câu hỏi của bài 2 là j z bn?

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k bạn

Đặt: \(\left\{{}\begin{matrix}x=n_{Fe}\left(mol\right)\\y=n_{Al}\left(mol\right)\end{matrix}\right.\)

\(\sum m_{hh}=11\left(g\right)\Rightarrow56x+27y=11\left(1\right)\)

\(PTHH:Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\\ \left(mol\right)....x\rightarrow..2x........x......x\\ PTHH:2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\\ \left(mol\right)....y\rightarrow..3y.........y......1,5y\)

\(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ \Rightarrow x+1,5y=0,4\left(2\right)\)

\(\xrightarrow[\left(2\right)]{\left(1\right)}\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)

a) \(\%m_{Fe}=\dfrac{56.0,1}{11}=51\%\)

\(\rightarrow\%m_{Al}=49\%\)

b) \(\sum m_{ctHCl}=\left(2.0,1+3.0,2\right).36,5=29,2\left(g\right)\)

\(m_{ddHCl}=\dfrac{29,2.100\%}{10\%}=292\left(g\right)\)

c) \(m_{H_2\uparrow}=\left(1.0,1+1,5.0,2\right).2=0,8\left(g\right)\)

\(m_{ddsaupu}=m_{hh}+m_{ddHCl}-m_{H_2\uparrow}=11+292-0,8=302,2\left(g\right)\)

\(C\%_{FeCl_2}=\dfrac{0,1.127}{302,2}.100=4,2\%\\ C\%_{AlCl_3}=\dfrac{0,2.133,5}{302,2}.100=8,8\%\)

Đặt: 

a) 

b) 

c) 

C_H2SO4=1M nha tính vt nhầm đó

\(a)n_{H_2}=\dfrac{8,96}{22,4}=0,4mol\\ n_{Fe}=a;n_{Al}=b\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

\(\Rightarrow\left\{{}\begin{matrix}56a+27b=11\\a+1,5b=0,4\end{matrix}\right.\\ \Rightarrow a=0,1;b=0,2\)

\(\%m_{Fe}=\dfrac{0,1.56}{11}\cdot100=50,91\%\\ \%m_{Al}=100-50,91=49,09\%\)

\(b)Fe+2HCl\rightarrow FeCl_2+H_2\)

0,1            0,2          0,1          0,1

\(2Al+6HCl\rightarrow2AlCl_2+3H_2\)

0,2          0,6           0,2            0,3

\(m_{HCl}=\dfrac{\left(0,2+0,6\right).36,5}{9,125}\cdot100=320g\)       

\(c)m_{dd}=320+11-0,1.2-0,3.2=308,2g\)

\(C_{\%FeCl_2}=\dfrac{0,1.127}{308,2}\cdot100=4,12\%\\ C_{\%AlCl_3}=\dfrac{0,2.133,5}{308,2}\cdot100=8,66\%\)

\(Đặt:n_{Fe}=a\left(mol\right);n_{Al}=b\left(mol\right)\left(a,b>0\right)\\ Kim.loại.còn.lại.sau.p.ứ:Cu\\ n_{Cu}=\dfrac{25,4}{64}=0,4\left(mol\right)\\ a,PTHH:Fe+CuSO_4\rightarrow FeSO_4+Cu\\ 2Al+3CuSO_4\rightarrow Al_2\left(SO_4\right)_3+3Cu\\ \Rightarrow\left\{{}\begin{matrix}56a+27b=11\\a+1,5b=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,2\end{matrix}\right.\\b, \%m_{Fe}=\dfrac{0,1.56}{11}.100\approx50,909\%\\ \%m_{Cu}\approx100\%-50,909\%\approx49,091\%\\ c,V_{ddsau}=V_{ddCuSO_4}=0,2\left(l\right)\\ C_{MddFeSO_4}=\dfrac{0,1}{0,2}=0,5\left(M\right);C_{MddAl_2\left(SO_4\right)_3}=\dfrac{0,2:2}{0,2}=0,5\left(M\right)\\ d,C_{MddCuSO_4}=\dfrac{a+1,5b}{0,2}=2\left(M\right)\)

a) \(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\left(1dm^3=1l\right)\)

PTHH: 2Al + 3H₂SO₄ → Al₂(SO₄)₃ + 3H₂

Mol:      x                                                1,5x

PTHH: Mg + H₂SO₄ → MgSO₄ + H₂

Mol:      y                                             y

Ta có: \(\left\{{}\begin{matrix}27x+24y=7,8\\1,5x+y=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)

\(\%m_{Al}=\dfrac{0,2.27.100\%}{7,8}=69,23\%;\%m_{Mg}=100-69,23=30,77\%\)

b) 

