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\(m_{CuO}=50.20\%=10\left(g\right)\)
\(n_{CuO}=\dfrac{10}{80}=0,125\left(mol\right)\)
\(m_{Fe_2O_3}=50-10=40\left(g\right)\)
\(n_{Fe_2O_3}=\dfrac{40}{160}=0,25\left(mol\right)\)
PTHH :
\(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)
0,125 0,125 0,125
\(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
0,25 0,75 0,5
\(a,V_{H_2}=\left(0,75+0,125\right).22,4=19,6\left(l\right)\)
\(b,m_{Cu}=0,125.64=8\left(g\right)\)
\(m_{Fe}=0,5.56=28\left(g\right)\)
3Fe + 2O2 --to> Fe3O4 4Al + 3O2 -to-> 2Al2O3
x ---------------> x/3 y------------------> y/2
Theo đề bài\(\dfrac{\dfrac{x.232}{3}+\dfrac{y.102}{2}}{56x+27y}=\dfrac{283}{195}\)
Giải pt => x = 3y
=> %mFe =\(\dfrac{3y.56}{3y.56+27y}100=\) 86,15%
<=> %mAl = 100 - 86,15 = 13,85%
\(n_{Cu}=\dfrac{19,2}{64}=0,3mol\)
\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\)
\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)
0,3 0,3 ( mol )
\(m_{CuO}=0,3.80=24g\)
\(\Rightarrow m_{Fe_2O_3}=40-24=16g\)
\(\%m_{CuO}=\dfrac{24}{40}.100=60\%\)
\(\%m_{Fe_2O_3}=100\%-60\%=40\%\)
\(n_{Cu}=\dfrac{19,2}{64}=0,3mol\)
\(CuO+H_2\rightarrow Cu+H_2O\)
0,3 0,3
\(\Rightarrow n_{CuO}=0,3\Rightarrow m_{CuO}=24g\)
\(\Rightarrow m_{Fe_2O_3}=40-24=16g\Rightarrow n_{Fe_2O_3}=0,1mol\)
\(Fe_2O_3+3H_2\rightarrow2Fe+3H_2O\)
\(\%m_{CuO}=\dfrac{24}{40}\cdot100\%=60\%\)
\(\%m_{Fe_2O_3}=100\%-60\%=40\%\)
\(Fe_2O_3 + 3H_2 \xrightarrow{t^o} 2Fe + 3H_2O\\ CuO + H_2 \xrightarrow{t^o} Cu + H_2O\\ \text{Theo PTHH : } n_{H_2} = n_{H_2O} = \dfrac{9}{18} = 0,5(mol)\\ \text{Bảo toàn khối lượng : } m_{Oxit} + m_{H_2} = m_{kim\ loại} + m_{H_2O}\\ \Rightarrow m_{kim\ loại} = 32 + 0,5.2 - 9 = 24(gam)\)
PT: Fe2O3+3H2to→2Fe+3H2O
CuO+H2to→Cu+H2O
a, Ta có: mFe2O3=20.60%=12(g)
⇒nFe2O3=\(\dfrac{12}{160}\)=0,075(mol
mCuO=20−12=8(g
⇒nCuO=\(\dfrac{8}{80}\)=0,1(mol)
Theo pT:
nFe=2nFe2O3=0,15(mol)
nCu=nCuO=0,1(mol)
⇒mFe=0,15.56=8,4(g)
mCu=0,1.64=6,4(g)
b, Theo PT: nH2=3nFe2O3+nCuO=0,325(mol)
⇒VH2=0,325.22,4=7,28(l)
c. Zn+2HCl->ZnCl2+H2
0,65----------0,325
=>m HCl=0,65.36,5=23,725g
3Fe + 2O2 --> Fe3O4 4Al + 3O2 --> 2Al2O3
x ---------------> x/3 y------------------> y/2
Theo đề bài \(\dfrac{\dfrac{x.232}{3}+\dfrac{y.102}{2}}{56x+27y}\) = \(\dfrac{283}{195}\)
Giải pt => x = 3y
=> %mFe = \(\dfrac{mFe}{mFe+mAl}.100\%\)= \(\dfrac{3y.56}{3y.56+27y}.100\%\) = 86,15%
<=> %mAl = 100 - 86,15 = 13,85%
Gọi số mol Fe3O4, PbO là a, b
=> 232a + 223b= 78,95
PTHH: Fe3O4 + 4H2 --to--> 3Fe + 4H2O
a------>4a---------->3a
PbO + H2 --to--> Pb + H2O
b--->b--------->b
=> 56.3a + 207.b = 68,55
=> a = 0,1; b = 0,25
=> \(\left\{{}\begin{matrix}\%Fe_3O_4=\dfrac{232.0,1}{78,95}.100\%=29,386\%\\\%PbO=\dfrac{0,25.223}{78,95}.100\%=70,614\%\end{matrix}\right.\)
nH2 = 4a + b = 0,65 (mol)
=> VH2 = 0,65.22,4 = 14,56 (l)