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PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)
Ta có: \(\left\{{}\begin{matrix}n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\\n_{HCl}=\dfrac{109,5\cdot10\%}{36,5}=0,3\left(mol\right)\end{matrix}\right.\)
Xét tỉ lệ: \(\dfrac{0,1}{1}< \dfrac{0,3}{2}\) \(\Rightarrow\) HCl còn dư, Magie p/ứ hết
\(\Rightarrow n_{Mg}=n_{MgCl_2}=n_{H_2}=0,1\left(mol\right)=n_{HCl\left(dư\right)}\)
\(\Rightarrow\left\{{}\begin{matrix}m_{MgCl_2}=0,1\cdot95=9,5\left(g\right)\\m_{HCl\left(dư\right)}=0,1\cdot36,5=3,65\left(g\right)\\m_{H_2}=0,1\cdot2=0,2\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd\left(saup/ứ\right)}=m_{Mg}+m_{ddHCl}-m_{H_2}=111,7\left(g\right)\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{MgCl_2}=\dfrac{9,5}{111,7}\cdot100\%\approx8,5\%\\C\%_{HCl\left(dư\right)}=\dfrac{3,65}{111,7}\cdot100\%\approx3,27\%\end{matrix}\right.\)
\(a.Mg+2HCl->MgCl_2+H_2\\ b.n_{Mg}=\dfrac{2,4}{24}=0,1mol\\ n_{HCl}=\dfrac{109,5.10\%}{36,5}=0,3mol\\ n_{Mg}:1< n_{HCl}:2\\ Mg:hết\\ m_{ddsau}=2,4+109,5-2.0,1=111,7g\\ C\%_{HCl\left(dư\right)}=\dfrac{36,5.0,1}{111,7}.100\%=3,27\%\\ C\%_{MgCl_2}=\dfrac{95.0,1}{111,7}.100\%=8,50\%\)
`a)PTPƯ: Zn + 2HCl -> ZnCl_2 + H_2↑`
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`b) n_[Zn] = 13 / 65 = 0,2 (mol)`
Theo `PTPƯ` có: `n_[HCl] = 2n_[Zn] = 2 . 0,2 = 0,4 (mol)`
`-> m_[dd HCl] = [ 0,4 . 36,5 ] / [ 7,3 ] . 100 = 200 (g)`
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`c)` Theo `PTPƯ` có: `n_[H_2] = n_[ZnCl_2] = n_[Zn] = 0,2 (mol)`
`-> C%_[ZnCl_2] = [ 0,2 . 136 ] / [ 13 + 200 - 0,2 . 2 ] . 100 ~~ 12,79 %`
Ta có: \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
_____0,2____0,4____0,2 (mol)
b, mZnCl2 = 0,2.136 = 27,2 (g)
c, \(V_{ddHCl}=\dfrac{0,4}{2}=0,2\left(l\right)\)
Bạn tham khảo nhé!
\(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\\ m_{HCl}=\dfrac{109,5\cdot10\%}{100\%}=10,95\left(g\right)\\ \Rightarrow n_{HCl}=\dfrac{10,95}{36,5}=0,3\left(mol\right)\\ a,PTHH:Mg+2HCl\rightarrow MgCl_2+H_2\\ \text{Vì }\dfrac{n_{Mg}}{1}< \dfrac{n_{HCl}}{2}\text{ nên sau p/ứ }HCl\text{ dư}\\ \Rightarrow n_{H_2}=0,1\left(mol\right)\\ \Rightarrow V_{H_2\left(đktc\right)}=0,1\cdot22,4=2,24\left(l\right)\)
\(b,n_{MgCl_2}=0,1\left(mol\right)\\ \Rightarrow m_{CT_{MgCl_2}}=0,1\cdot95=9,5\left(g\right)\\ m_{H_2}=0,1\cdot2=0,2\left(mol\right)\\ m_{dd_{MgCl_2}}=2,4+109,5-0,2=111,7\left(g\right)\\ \Rightarrow C\%_{MgCl_2}=\dfrac{9,5}{111,7}\cdot100\%\approx8,5\%\)
\(n_{HCl}=\dfrac{10\%.109,5}{36,5}=0,3\left(mol\right);n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\\ a,PTHH:Mg+2HCl\rightarrow MgCl_2+H_2\\ Vì:\dfrac{0,3}{2}>\dfrac{0,1}{1}\Rightarrow HCldư\\ n_{H_2}=n_{MgCl_2}=n_{Mg}=0,1\left(mol\right)\\ n_{HCl\left(p.ứ\right)}=2.0,1=0,2\left(mol\right)\Rightarrow n_{HCl\left(dư\right)}=0,3-0,2=0,1\left(mol\right)\\ V_{H_2\left(đkc\right)}=24,79.0,1=2,479\left(l\right)\\ b,ddA:HCl\left(dư\right),MgCl_2\\ m_{ddA}=2,4+109,5-0,1.2=111,7\left(g\right)\\ C\%_{ddHCl\left(dư\right)}=\dfrac{0,1.36,5}{111,7}.100\%\approx3,268\%;C\%_{ddMgCl_2}=\dfrac{0,1.95}{111,7}.100\%\approx8,505\%\)
