\(n_{Cl_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\\ Cl_2+2NaOH\rightarrow NaCl+NaClO+H_2O\\ C_{MddNaOH\left(dư\right)}=0,05\left(mol\right)\Rightarrow Tính.theo.Cl_2\\ n_{NaOH\left(P.Ứ\right)}=2.n_{Cl_2}=2.0,05=0,1\left(mol\right)\\ n_{NaOH\left(dư\right)}=0,2.0,05=0,01\left(mol\right)\\ \Rightarrow C_{MddNaOH\left(ban.đầu\right)}=\dfrac{0,1+0,01}{0,2}=0,55\left(M\right)\\ \Rightarrow Chọn.D\)

Câu 10:

\(PCl_3+3H_2O\rightarrow H_3PO_3+3HCl\\ H_3PO_3+3NaOH\rightarrow Na_3PO_3+3H_2O\\HCl+NaOH\rightarrow NaCl+H_2O\\ Đặt:n_{PCl_3}=k\left(mol\right)\\ \Rightarrow n_{H_3PO_3}=k\left(mol\right);n_{HCl}=3k\left(mol\right)\\ Ta.có:n_{NaOH}=3.n_{H_3PO_3}+n_{HCl}=3k+3k\\ \Leftrightarrow0,6=6k\\ \Leftrightarrow k=0,1\left(mol\right)\\ \Rightarrow n_{PCl_3}=0,1\left(mol\right)\\ \Rightarrow Chọn.A\)

Câu 8:

\(n_{NaCl}=\dfrac{8,775}{58,5}=0,15\left(mol\right)\\ NaCl+H_2SO_{4\left(đặc\right)}\rightarrow\left(250^oC\right)NaHSO_4+HCl\uparrow\\ n_{HCl}=n_{NaCl}=0,15\left(mol\right)\\ \Rightarrow C\%_{ddHCl}=\dfrac{0,15.36,5}{0,15.36,5+14,525}.100=27,375\%\\ \Rightarrow Chọn.A\\ MnO_2+4HCl_{đặc}\rightarrow\left(t^o\right)MnCl_2+Cl_2+2H_2O\\ n_{Cl_2\left(thu\right)}=70\%.n_{Cl_2\left(LT\right)}=70\%.\dfrac{0,15}{4}=0,02625\left(mol\right)\\ \Rightarrow V_{Cl_2\left(đktc,thu\right)}=0,02625.22,4=0,588\left(l\right)\\ \Rightarrow Chọn.B\)

Gọi kim loại cần tìm là M

PTHH: \(M+2H_2O\rightarrow M\left(OH\right)_2+H_2\)

Áp dụng định luật bảo toàn khối lượng:

\(m_M+m_{H_2O}=m_{ddM\left(OH\right)_2}+m_{H_2}\)

\(\Rightarrow m_{H_2}=m_M+m_{H_2O}-m_{ddM\left(OH\right)_2}=0,6+80-80,57=0,03\left(g\right)\)

\(\Rightarrow n_M=n_{H_2}=\dfrac{0,03}{2}=0,015\left(mol\right)\)

\(\Rightarrow M_M=\dfrac{0,6}{0,015}=40\Rightarrow M\) là \(Ca\)

Câu 29:

(1) \(Cl_2+2NaOH\rightarrow NaCl+NaClO+H_2O\)

(2) \(2Fe+3Cl_2\underrightarrow{t^o}2FeCl_3\)

(3) \(H_2+Cl_2\underrightarrow{t^o}2HCl\)

(4) \(HCl+NaOH\rightarrow NaCl+H_2O\)

(5) \(NaCl+AgNO_3\rightarrow NaNO_3+AgCl_{\downarrow}\)

(6) \(Fe+2HCl\rightarrow FeCl_2+H_2\)

Câu 30:

a, PT: \(Zn+S\underrightarrow{t^o}ZnS\)

\(Fe+S\underrightarrow{t^o}FeS\)

b, Giả sử: \(\left\{{}\begin{matrix}n_{Zn}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\)

⇒ 65x + 56y = 26,55 (1)

Ta có: \(n_S=\dfrac{14,4}{32}=0,45\left(mol\right)\)

Theo PT: \(n_S=n_{Zn}+n_{Fe}=x+y\left(mol\right)\)

⇒ x + y = 0,45 (2)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,15\left(mol\right)\\y=0,3\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,15.65}{26,55}.100\%\approx36,7\%\\\%m_{Fe}\approx63,3\%\end{matrix}\right.\)

Bạn tham khảo nhé!

\(n_{halogen}=\dfrac{35,875-18,625}{108-39}=0,25\left(mol\right)\\ M_{muối\left(t.gia\right)}=\dfrac{18,625}{0,25}=74,5=39+M_{halogen}\\ \Leftrightarrow M_{halogen}=35,5\left(\dfrac{g}{mol}\right)\\ Vậy.muối.halogen.đó:KCl\left(Cl=35,5\right)\\ Chọn.A\)

Đáp án C

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