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\(m_{CuO}=50.20\%=10\left(g\right)\)
\(n_{CuO}=\dfrac{10}{80}=0,125\left(mol\right)\)
\(m_{Fe_2O_3}=50-10=40\left(g\right)\)
\(n_{Fe_2O_3}=\dfrac{40}{160}=0,25\left(mol\right)\)
PTHH :
\(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
0,125 0,125 0,125
\(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
0,25 0,75 0,5
\(a,V_{H_2}=\left(0,75+0,125\right).22,4=19,6\left(l\right)\)
\(b,m_{Cu}=0,125.64=8\left(g\right)\)
\(m_{Fe}=0,5.56=28\left(g\right)\)
\(n_{Cu}=\dfrac{19,2}{64}=0,3mol\)
\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\)
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,3 0,3 ( mol )
\(m_{CuO}=0,3.80=24g\)
\(\Rightarrow m_{Fe_2O_3}=40-24=16g\)
\(\%m_{CuO}=\dfrac{24}{40}.100=60\%\)
\(\%m_{Fe_2O_3}=100\%-60\%=40\%\)
\(n_{Cu}=\dfrac{19,2}{64}=0,3mol\)
\(CuO+H_2\rightarrow Cu+H_2O\)
0,3 0,3
\(\Rightarrow n_{CuO}=0,3\Rightarrow m_{CuO}=24g\)
\(\Rightarrow m_{Fe_2O_3}=40-24=16g\Rightarrow n_{Fe_2O_3}=0,1mol\)
\(Fe_2O_3+3H_2\rightarrow2Fe+3H_2O\)
\(\%m_{CuO}=\dfrac{24}{40}\cdot100\%=60\%\)
\(\%m_{Fe_2O_3}=100\%-60\%=40\%\)
\(n_{Fe}=\dfrac{2,8}{56}=0,05mol\)
\(\Rightarrow m_{Cu}=6-2,8=3,2g\)\(\Rightarrow n_{Cu}=0,05mol\)
\(CuO+H_2\rightarrow Cu+H_2O\)
0,05 0,05
\(Fe_2O_3+3H_2\rightarrow2Fe+3H_2O\)
0,075 0,05
\(\Rightarrow\Sigma n_{H_2}=0,075+0,05=0,125mol\)
\(\Rightarrow V=0,125\cdot22,4=2,8l\)
PT: Fe2O3+3H2to→2Fe+3H2O
CuO+H2to→Cu+H2O
a, Ta có: mFe2O3=20.60%=12(g)
⇒nFe2O3=\(\dfrac{12}{160}\)=0,075(mol
mCuO=20−12=8(g
⇒nCuO=\(\dfrac{8}{80}\)=0,1(mol)
Theo pT:
nFe=2nFe2O3=0,15(mol)
nCu=nCuO=0,1(mol)
⇒mFe=0,15.56=8,4(g)
mCu=0,1.64=6,4(g)
b, Theo PT: nH2=3nFe2O3+nCuO=0,325(mol)
⇒VH2=0,325.22,4=7,28(l)
c. Zn+2HCl->ZnCl2+H2
0,65----------0,325
=>m HCl=0,65.36,5=23,725g
\(n_{Fe}=\dfrac{2,8}{56}=0,05\left(mol\right)\\ m_{Cu}=6-2,8=3,2\left(g\right)\\ n_{Cu}=\dfrac{3,2}{64}=0,05\left(mol\right)\\ CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\\ Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\\ n_{H_2}=\dfrac{3}{2}.n_{Fe}+n_{Cu}=\dfrac{3}{2}.0,05+0,05=0,125\left(mol\right)\\ \Rightarrow V_{H_2\left(đktc\right)}=0,125.22,4=2,8\left(l\right)\\ \Rightarrow D\)
Fe2O3+3H2-to>2Fe+3H2O
0,05-----0,15------0,1
CuO+H2-to>Cu+H2O
0,05---0,05-----0,05
ta có CuOchiếm 33,3%
=> m CuO=12.\(\dfrac{33,3}{100}\)= 4g
=>n CuO=\(\dfrac{4}{80}\)=0,05 mol
=>m Fe2O3=12-4=8g
->n Fe2O3=\(\dfrac{8}{160}\)=0,05 mol
=>VH2= 0,2.22,4=4,48l
=>m Y=0,1.56+0,05.64=8,8g