\(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\\ m_{HCl}=\dfrac{100.18,25}{100}=18,25\left(g\right)\\
n_{HCl}=\dfrac{18,25}{36,5}=0,5\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,125 0,125 (mol )
\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(l\right)\\
\)
\(C\%=\dfrac{8,125}{8,125+18,25}.100\%=30,8\%\)
Bài 18:
Ta có: \(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\)
\(m_{HCl}=100.18,25\%=18,25\left(g\right)\Rightarrow n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)
a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
b, Xét tỉ lệ: \(\dfrac{0,125}{1}< \dfrac{0,5}{2}\), ta được HCl dư.
Theo PT: \(n_{H_2}=n_{Zn}=0,125\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(g\right)\)
\(m_{H_2}=0,125.2=0,25\left(g\right)\)
c, Theo PT: \(\left\{{}\begin{matrix}n_{ZnCl_2}=n_{Zn}=0,125\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{Zn}=0,25\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow n_{HCl\left(dư\right)}=0,25\left(mol\right)\)
Có: m dd sau pư = 8,125 + 100 - 0,25 = 107,875 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,125.136}{107,875}.100\%\approx15,76\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,25.36,5}{107,875}.100\%\approx8,46\%\end{matrix}\right.\)
Bạn tham khảo nhé!
Câu 1 :
\(n_{Mg}=\dfrac{8.4}{24}=0.35\left(mol\right)\)
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(0.35.......0.7.........0.35..........0.35\)
\(C\%_{HCl}=\dfrac{0.7\cdot36.5}{146}\cdot100\%=17.5\%\)
\(m_{\text{dung dịch sau phản ứng}}=8.4+146-0.35\cdot2=153.7\left(g\right)\)
\(C\%_{MgCl_2}=\dfrac{0.35\cdot95}{153.7}\cdot100\%=21.6\%\)
Câu 2 :
\(n_{CaCO_3}=\dfrac{10}{100}=0.1\left(mol\right)\)
\(n_{HCl}=\dfrac{114.1\cdot8\%}{36.5}=0.25\left(mol\right)\)
\(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)
\(1................2\)
\(0.1.............0.25\)
\(LTL:\dfrac{0.1}{1}< \dfrac{0.25}{2}\Rightarrow HCldư\)
\(m_{\text{dung dịch sau phản ứng}}=10+114.1-0.1\cdot44=119.7\left(g\right)\)
\(C\%_{HCl\left(dư\right)}=\dfrac{\left(0.25-0.2\right)\cdot36.5}{119.7}\cdot100\%=1.52\%\)
\(C\%_{CaCl_2}=\dfrac{0.2\cdot111}{119.7}\cdot100\%=18.54\%\)
Sửa đề : 109,5 ml $\to$ 109,5 gam
a) $Mg + 2HCl \to MgCl_2 + H_2$
b)
n Mg = 2,4/24 = 0,1(mol) ; n HCl = 109,5.10%/36,5 = 0,3(mol)
Ta thấy :
n Mg / 1 = 0,1 < n HCl /2 = 0,15 nên HCl dư
Theo PTHH :
n HCl pư = 2n Mg = 0,2(mol) => n HCl dư = 0,3- 0,2 = 0,1(mol)
n MgCl2 = n Mg = 0,1(mol)
Sau phản ứng :
m dd = m Mg + m HCl - m H2 = 2,4 + 109,5 -0,1.2 =111,7(gam)
Vậy :
C% MgCl2 = 0,1.95/111,7 .100% = 8,5%
C% HCl = 0,1.36,5/111,7 .100% = 3,27%