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nAl = 5.4 / 27 = 0.2 (mol)
2Al + 6HCl => 2AlCl3 + 3H2
0.2......0.6............0.2.......0.3
a) VH2 = 0.3 * 22.4 = 6.72 (l)
b) mAlCl3 = 0.2 * 133.5 = 26.7 (g)
c) VddHCl = 0.6 / 1.5 = 0.4 (l)
d) CMAlCl3 = 0.2 / 0.4 = 0.5 (M)
PTHH: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,6\left(mol\right)\\n_{AlCl_3}=0,2\left(mol\right)\\n_{H_2}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\\m_{AlCl_3}=0,2\cdot133,5=26,7\left(g\right)\\V_{HCl}=\dfrac{0,6}{1,5}=0,4\left(l\right)=400\left(ml\right)\\C_{M_{AlCl_3}}=\dfrac{0,2}{0,4}=0,5\left(M\right)\end{matrix}\right.\)
\(n_{H_2}=\dfrac{6.72}{22.4}=0.3\left(mol\right)\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
\(.........0.6............0.3\)
\(C_{M_{HCl}}=\dfrac{0.6}{0.3}=2\left(M\right)\)
\(n_{Fe_2O_3}=\dfrac{48}{160}=0.3\left(mol\right)\)
\(Fe_2O_3+3H_2\underrightarrow{^{t^0}}2Fe+3H_2O\)
\(1..............3\)
\(0.3..........0.3\)
\(LTL:\dfrac{0.3}{1}>\dfrac{0.3}{3}\Rightarrow Fe_2O_3dư\)
\(n_{Fe}=\dfrac{2}{3}n_{H_2}=\dfrac{2}{3}\cdot0.3=0.2\left(mol\right)\)
\(m_{Fe}=0.2\cdot56=11.2\left(g\right)\)
\(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\)
PTHH :
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
0,4 1,2 0,4 0,6
\(a,V_{H_2}=0,6.22,4=13,44\left(l\right)\)
\(b,m_{HCl}=1,2.36,5=43,8\left(g\right)\)
\(c,m_{AlCl_3}=133,5.0,4=53,4\left(g\right)\)
\(m_{ddHCl}=\dfrac{43,8.100}{10}=438\left(g\right)\)
\(m_{ddAlCl_3}=10,8+438-\left(0,6.2\right)=447,6\left(g\right)\)
\(C\%=\dfrac{53,8}{447,6}.100\%\approx12,02\%\)
\(n_{Fe}=\dfrac{22,4}{56}=0,4\) (mol) (1)
Phương trình hóa học :
Fe + 2HCl ---> FeCl2 + H2 (2)
Từ (1) và (2) ta có \(n_{FeCl_2}=n_{H_2}=0,4\) (mol) ; \(n_{HCl}=0,8\left(mol\right)\)
b) => \(m_{\text{muối}}=0,4.\left(56+35,5.2\right)=50.8\left(g\right)\)
c) \(V_{\text{khí}}=0,4.22,4=8,96\left(l\right)\)
d) \(m_{HCl}=0,8.36.5=29,2\left(g\right)\)
\(\Rightarrow C\%=\dfrac{29,2}{200}.100\%=14,6\%\)
\(n_{Zn}=\dfrac{26}{65}=0,4\left(mol\right)\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,4 0,8 0,4 0,4
\(a,V_{H_2}=0,4.22,4=8,96\left(l\right)\\ b,C\%_{HCl}=\dfrac{0,8.36,5}{150}.100\%=19,5\%\\ c,m_{\text{dd}}=26+150-\left(0,4.2\right)=175,2\left(g\right)\\ C\%_{ZnCl_2}=\dfrac{0,4.136}{175,2}.100\%=31\%\)
1)
a) Fe + 2HCl --> FeCl2 + H2
b) \(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
0,15->0,3--->0,15-->0,15
=> VH2 = 0,15.22,4 = 3,36 (l)
c) mdd sau pư = 8,4 + 250 - 0,15.2 = 258,1 (g)
=> \(C\%_{FeCl_2}=\dfrac{0,15.127}{258,1}.100\%=7,38\%\)
2)
a) Zn + 2HCl --> ZnCl2 + H2
b) \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
PTHH: Zn + 2HCl --> ZnCl2 + H2
0,2-->0,4---->0,2--->0,2
=> VH2 = 0,2.22,4 = 4,48 (l)
mZnCl2 = 0,2.136 = 27,2 (g)
c) \(C_{M\left(dd.HCl\right)}=\dfrac{0,4}{0,2}=2M\)
d)
PTHH: A + 2HCl --> ACl2 + H2
0,2<--0,4
=> \(M_A=\dfrac{4,8}{0,2}=24\left(g/mol\right)\)
=> A là Mg(Magie)
a, \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
____0,1_____0,2______0,1_____0,1 (mol)
\(V_{H_2}=0,1.24,79=2,479\left(l\right)\)
\(m_{ZnCl_2}=0,1.136=13,6\left(g\right)\)
b, \(C_{M_{HCl}}=\dfrac{0,2}{0,1}=1\left(M\right)\)
c, \(n_{CuO}=\dfrac{12}{80}=0,15\left(mol\right)\)
PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
Xét tỉ lệ: \(\dfrac{0,15}{1}>\dfrac{0,1}{1}\), ta được CuO dư.
Theo PT: \(n_{CuO\left(pư\right)}=n_{Cu}=n_{H_2}=0,1\left(mol\right)\Rightarrow n_{CuO\left(dư\right)}=0,05\left(mol\right)\)
⇒ m chất rắn = mCuO (dư) + mCu = 0,05.80 + 0,1.64 = 10,4 (g)
\(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{FeCl_2}=n_{H_2}=n_{Fe}=0,15\left(mol\right)\\ n_{HCl}=0,15.2=0,3\left(mol\right)\\ a,m_{FeCl_2}=127.0,15=19,05\left(g\right)\\ b,V_{H_2\left(đktc\right)}=0,15.22,4=3,36\left(l\right)\\ c,C_{MddHCl}=\dfrac{0,3}{0,02}=15\left(M\right)\)