PTHH: 2Al + 3H₂SO₄ → Al₂(SO₄)₃ + 3H₂

Mol:      0,2         0,3              0,1

PTHH: Mg + H₂SO₄ → MgSO₄ + H₂

Mol:     0,1        0,1           0,1

 \(V_{ddH_2SO_4}=\dfrac{0,3+0,1}{2}=0,2\left(l\right)=200\left(ml\right)\)

 \(\Rightarrow m_{ddH_2SO_4}=1,12.200=224\left(g\right)\)

c) \(C_{M_{ddAl_2\left(SO_4\right)_3}}=\dfrac{0,1}{0,2}=0,5M\)

   \(C_{M_{ddMgSO_4}}=\dfrac{0,1}{0,2}=0,5M\)

\(a)2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ b)n_{H_2}=\dfrac{5,6}{22,4}=0,25mol\\ n_{Al}=a;n_{Fe}=b\\ \left\{{}\begin{matrix}3a+b=0,25\\27a+56b=8,3\end{matrix}\right.\\ a=\dfrac{19}{470};b=\dfrac{121}{940}\\ \%m_{Al}=\dfrac{\dfrac{19}{470}\cdot27}{8,3}\cdot100=13,15\%\\ \%m_{Fe}=100-13,15=86,85\%\\ c)n_{HCl}=3\cdot\dfrac{19}{470}+2\cdot\dfrac{121}{940}=\dfrac{89}{235}mol\\ m_{ddHCl=}=\dfrac{\dfrac{89}{235}\cdot36,5}{7,3}\cdot100=189g\\ d)n_{AlCl_3}=n_{Al}=\dfrac{19}{470}mol\\ n_{Fe}=n_{FeCl_2}=\dfrac{121}{940}mol\)

\(m_{dd}=8,3+189-0,25.2=196,8g\\ C_{\%AlCl_3}=\dfrac{\dfrac{19}{470}\cdot133,8}{196,8}\cdot100=2,8\%\\ C_{\%FeCl_2}=\dfrac{\dfrac{121}{940}127}{196,8}\cdot100=8,3\%\)

\(a.2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ Đặt:\left\{{}\begin{matrix}n_{Al}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\\ Tacó:\left\{{}\begin{matrix}27x+56y=17,6\\1,5x+y=\dfrac{61}{112}\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}x=\dfrac{43}{190}\\y=\dfrac{2183}{10640}\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}\%m_{Al}=34,72\%\\m_{Fe}=65,28\%\end{matrix}\right.\\ b.BTNT\left(H\right):n_{H_2SO_4}=n_{H_2}=\dfrac{61}{112}\left(mol\right)\\ \Rightarrow m_{ddH_2SO_4}=\dfrac{\dfrac{61}{112}.98}{30\%}=177,92\left(g\right)\\ m_{ddsaupu}=17,6+177,92-\dfrac{61}{11,2}.2=194,43\left(g\right)\\Tacó:\left\{{}\begin{matrix}n_{AlCl_3}=\dfrac{43}{190}\\n_{FeCl_2}=\dfrac{2183}{10640}\end{matrix}\right. \\ C\%_{AlCl_3}=15,54\%;C\%_{FeCl_2}=13,4\%\)

\(a,\) Đặt \(\begin{cases} n_{Al}=x(mol)\\ n_{Fe}=y(mol \end{cases} \Rightarrow 27x+56y=17,6(1)\)

\(n_{H_2}=\dfrac{12,2}{22,4}=0,54(mol)\\ PTHH:2Al+3H_2SO_4\to Al_2(SO_4)_3+3H_2\\ Fe+H_2SO_4\to FeSO_4+H_2\\ \Rightarrow 1,5x+y=0,54(2)\\ (1)(2)\Rightarrow \begin{cases} x=0,22(mol)\\ y=0,21(mol) \end{cases} \Rightarrow \begin{cases} \%_{Al}=\dfrac{0,22.27}{17,6}.100\%=33,75\%\\ \%_{Fe}=100\%-33,75\%=66,25\% \end{cases}\\ b,\Sigma n_{H_2SO_4}=1,5x+y=0,54(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,54.98}{30\%}=176,4(g)\)

\(m_{H_2}=0,54.2=1,08(g)\\ \Rightarrow m_{dd{\text{ sau phản ứng}}}=17,6+176,4-1,08=192,92(g)\\ n_{Al_2(SO_4)_3}=\dfrac{1}{2}n_{Al}=0,11(mol);n_{FeSO_4}=n_{Fe}=0,21(mol)\\ \Sigma m_{\text{các chất sau phản ứng}}=m_{Al_2(SO_4)_3}+m_{FeSO_4}=0,11.342+0,21.152=69,54(g)\\ \Rightarrow C\%_{\text{chất sau phản ứng}}=\dfrac{69,54}{192,92}.100\%=36,05\%\)