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a, Ta có: 24nMg + 56nFe = 12,8 (1)
PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
Theo PT: \(n_{H_2}=n_{Mg}+n_{Fe}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Mg}=0,3\left(mol\right)\\n_{Fe}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Mg}=0,3.24=7,2\left(g\right)\\m_{Fe}=0,1.56=5,6\left(g\right)\end{matrix}\right.\)
b, \(n_{HCl}=2n_{H_2}=0,8\left(mol\right)\)
\(\Rightarrow V_{HCl}=\dfrac{0,8}{2}=0,4\left(l\right)\)
c, \(MgCl_2+2NaOH\rightarrow Mg\left(OH\right)_2+2NaCl\)
\(FeCl_2+2NaOH\rightarrow Fe\left(OH\right)_2+2NaCl\)
Theo PT: \(\left\{{}\begin{matrix}n_{Mg\left(OH\right)_2}=n_{MgCl_2}=n_{Mg}=0,3\left(mol\right)\\n_{Fe\left(OH\right)_2}=n_{FeCl_2}=n_{Fe}=0,1\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow m_{\downarrow}=0,3.58+0,1.90=26,4\left(g\right)\)
a. Số gam mỗi kim loại trong hỗn hợp ban đầu:
Mg: 9,6 gamFe: 22,4 gamb. Thể tích dung dịch HCl 2M đã phản ứng: 0,2 lít
c. Khối lượng kết tủa thu được khi dd A tác dụng với dung dịch NaOH dư là 0,4 gam.
------------------------------------đấy
Gọi \(n_{Fe}=x\left(mol\right)\)\(;n_{Zn}=y\left(mol\right)\)
\(n_{H_2}=\dfrac{6,72}{22,4}=0,3mol\)
Ta có: \(\left\{{}\begin{matrix}56x+65y=18,6\\2x+2y=2n_{H_2}=0,6\end{matrix}\right.\)\(\Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)
\(\%m_{Fe}=\dfrac{0,1\cdot56}{18,6}\cdot100\%=30,11\%\)
\(\%m_{Zn}=100\%-30,11\%=69,89\%\)
\(Fe+2HCl\rightarrow FeCl_2+H_2\)
0,1 0,2
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,2 0,4
\(n_{HCl}=0,2+0,4=0,6mol\)
\(C_M=\dfrac{n}{V}=\dfrac{0,6}{0,2}=3M\)
a/ Fe + 2HCl \(\rightarrow\) FeCl2 + H2
nH2 = \(\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
Theo PTHH: nH2 = nFe = 0,15 (mol) \(\Rightarrow m_{Fe}=0,15.56=8,4\left(g\right)\)
\(\Rightarrow m_{Cu}=11-8,4=2,6\left(g\right)\)
\(\Rightarrow\%m_{Fe}=\dfrac{8,4}{11}.100\%\approx76,4\%\)
\(\Rightarrow\%m_{Cu}=100-76,4\approx23,6\%\)
b/ Theo PTHH ta có: nHCl = 2nFe = 2.0,15 = 0,3 (mol)
\(\Rightarrow V_{ddHCl}=\dfrac{0,3}{2}=0,15\left(M\right)\)
c/ mHCl = 36,5 . 0,3 = 10,95(g)
\(\Rightarrow C\%_{HCl}=\dfrac{m_{HCl}}{m_{ddHCl}}.100\%=\dfrac{10,95}{200}.100\%=5,475\%\)
a, PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)
Ta có: \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
Theo PT: \(n_{Fe}=n_{H_2}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,15.56}{11}.100\%\approx76,36\%\\\%m_{Cu}\approx23,64\%\end{matrix}\right.\)
b, Theo PT: \(n_{HCl}=2n_{H_2}=0,3\left(mol\right)\)
\(\Rightarrow V_{ddHCl}=\dfrac{0,3}{2}=0,15\left(l\right)\)
c, \(C\%_{HCl}=\dfrac{0,3.36,5}{200}.100\%=5,475\%\)
a) \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
____0,15<--0,3<--------------0,15
=> mFe = 0,15.56 = 8,4 (g)
=> \(\left\{{}\begin{matrix}\%Fe=\dfrac{8,4}{21,2}.100\%=39,62\%\\\%Cu=\dfrac{21,2-8,4}{21,2}.100\%=60,38\%\end{matrix}\right.\)
b) mHCl = 0,3.36,5 = 10,95(g)
=> \(m_{ddHCl}=\dfrac{10,95.100}{3,65}.100\%=300\left(g\right)\)
a)
Gọi $n_{Fe} = a(mol) ; n_{Al} =b (mol) \Rightarrow 56a + 27b = 11(1)$
$Fe + 2HCl \to FeCl_2 + H_2$
$2Al + 6HCl \to 2AlCl_3 + 3H_2$
Theo PTHH : $n_{H_2} = a + 1,5b = \dfrac{8,96}{22,4} = 0,4(2)$
Từ (1)(2) suy ra : a = 0,1 ; b = 0,2
$\%m_{Fe} = \dfrac{0,1.56}{11}.100\% = 50,9\%$
$\%m_{Al} = 100\% - 50,9\% = 49,1\%$
b) $n_{HCl} = 2n_{H_2} = 0,8(mol)$
$\Rightarrow C_{M_{HCl}} = \dfrac{0,8}{0,4} = 2M$
c)
$C_{M_{FeCl_2}} = \dfrac{0,1}{0,4} = 0,25M$
$C_{M_{AlCl_3}} =\dfrac{0,2}{0,4} = 0,5M$
Chọn C.
\(n_{H_2}=0,4mol\)
\(\Rightarrow n_{HCl}=2n_{H_2}=0,8mol\)
\(C_M=\dfrac{0,8}{\dfrac{400}{1000}}=2M\)
c