\(a)n_{Mg} = a ; n_{Al} = b \Rightarrow 24a +27b = 5,1(1)\\ Mg + 2HCl \to MgCl_2 + H_2\\ 2Al + 6HCl \to 2AlCl_3 + 3H_2\\ n_{H_2} = a + 1,5b = \dfrac{5,6}{22,4} = 0,25(2)\\ (1)(2) \Rightarrow a = 0,1 ; b = 0,1\\ \%m_{Mg} = \dfrac{0,1.24}{5,1}.100\% = 44,44\%\ ;\ \%m_{Al} = 100\% -44,44\% = 55,56\%\\ b) n_{MgCl_2} = n_{Mg} = 0,1 \Rightarrow m_{MgCl_2} = 0,1.95 = 9,5(gam)\\ n_{AlCl_3} = n_{Al} = 0,1 \Rightarrow m_{AlCl_3} = 0,1.133,5 = 13,35(gam)\\ c)n_{HCl} = 2n_{Mg} + 3n_{Al} = 0,5(mol) \Rightarrow m_{dd\ HCl} = \dfrac{0,5.36,5}{3,65\%} = 500(gam)\)

\(m_{dd\ sau\ pư} = 5,1 + 500 - 0,25.2 = 504,6(gam)\\ C\%_{MgCl_2} = \dfrac{9,5}{504,6}.100\% = 1,89\%\\ C\%_{AlCl_3} = \dfrac{13,35}{504,6}.100\% = 2,65\%\)

$a)PTHH:2Al+6HCl\to 2AlCl_3+3H_2$

$n_{H_2}=\dfrac{5,04}{22,4}=0,225(mol)$

$\Rightarrow n_{Al}=0,15(mol)$

$\Rightarrow \%m_{Al}=\dfrac{0,15.27}{9,45}.100\%\approx 42,86\%$

$\Rightarrow \%m_{Cu}=100-42,86=57,14\%$

$b)$ Theo PT: $n_{HCl}=2n_{H_2}=0,45(mol)$

$\Rightarrow C_{M_{HCl}}=\dfrac{0,45.110\%}{0,5}=0,99M$

a) Chất rắn không tan là Cu

=> m Cu = 19,2(gam)

n Mg = a(mol) ; n Fe = b(mol)

=> 24a + 56b = 32,8 -19,2 = 13,6(1)

$Mg + H_2SO_4 \to MgSO_4 + H_2$
$Fe + H_2SO_4 \to FeSO_4 + H_2$
n H2 = a + b = 6,72/22,4 = 0,3(2)

Từ (1)(2) suy ra a = 0,1 ; b = 0,2

%m Cu = 19,2/32,8  .100% = 58,54%
%m Mg = 0,1.24/32,8   .100% = 7,32%
%m Fe = 100% -58,54% -7,32% = 34,14%

b)

m dd A = 32,8 + 200 - 0,3.2 = 232,2(gam)

n MgSO4 = a = 0,1(mol)

n FeSO4 = b = 0,2(mol)

C% MgSO4 = 0,1.120/232,2   .100% = 5,17%
C% FeSO4 = 0,2.152/232,2   .100% = 13,09%

a) 2Al + 6HCl -> 2AlCl3 + 3H2

Al2O3 + 6HCl -> 2AlCl3 + 3H2O

nH2 = 0,15mol => nAl=0,1mol => mAl=2,7g; mAl2O3 = 10,2g => nAl2O3 = 0,1mol

=>%mAl=20,93% =>%mAl2O3 = 79,07%

b) nHCl = 0,1.3+0,1.6=0,9 mol=>mHCl(dd)=100g

mddY=12,9+100-0,15.2=112,6g

mAlCl3=22,5g=>C%=19,98%

Fe+2HCl->FeCl₂+H₂

x---2x-----------x

Mg+2HCl->MgCl₂+H₂

y------2y-----------y

Ta có :

\(\left\{{}\begin{matrix}56x+24y=24\\x+y=\dfrac{13,44}{22,4}\end{matrix}\right.\)

=>x=0,3 mol, y=0,3 mol

=>%m Fe=\(\dfrac{0,3.56}{24}.100\)=70%

=>%m Mg=100-70=30%

=>VHCl=\(\dfrac{0,3.2+0,3.2}{2}\)=0,6l=600ml

b)

 XCl₂+2AgNO₃->2AgCl+X(NO₃)₂

0,6--------------------1,2mol

=>m AgCl=1,2.143,5=172,2g

\(Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{Fe}=n_{H_2}=\dfrac{0,448}{22,4}=0,02\left(mol\right)\\ a,\%m_{Fe}=\dfrac{0,02.56}{4,36}.100\approx25,688\%\\ \Rightarrow\%m_{Ag}\approx74,312\%\\ b,Ta.thấy:2,18=\dfrac{1}{2}.4,36\\ \Rightarrow m_{hh\left(câuB\right)}=\dfrac{1}{2}.m_{hh\left(câuA\right)}\\ n_{Fe}=\dfrac{0,02}{2}=0,01\left(mol\right)\\ n_{Ag}=\dfrac{2,18-0,01.56}{108}=0,015\left(mol\right)\\ 2Fe+3Cl_2\rightarrow\left(t^o\right)2FeCl_3\\ 2Ag+Cl_2\rightarrow\left(t^o\right)2AgCl\\ n_{Cl_2}=\dfrac{3}{2}.n_{Fe}+\dfrac{1}{2}.n_{Ag}=\dfrac{3}{2}.0,01+\dfrac{1}{2}.0,015=0,0225\left(mol\right)\\ \Rightarrow V_{Cl_2\left(đktc\right)}=0,0225.22,4=0,504\left(l\right)\)

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