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a, Ta có: \(n_{CO_2}=\dfrac{0,84}{22,4}=0,0375\left(mol\right)\)
PT: \(CO_2+2KOH\rightarrow K_2CO_3+H_2O\)
\(n_{K_2CO_3}=n_{CO_2}=0,0375\left(mol\right)\)
\(\Rightarrow m_{K_2CO_3}=0,0375.138=5,175\left(g\right)\)
b, \(n_{KOH}=2n_{CO_2}=0,075\left(mol\right)\)
\(\Rightarrow C_{M_{KOH}}=\dfrac{0,075}{0,2}=0,375\left(M\right)\)
PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)
Ta có: \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,2\left(mol\right)\\n_{FeCl_2}=0,1\left(mol\right)=n_{H_2}\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,1\cdot22,4=2,24\left(l\right)\\m_{FeCl_2}=0,1\cdot127=12,7\left(g\right)\\C_{M_{FeCl_2}}=\dfrac{0,1}{0,1}=1\left(M\right)\\C_{M_{HCl}}=\dfrac{0,2}{0,1}=2\left(M\right)\end{matrix}\right.\)
\(n_{Na}=\dfrac{6,9}{23}=0,3\left(mol\right)\\ 2Na+2H_2O\rightarrow2NaOH+H_2\\ n_{H_2}=\dfrac{0,3}{2}=0,15\left(mol\right)\\ a,V_{H_2\left(đktc\right)}=0,15.22,4=3,36\left(l\right)\\ b,m_{ddsaup.ứ}=m_{Na}+m_{H_2O}-m_{H_2}=6,9+100-0,15.2=106,6\left(g\right)\)
a, PTPƯ: SO3 + H2O ---> H2SO4
nSO3=\(\dfrac{2,24}{22,4}=0,1mol\)
1 mol SO3 ---> 0,1 mol H2SO4
nên 0,1 mol SO3 ---> 0,1 mol H2SO4
CM H2SO4=\(\dfrac{0,1}{0,5}\)=0,2 M
b, PTPƯ: Zn + H2SO4 ---> ZnSO4 + H2
1 mol H2SO4 ---> 1 mol Zn
nên 0,1 mol H2SO4 ---> 0,1 mol Zn
mZn=0,1.65=6,5 g
a) \(PT:CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\uparrow\)
\(HCl+NaOH\rightarrow NaOH+H_2O\)
b) \(m_{HCl}=\frac{200.10,95\%}{100\%}=21,9\left(g\right)\)
\(n_{HCl}=\frac{21,9}{36,5}=0,6\left(mol\right)\)
c) \(n_{NaOH}=2.0,05=0,1\left(mol\right)\Rightarrow n_{HCl\left(pưNaOH\right)}=0,1\left(mol\right)\)
\(\Rightarrow n_{HCl\left(pưCaCO_3\right)}=0,6-0,1=0,5\left(mol\right)\)
d) \(n_{CaCO_3}=\frac{1}{2}n_{HCl\left(pưCaCO_3\right)}=0,5.\frac{1}{2}=0,25\left(mol\right)\)
\(m_{CaCO_3}=0,25.100=25\left(g\right)\)
e) \(n_{CO_2}=n_{CaCO_3}=0,25\left(mol\right)\)
\(V_{CO_2}=0,25.22,4=5,6\left(l\right)\)
f) \(n_{CaCl_2}=n_{CaCO_3}=0,25\left(mol\right)\)
\(m_{ddA}=25+200-0,25.44=214\left(g\right)\)
\(C\%_{ddCaCl_2}=\frac{0,25.111}{214}.100\%=12,97\%\)
\(C\%_{ddHCldư}=\frac{0,1.36,5}{214}.100\%=1,71\%\)
2NaOH + CuSO4 → Cu(OH)2 + Na2SO4
n NaOH = 0,2.5 = 1(mol)
n CuSO4 = 0,1.2 = 0,2(mol)
Ta có :
n NaOH / 2 = 0,5 > n CuSO4 / 1 = 0,2 => NaOH dư
n Cu(OH)2 = n CuSO4 = 0,2 mol
=> m A = 0,2.98 = 19,6 gam
n Na2SO4 = n CuSO4 = 0,2 mol
n NaOH pư = 2n CuSO4 = 0,4(mol)
V dd = 0,2 + 0,1 = 0,3(lít)
Suy ra:
CM Na2SO4 = 0,2/0,3 = 0,67M
CM NaOH = (1 - 0,4)/0,3 = 2M
\(n_{CO2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Pt : \(2NaOH+CO_2\rightarrow Na_2CO_3+H_2O|\)
2 1 1 1
0,4 0,2 0,2
a) \(n_{NaOH}=\dfrac{0,2.2}{1}=0,4\left(mol\right)\)
500ml = 0,5l
\(C_{M_{ddNaOH}}=\dfrac{0,4}{0,5}=0,8\left(M\right)\)
b) \(n_{Na2CO3}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
⇒ \(m_{Na2CO3}=0,2.106=21,2\left(g\right)\)
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