Al+6HCl\rightarrow2AlCl_3+3H_2\left(1\right)\)

b. \(n_{Al}=\frac{m}{M}=\frac{2,7}{27}=0,1mol\)

Theo phương trình `(1)` \(n_{H_2}=\frac{3}{2}.n_{Al}=\frac{3}{2}.0,1=0,15mol\)

\(\rightarrow V_{H_2\left(ĐKTC\right)}=n.22,4=0,15.22,4=3,36l\)

c. \(CuO+H_2\rightarrow^{t^o}Cu+H_2O\left(2\right)\)

\(n_{CuO}=\frac{m}{M}=\frac{32}{80}=0,4mol\)

Tỷ lệ \(\frac{0,4}{1}>\frac{0,15}{1}\)

`->CuO` dư

Theo phương trình `(2)` \(n_{Cu}=n_{H_2}=0,15mol\)

\(n_{CuO\left(pứ\right)}=n_{H_2}=0,15mol\)

\(\rightarrow n_{CuO\left(dư\right)}=0,4-0,15=0,25mol\)

\(m\left(g\right)\text{ chất rắn }\hept{\begin{cases}CuO_{dư}=0,25mol\\Cu=0,15mol\end{cases}}\)

\(\rightarrow m=0,15.64+0,25.80=29,6g\)

\(\%m_{CuO\left(dư\right)}=\frac{0,25.80.100}{29,6}\approx67,6\%\)

\(\%m_{Cu}=100\%-67,6\%=32,4\%\)

2Al+6HCl->2AlCl3+3H2

          1,2------------------0,6 mol

H2+CuO->Cu+H2O

        0,4----0,4

m HCl=43,8=>n HCl=\(\dfrac{43,8}{36,5}\)=1,2 mol

=>VH2=0,6.22,4=13,44l

b)n CuO=\(\dfrac{32}{80}\)=0,4 mol

=>H2 dư

=>m=m Cu=0,4.64=25,6g

=>%mCu=100%

cái dấu --- là sao v ạ