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nCO2 = 0,03 mol → nC = nCO2 = 0,03 mol
nH2O = 0,06 mol → nH = 2nH2O = 0,12 mol
mN = 1,8.46,67% = 0,84 gam → nN = 0,84/14 = 0,06 mol
→ mO = mA - mC - mH - mN = 1,8 - 0,03.12 - 0,12 - 0,06.14 = 0,48 gam
→ nO = 0,48/16 = 0,03 mol
→ C : H : O : N = 0,03 : 0,12 : 0,03 : 0,06 = 1 : 4 : 1 : 2
→ CTPT có dạng (CH4ON2)n
Mà N trong 1 mol A ít hơn N trong 100 gam NH4NO3 nên ta có:
2n < 2.(100/80) → n < 1,25
→ n = 1
→ CTPT là CH4ON2 hay (NH2)2CO
Tên gọi của A là ure
\(a.M_{C_2H_6O}=12,2+2+16=46\left(đvC\right)\\ \%C=\dfrac{12.2}{46}.100=52,17\%\\ \%H=\dfrac{6}{46}.100=13,04\%\\ \%O=100-52,17-13,04=34,79\%\\ b.n_{CO_2}=\dfrac{6.6}{44}=0,15\left(mol\right)\\ BTNT\left(C\right):n_{C_2H_6O}.2=n_{CO_2}.1\\ \Rightarrow n_{C_2H_6O}=0,075\left(mol\right)\\ \Rightarrow m_{C_2H_6O}=0,075.46=3,45\left(g\right)\)
\(a,\%m_C=\dfrac{12.2}{12.2+6.1+16}.100\approx52,174\%\\ \%m_H=\dfrac{6.1}{12.2+6.1+16}.100\approx13,043\%\\ \%m_O=\dfrac{16}{12.2+6.1+16}.100\approx34,783\%\)
\(b,n_C=n_{CO_2}=\dfrac{6,6}{44}=0,15\left(mol\right)\\ \Rightarrow m_{C_2H_5OH}=\dfrac{n_C}{2}=\dfrac{0,15}{2}=0,075\left(mol\right)\\ \Rightarrow m_{C_2H_5OH}=0,075.46=3,45\left(g\right)\)
Ta có: MAl2O3 = 27.2+16.3 = 102 g/mol
%Al = 27.210227.2102.100% = 52,94%
%O = 16.310216.3102.100% = 47,06%
\(a.\%m_N=\dfrac{14.2}{\left(14+4.1\right).2+32+4.16}.100\approx21,212\%\\ \%m_H=\dfrac{4.2}{\left(14+4.1\right).2+32+4.16}.100\approx6,061\%\\ \%m_S=\dfrac{32}{\left(14+4.1\right).2+32+4.16}.100\approx24,242\%\\ \%m_O=\dfrac{4.16}{\left(14+4.1\right).2+32+4.16}.100\approx48,485\%\)
\(b.m_{N\left(20kg\right)}=20.\dfrac{2.14}{\left(14+4.1\right).2+32+4.16}.100\%\approx4,2424\left(kg\right)\)
*Trong hợp chất A:
\(\%X_1=75\%\)
\(\Rightarrow\dfrac{X_1}{X_1+4X_2}\cdot100\%=75\%\)
\(\Rightarrow100X_1=75X_1+300X_2\)
\(\Rightarrow25X_1=300X_2\Rightarrow X_1=12X_2\)
*Trong hợp chất B:
Gọi CTHH là \(A_aB_b\)
\(a:b=\dfrac{90\%}{X_1}:\dfrac{10\%}{X_2}=\dfrac{90\%}{12X_2}:\dfrac{10\%}{X_2}=3:4\)
Vậy CTHH là \(A_3B_4\)
\(\%K=\dfrac{m_K}{M_{K_2SO_3}}=\dfrac{78}{158}=49,36\%\\ \%S=\dfrac{m_S}{M_{K_2SO_3}}=\dfrac{32}{158}=20,25\%\\ \%O=100\%-\%K-\%S=100\%-49,36\%-20,25\%=30,39\%\)
a/ %mC = \(\frac{12}{12+16.2}.100\%=27,27\%\)
b/ %mAl = \(\frac{27.2}{27.2+16.3}.100\%=52,94\%\)
=> %mO = 100% - 52,94% = 47,06%
a/ %mC = \(\dfrac{12}{12+16.2}\).100%=27,27%
b/ %mAl = \(\dfrac{27.2}{27.2+16.3}\).100%=52,94%
%mO = 100% - 52,94% = 47,06%