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\(m_{CH_4} = 8.30\% = 2,4(gam)\\ m_{C_2H_4} = 8 - 2,4 = 5,6(gam)\\ CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ C_2H_4 + 3O_2 \xrightarrow{t^o} 2CO_2 + 2H_2O\\\)
Theo PTHH :
\(n_{CO_2} = n_{CH_4} + 2n_{C_2H_4} = \dfrac{2,4}{16} + \dfrac{5,6}{28}.2 = 0,55(mol)\\ \Rightarrow m_{CO_2} = 0,55.44 = 24,2(gam)\)
\(m_{CH_4}=0.3\cdot8=2.4\left(g\right)\)
\(n_{CH_4}=\dfrac{2.4}{16}=0.15\left(mol\right)\)
\(m_{C_2H_4}=8-2.4=5.6\left(g\right)\)
\(n_{C_2H_4}=\dfrac{5.6}{28}=0.2\left(mol\right)\)
\(CH_4+2O_2\underrightarrow{t^0}CO_2+2H_2O\)
\(C_2H_4+3O_2\underrightarrow{t^0}2CO_2+2H_2O\)
\(n_{CO_2}=2\cdot0.15+0.2=0.5\left(mol\right)\)
\(m_{CO_2}=0.5\cdot44=22\left(g\right)\)
CH4 + 2O2 t0→ CO2 + 2H2O
C2H4 + 3O2 t0→ 2CO2 + 2H2O
C2H2 + 52 O2 t0→ 2CO2 + 2H2O
-Gọi: nCH4:a(mol)
nC2H4:b(mol)
nC2H2:c(mol)
⇒16a+28b+26c=11(1)
BTNT C ⇒a+2b+2c=0,75(2)
-Phân tích (1)và (2) ta được:
{13a+26b+26c=9,75
=>3a+2b=1,25(3)
16a+32b+32c=12
=>4b+6c=1(4)
-Từ (3) ⇒ \(a=\dfrac{1,25-2b}{3}\)
-Từ (4)⇒\(\dfrac{1-4c}{6}\)
-% CH4 =\(\dfrac{16a}{16a+32b+32c}.100\)
-Thay công thức a và c vào (⋅)
⇒%CH4=\(\dfrac{\dfrac{1,25-2b}{3}16}{16\dfrac{1,25-2b}{3}+28b+26.\dfrac{1-4b}{6}}100=12,12\%\)
a, \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
\(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)
\(2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\)
b, Sửa đề: 17,9 (l) → 17,92 (l)
Ta có: \(n_{CO_2}=\dfrac{17,92}{22,4}=0,8\left(mol\right)=n_C\)
\(n_{H_2O}=\dfrac{18}{18}=1\left(mol\right)\Rightarrow n_H=1.2=2\left(mol\right)\)
⇒ mA = mC + mH = 0,8.12 + 2.1 = 11,6 (g)
Theo ĐLBT KL, có: mA + mO2 = mCO2 + mH2O
⇒ mO2 = 0,8.44 + 18 - 11,6 = 41,6 (g)
\(\Rightarrow n_{O_2}=\dfrac{41,6}{32}=1,3\left(mol\right)\Rightarrow V_{O_2}=1,3.22,4=29,12\left(l\right)\)
\(Đặt:n_{CH_4}=a\left(mol\right),n_{C_2H_4}=b\left(mol\right)\)
\(\Rightarrow a+b=0.15\left(1\right)\)
\(n_{CO_2}=\dfrac{4.48}{22.4}=0.2\left(mol\right)\)
\(CH_4+2O_2\underrightarrow{t^0}CO_2+2H_2O\)
\(C_2H_4+3O_2\underrightarrow{t^0}2CO_2+2H_2O\)
\(\Rightarrow a+2b=0.2\left(2\right)\)
\(\left(1\right),\left(2\right):a=0.1,b=0.05\)
Vì : tỉ lệ thể tích tương ứng với tỉ lệ số mol :
\(\%n_{CH_4}=\dfrac{0.1}{0.15}\cdot100\%=66.67\%\)
\(\%n_{C_2H_4}=100-66.67=33.33\%\)
Chúc em học tốt !!
