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1.\(n_{Zn}=\dfrac{13}{65}=0,2mol\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,2 0,2 ( mol )
\(V_{H_2}=0,2.22,4=4,48l\)
2.\(n_{CuO}=\dfrac{12}{80}=0,15mol\)
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,15 < 0,2 ( mol )
0,15 0,15 ( mol )
\(m_{Cu}=0,15.64=9,6g\)
a.b.c.\(n_{Zn}=\dfrac{m}{M}=\dfrac{13}{65}=0,2mol\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,2 0,2 0,2 ( mol )
\(m_{ZnCl_2}=n.M=0,2.136=27,2g\)
\(V_{H_2}=n.22,4=0,2.22,4=4,48l\)
d.\(n_{CuO}=\dfrac{m}{M}=\dfrac{32}{80}=0,4mol\)
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,4 > 0,2 ( mol )
0,2 0,2 0,2 ( mol )
\(m_{chất.rắn}=m_{CuO\left(dư\right)}+m_{Cu}=0,2.80+0,2.64=16+12,8=28,8g\)
\(\%m_{CuO}=\dfrac{16}{28,8}.100=55,55\%\)
\(\%m_{Cu}=100\%-55,55\%=44,45\%\)
a.\(n_{Zn}=\dfrac{m}{M}=\dfrac{23}{65}=0,35mol\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,35 0,35 ( mol )
\(V_{H_2}=n.22,4=0,35.22,4=7,84l\)
b.\(n_{CuO}=\dfrac{m}{M}=\dfrac{6}{80}=0,075mol\)
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,075 < 0,35 ( mol )
0,075 0,075 ( mol )
\(m_{Cu}=n.M=0,075.64=4,8g\)
a) \(n_{Mg}=\dfrac{4,8}{24}=0,2\left(mol\right)\)
PTHH: Mg + 2HCl --> MgCl2 + H2
0,2--------------------->0,2
=> VH2 = 0,2.22,4 = 4,48 (l)
b) \(n_{CuO}=\dfrac{24}{80}=0,3\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
Xét tỉ lệ: \(\dfrac{0,3}{1}>\dfrac{0,2}{1}\) => H2 hết, CuO dư
PTHH: CuO + H2 --to--> Cu + H2O
0,2<--0,2-------->0,2
=> mrắn sau pư = 24 - 0,2.80 + 0,2.64 = 20,8 (g)
c)
PTHH: RO + H2 --to--> R + H2O
0,2------>0,2
=> \(M_R=\dfrac{12,8}{0,2}=64\left(g/mol\right)\)
=> R là Cu
+) \(N_{Mg}\) = \(\dfrac{m}{M}\) = \(\dfrac{4,8}{24}\) = 0,2 mol
a) Mg + HCl -> \(MgCl_2\) + \(H_2\)
0,2 -> 0,2 (mol)
b) +) \(N_{CuO}\text{ }\)= \(\dfrac{m}{M}\) = \(\dfrac{24}{80}\) = 0,3 mol
+) \(H_2\) + CuO -> Cu + \(H_2O\)
+) Ta có: \(\dfrac{N_{H_2}}{1}\)= \(\dfrac{0,2}{1}\) < \(\dfrac{N_{CuO}}{1}\)= \(\dfrac{0,3}{1}\)
=> \(H_2\) hết. Tính toán theo \(N_{H_2}\)
+)\(H_2\) + CuO -> Cu + \(H_2O\)
Ban đầu: 0,2 0,3 0 0 }
P/ứng: 0,2 -> 0,2 -> 0,2 -> 0,2 } mol
Sau p/ư: 0 0,1 0,2 0,2 }
=> \(m_{Cu}\) = 12,8 gam .Thu được 2,8 gam Cu
\(a.n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\ Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{ZnCl_2}=n_{H_2}=n_{Zn}=0,2\left(mol\right)\\ m_{ZnCl_2}=0,2.136=27,2\left(g\right)\\ V_{H_2}=0,2.22,4=4,48\left(l\right)\\ b.n_{CuO}=\dfrac{12}{80}=0,15\left(mol\right)\\ CuO+H_2-^{t^o}\rightarrow Cu+H_2O\\ LTL:\dfrac{0,15}{1}< \dfrac{0,2}{1}\\ \Rightarrow H_2dưsauphảnứng\\ n_{Cu}=n_{H_2\left(pứ\right)}=n_{H_2O}=n_{CuO}=0,15\left(mol\right)\\ m_{Cu}=0,15.64=9,6\left(g\right)\\ m_{H_2\left(dư\right)}=\left(0,2-0,15\right).2=0,1\left(g\right)\\ m_{H_2O}=0,15.18=2,7\left(g\right)\)
\(n_{Cu}=\dfrac{12.8}{64}=0.2\left(mol\right)\)
\(CuO+H_2\underrightarrow{^{t^0}}Cu+H_2O\)
\(0.2......0.2.....0.2\)
\(V_{H_2}=0.2\cdot22.4=4.48\left(l\right)\)
\(m_{CuO}=0.2\cdot80=16\left(g\right)\)
nZn = 13/65 = 0,2 (mol)
PTHH: Zn + 2HCl -> ZnCl2 + H2
Mol: 0,2 ---> 0,4 ---> 0,2 ---> 0,2
mZnCl2 = 0,2 . 136 = 27,2 (g)
VH2 = 0,2 . 22,4 = 4,48 (l)
nCuO = 12/80 = 0,15 (mol)
PTHH: CuO + H2 -> (t°) Cu + H2O
LTL: 0,15 < 0,2 => H2 dư
nCuO (p/ư) = nCu = nH2O = nCuO = 0,15 (mol)
mCu = 0,15 . 64 = 9,6 (g)
mH2O = 0,15 . 18 = 2,7 (g)
mCuO (dư) = (0,2 - 0,15) . 80 = 4 (g)
a.b.
\(n_{Fe}=\dfrac{2,8}{56}=0,05mol\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,05 0,1 0,05 ( mol )
\(V_{H_2}=0,05.22,4=1,12l\)
\(m_{HCl}=0,1.36,5=3,65g\)
c.
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,05 0,05 ( mol )
\(m_{Cu}=0,05.64=3,2g\)
\(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\\ PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
(mol).......0,3........0,6.........0,3.......0,3
a) \(V_{H_2}=0,3.22,4=6,72\left(l\right)\)
b) \(m_{ZnCl_2}=0,3.136=40,8\left(g\right)\)
c) \(200ml=0,2l\)
\(C_{M_{HCl}}=\dfrac{0,6}{0,2}=3\left(M\right)\)
d) \(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)
\(PTHH:CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Ban đầu: 0,2......0,3
Phản ứng: 0,2....0,2.....0,2.....0,2
Dư:.....................0,1
Lập tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,3}{1}\left(0,2< 0,3\right)\)
\(\Rightarrow H_2\) dư