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a) \(C_2H_4 + Br_2 \to C_2H_4Br_2\)
b)
\(n_{C_2H_4} = n_{Br_2} = \dfrac{5,6}{160} = 0,035(mol)\\ \%V_{C_2H_4} = \dfrac{0,035.22,4}{0,86}.100\% = 91,16\%\\ \%V_{CH_4} = 100\% - 91,16\% = 8,84\%\)
\(n_{hhkhí\left(C_2H_4,CH_4\right)}=\dfrac{7,84}{22,4}=0,35\left(mol\right)\)
\(m_{tăng}=m_{C_2H_4}=4,2\left(g\right)\\ n_{C_2H_4}=\dfrac{4,2}{28}=0,15\left(mol\right)\\ \%V_{C_2H_4}=\dfrac{0,15}{0,35}=42,85\%\\ \%V_{CH_4}=100\%-42,85\%=57,15\%\)
\(a,n_{Br_2}=\dfrac{6,4}{160}=0,04\left(mol\right)\)
PTHH: C2H4 + Br2 ---> C2H4Br2
0,04<---0,04
\(\rightarrow\left\{{}\begin{matrix}V_{C_2H_4}=0,04.22,4=0,896\left(l\right)\\V_{CH_4}=2,24-0,896=1,344\left(l\right)\end{matrix}\right.\\ b,\rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,896}{2,24}.100\%=40\%\\\%V_{CH_4}=100\%-40\%=60\%\end{matrix}\right.\)
\(n_{Br_2}=\dfrac{4}{160}=0,025\left(mol\right);n_{hh}=\dfrac{2,8}{22,4}=0,125\left(mol\right)\)
PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
0,025<-0,125
\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,025}{0,125}.100\%=20\%\\\%V_{CH_4}=100\%-20\%=80\%\end{matrix}\right.\)
\(m_{Br_2}=80g\Rightarrow n_{Br_2}=0,5mol\)
\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)
0,5 0,5
\(n_{hh}=\dfrac{28}{22,4}=1,25mol\)
\(\Rightarrow n_{CH_4}=1,25-0,5=0,75mol\)
\(\%V_{CH_4}=\dfrac{0,75}{1,25}\cdot100\%=60\%\)
\(\%V_{C_2H_4}=100\%-60\%=40\%\)
nBr2 = 32/160 = 0,2 (mol)
PTHH: C2H4 + Br2 -> C2H4Br2
Mol: 0,2 <--- 0,2
nhh khí = 44,8/22,4 = 2 (mol)
%VC2H4 = 0,2/2 = 10%
%VCH4 = 100% - 10% = 90%
a)
C2H4 + Br2 --> C2H4Br2
C2H2 + 2Br2 --> C2H2Br4
b) Gọi số mol C2H4, C2H2 là a, b (mol)
=> \(a+b=\dfrac{11,2}{22,4}=0,5\) (1)
PTHH: C2H4 + Br2 --> C2H4Br2
a---->a
C2H2 + 2Br2 --> C2H2Br4
b---->2b
=> a + 2b = \(\dfrac{112}{160}=0,7\) (2)
(1)(2) => a = 0,3 (mol); b = 0,2 (mol)
\(\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,3}{0,5}.100\%=60\%\\\%V_{C_2H_2}=\dfrac{0,2}{0,5}.100\%=40\%\end{matrix}\right.\)
\(\left\{{}\begin{matrix}\%m_{C_2H_4}=\dfrac{0,3.28}{0,3.28+0,2.26}.100\%=61,765\%\\\%m_{C_2H_2}=\dfrac{0,2.26}{0,3.28+0,2.26}.100\%=38,235\%\end{matrix}\right.\)
nhh = 6.72/22.4 = 0.3 (mol)
nBr2 = 64/160 = 0.4 (mol)
nC2H4 = a (mol) . nC2H2 = b (mol)
C2H2 + 2Br2 => C2H2Br4
C2H4 + Br2 => C2H4Br2
=> a + b = 0.3
a + 2b = 0.4
=> a =0.2 , b = 0.1
%VC2H4 = 0.2/0.3 * 100% = 66.67%
%VC2H2 = 33.33%
a, vì CH4 là hidrocacbon no => không xảy ra phản ứng với Brom
pt: C2H4 + Br2 -> C2H4Br2
1 1 1
nBr2 = m/M = 6,4/160 = 0,04 mol => nC2H4 = 0,04 mol
=> VC2H4 = n x 22,4 = 0,04 x 22,4 = 0,896 lit
=> VCH4 = Vhh - VC2H4 = 6,72 - 0,896 = 5,824 lit
b, C%VC2H4 = VC2H4/Vhh = 0,896/6,72 X 100 = 13,33%
=> C%VCH4 = Vhh - VC2H4 = 100% - 13,33% = 86,67%
C2H4 + Br2 -> C2H4Br2
a a a
C2H2 + 2Br2 -> C2H2Br4
b 2b b
n hỗn hợp khí = \(\dfrac{7.84}{22.4}=0.35mol\)
Ta có: \(\left\{{}\begin{matrix}a+b=0.35\\160a+320b=72\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0.25mol\\b=0.1mol\end{matrix}\right.\)
\(\%VC2H4=\dfrac{0.25\times22.4\times100}{7.84}=71.43\%\)
%VC2H2 = 100 - 71.43 = 28.57%
C2H4 + Br2 -> C2H4Br2
a a a
C2H2 + 2Br2 -> C2H2Br4
b 2b b
n hỗn hợp khí = 7.8422.4=0.35mol7.8422.4=0.35mol
Ta có: {a+b=0.35160a+320b=72⇔{a=0.25molb=0.1mol{a+b=0.35160a+320b=72⇔{a=0.25molb=0.1mol
%VC2H4=0.25×22.4×1007.84=71.43%%VC2H4=0.25×22.4×1007.84=71.43%
%VC2H2 = 100 - 71.43 = 28.57%