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a. \(n_{Al_2O_3}=\dfrac{10,2}{102}=0,1\left(mol\right)\)
PTHH : Al2O3 + 6HCl -> 2AlCl3 + 3H2O
0,1 0,6 0,2 ( mol )
\(m_{HCl}=0,6.36,5=21,9\left(g\right)\)
\(m_{AlCl_3}=0,2.133,5=26,7\left(g\right)\)
b.
PTHH : 3O2 + 4Al -> 2Al2O3
0,15 0,1 ( mol)
\(V_{O_2}=0,15.22,4=3,36\left(l\right)\)
a. \(n_{Al_2O_3}=\dfrac{10,2}{102}=0,1\left(mol\right)\)
PTHH : Al2O3 + 3HCl -> 2AlCl3 + 3H2O
0,1 0,3 0,2 ( mol )
\(m_{HCl}=0,3.36,5=10,95\left(g\right)\)
\(m_{AlCl_3}=0,2.133,5=26,7\left(g\right)\)
b.
PTHH : 3O2 + 4Al -> 2Al2O3
0,15 0,1 ( mol)
\(V_{O_2}=0,15.22,4=3,36\left(l\right)\)
Gọi nAl = nFe = x (mol)
⇒ 27x + 56x = 8,3 ⇒ x = 0,1 (mol)
PT: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
a, Theo PT: \(n_{H_2SO_4}=\dfrac{3}{2}n_{Al}+n_{Fe}=0,25\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4}=0,25.98=24,5\left(g\right)\)
b, Theo PT: \(n_{H_2}=n_{H_2SO_4}=0,25\left(mol\right)\) \(\Rightarrow V_{H_2}=0,25.22,4=5,6\left(l\right)\)
\(\left\{{}\begin{matrix}n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=0,05\left(mol\right)\\n_{FeSO_4}=n_{Fe}=0,1\left(mol\right)\end{matrix}\right.\)
⇒ m muối = 0,05.342 + 0,1.152 = 32,3 (g)
nAl = 5.4 / 27 = 0.2 (mol)
2Al + 6HCl => 2AlCl3 + 3H2
0.2......0.6............0.2.......0.3
a) VH2 = 0.3 * 22.4 = 6.72 (l)
b) mAlCl3 = 0.2 * 133.5 = 26.7 (g)
c) VddHCl = 0.6 / 1.5 = 0.4 (l)
d) CMAlCl3 = 0.2 / 0.4 = 0.5 (M)
PTHH: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)
Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,6\left(mol\right)\\n_{AlCl_3}=0,2\left(mol\right)\\n_{H_2}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\\m_{AlCl_3}=0,2\cdot133,5=26,7\left(g\right)\\V_{HCl}=\dfrac{0,6}{1,5}=0,4\left(l\right)=400\left(ml\right)\\C_{M_{AlCl_3}}=\dfrac{0,2}{0,4}=0,5\left(M\right)\end{matrix}\right.\)
nH2O=0.2
nCuO=x,nAl2O3=y,nFeO=z
80x + 102y + 72z = 17.86
x + z =0.2
135x + 267y + 127z = 33.81
=> y=0.03 => mAl2O3=3.06g =>D
nAl = \(\frac{4,05}{27}=0,15mol\)
2Al + 6HCl ----> 2AlCl3 + 3 H2
0,15 0,45 0,15 0,225 (mol)
a) nHCl = 0,45 mol
=> mHCl = 0,45 . 36,5 = 16,425 g
b) nAlCl3 = 0,15 mol
=> mAlCl3 = 0,15 . 133,5 = 20,025 g
c) nH2 = 0,225 mol
=> mH2 = 0,225 . 2 = 0,45 g
=> VH2 = 0,225 . 22,4 = 5,04 lit
a) Gọi $n_{CO_2} = a(mol) ; n_{SO_2} = b(mol)$
Ta có :
$a + b = \dfrac{8,96}{22,4} = 0,4(mol)$
$\dfrac{44a + 64b}{a + b} = 27.2$
Suy ra : a = b = 0,2$
$V_{CO_2} = V_{SO_2} = 0,2.22,4 = 4,48(lít)$
b) Theo PTHH : $n_{K_2SO_3} = n_{SO_2} = 0,2(mol)$
$\Rightarrow m_{K_2SO_3} = 0,2.158 = 31,6(gam)$
Gọi $n_{K_2CO_3} = x(mol) ; n_{Na_2CO_3} = y(mol)$
$\Rightarrow 138x + 106y + 31,6 = 56(1)$
$n_{CO_2} = x + y = 0,2(2)$
Từ (1)(2) suy ra : x = y = 0,1
$m_{K_2CO_3} = 0,1.138 = 13,8(gam) ; m_{Na_2CO_3} = 0,1.106 = 10,6(gam)$
Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
\(n_{Al_2O_3}=\dfrac{10,2}{102}=0,1\left(mol\right)\)
PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)
a, Theo PT: \(n_{HCl}=3n_{Al}+6n_{Al_2O_3}=1,2\left(mol\right)\)
\(\Rightarrow m_{HCl}=1,2.36,5=43,8\left(g\right)\)
b, Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}=0,3\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,3.22,4=6,72\left(l\right)\)
\(n_{AlCl_3}=n_{Al}+2n_{Al_2O_3}=0,4\left(mol\right)\)
\(\Rightarrow m_{AlCl_3}=0,4.133,5=53,4\left(g\right)\)