Đặt \(\left\{{}\begin{matrix}n_{CH_4}=x\left(mol\right)\\n_{C_2H_4}=y\left(mol\right)\end{matrix}\right.\)
\(\Sigma n_{hhkA}=\dfrac{3,36}{22,4}=0,15\\ \rightarrow x+y=0,15\left(1\right)\)
\(PTHH:CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)
(mol)........x....->...2x.......x..............2x
\(PTHH:C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)
(mol)........y......->...3y...........2y........2y
\(\Sigma n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\ \rightarrow x+2y=0,2\)
Giải hpt (1) (2) ta được x=0,1 ; y=0,05
\(\%V_{CH_4}=\dfrac{0,1.22,4}{3,36}.100\%=66,67\%\\ \%V_{C_2H_4}=100\%-66,67\%=33,33\%\)
\(a,Đặt:n_{CH_4}=a\left(mol\right);n_{C_4H_{10}}=b\left(mol\right)\left(a,b>0\right)\\ PTHH:CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\\ 2C_4H_{10}+13O_2\rightarrow\left(t^o\right)8CO_2+10H_2O\\ \Rightarrow\left\{{}\begin{matrix}16a+58b=7,4\\22,4a+22,4.4b=22\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}m_{CH_4}=0,1.16=1,6\left(g\right)\\m_{C_4H_{10}}=0,1.58=5,8\left(g\right)\end{matrix}\right.\\ b,n_{O_2}=2a+\dfrac{13}{2}b=2.0,1+6,5.0,1=0,85\left(mol\right)\\ \Rightarrow V_{O_2\left(đktc\right)}=0,85.22,4=19,04\left(l\right)\)
PTHH: 2CO+O2to→2CO2 (1)
4H2+O2to→2H2O (2)
b) Ta có:
ΣnO2=\(\dfrac{9,6}{32}\)=0,3(mol)
nCO2=\(\dfrac{8,8}{44}\)=0,2(mol)
⇒{nO2(1)=0,1mol
nO2(2)=0,2mol
⇒{mCO=0,1⋅28=2,8(g)
mH2=0,2⋅2=0,4(g)
⇒%mCO=\(\dfrac{2,8}{2,8+0,4}\)⋅100%=87,5%
%mH2=12,5%
\(nO_2=\dfrac{9,6}{32}=0,3\left(mol\right)\)
\(nCO_2=\dfrac{8,8}{44}=0,2\left(mol\right)\)
\(2CO+O_2\underrightarrow{t^o}2CO_2\)
2 1 2 (mol)
0,2 0,1 0,2 (mol)
\(4H_2+O_2\underrightarrow{t^o}2H_2O\)
4 1 2 (mol)
0,8 0,2 0,4 (mol)
\(mCO=0,2.28=5,6\left(g\right)\)
\(mH_2=0,8.2=0,16\left(g\right)\)
\(\%mCO=\dfrac{5,6.100}{5,6+0,16}=97,22\%\)
\(\%mH_2=100-97,22=2,78\%\)
Gọi số mol C, S là a, b
=> 12a + 32b = 7,68
PTHH: C + O2 --to--> CO2
_____a--------------->a
S + O2 --to--> SO2
b--------------->b
=> a + b = \(\dfrac{9,856}{22,4}=0,44\)
=> a = 0,32; b = 0,12
=> \(\left\{{}\begin{matrix}\%C=\dfrac{0,32.12}{7,68}.100\%=50\%\\\%S=\dfrac{0,12.32}{7,68}.100\%=50\%\end{matrix}\right.\)
\(n_{CH_4}=a\left(mol\right),n_{C_2H_2}=b\left(mol\right)\)
\(\Rightarrow m_A=16a+26b=8.4\left(g\right)\left(1\right)\)
\(n_{O_2}=\dfrac{28.8}{32}=0.9\left(mol\right)\)
\(CH_4+2O_2\underrightarrow{t^0}CO_2+2H_2O\)
\(C_2H_2+\dfrac{5}{2}O_2\underrightarrow{t^0}2CO_2+H_2O\)
\(\Rightarrow2a+\dfrac{3}{2}b=0.9\left(2\right)\)
\(\left(1\right),\left(2\right):a=b=0.2\)
\(m_{CH_4}=0.2\cdot16=3.2\left(g\right)\)
\(m_{C_2H_2}=0.2\cdot26=5.2\left(g\right)\)
Chúc em học tốt !!
Sory anh lại sai đề là CH4 và C2H2 mới đúng. Ko phải C2H4. Phiền a giải lại ạ.