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\(n_{Al}=\dfrac{16,2}{27}=0,6\left(mol\right)\)
2Al + 3H2SO4 ---> Al2(SO4)3 + 3H2
0,6 0,9 0,3 0,9
\(\rightarrow V_{H_2}=0,9.22,4=20,16\left(l\right)\)
\(n_{Cu}=\dfrac{57}{64}=0,890625\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
0,890625 0,890625
\(H=\dfrac{0,890625}{0,9}=99\%\)
a.b.c.\(n_{Al}=\dfrac{2,7}{27}=0,1mol\)
\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
0,1 0,1 0,15 ( mol )
\(V_{H_2}=0,15.22,4=3,36l\)
\(m_{AlCl_3}=0,1.133,5=13,35g\)
d.\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\)
0,15 0,1 ( mol )
\(m_{Fe}=0,1.56=5,6g\)
a) 2Al+6HCl→2AlCl3+3H22Al+6HCl→2AlCl3+3H2
b) nAl=5,427=0,2(mol)nAl=5,427=0,2(mol)
Theo phương trình : nH2=32nAl=0,3(mol)nH2=32nAl=0,3(mol)
→VH2(đktc)=0,3.22,4=6,72(l)→VH2(đktc)=0,3.22,4=6,72(l)
c) Chất rắn : 0,2(mol)0,2(mol)
CuO dư : 0,2(mol)Cu0,2(mol)Cu
%CuO=0,2.80(0,2.80+0,2.64).100=55,56%%CuO=0,2.80(0,2.80+0,2.64).100=55,56%
%Cu=44,44%%Cu=44,44%
a)\(n_{Al}=\dfrac{5,4}{27}=0,2mol\)
\(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
0,2 0,3 0,1 0,3
b)\(V_{H_2}=0,3\cdot22,4=6,72l\)
c)\(n_{CuO}=\dfrac{32}{80}=0,4mol\)
\(CuO+H_2\rightarrow Cu+H_2O\)
0,4 0,3 0,3
\(m_{Cu}=0,3\cdot64=19,2g\)
nAl = 5.4/27 = 0.2 (mol)
2Al + 6HCl => 2AlCl3 + 3H2
0.2.......0.6......................0.3
CM HCl = 0.6 / 0.4 = 1.5 (M)
nCuO = 32/80 = 0.4 (mol)
CuO + H2 -to-> Cu + H2O
0.2.......0.2..........0.2
Chất rắn : 0.2 (mol) CuO dư , 0.2 (mol) Cu
%CuO =\(\dfrac{0,2.80}{0,2.80+0,2.64}\) 100% = 55.56%
%Cu = 44.44%
a) \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
b) \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
Theo phương trình : \(n_{H_2}=\dfrac{3}{2}n_{Al}=0,3\left(mol\right)\)
\(\rightarrow V_{H_2}\left(đktc\right)=0,3.22,4=6,72\left(l\right)\)
c) Chất rắn : \(0,2\left(mol\right)\)
CuO dư : \(0,2\left(mol\right)Cu\)
\(\%CuO=\dfrac{0,2.80}{\left(0,2.80+0,2.64\right)}.100=55,56\%\)
\(\%Cu=44,44\%\)
a) PTHH : \(2Al+6HCl-->2AlCl_3+3H_2\) (1)
\(Fe+2HCl-->FeCl_2+H_2\) (2)
\(H_2+CuO-t^o->Cu+H_2O\) (3)
b) Ta có : \(m_{CR\left(giảm\right)}=m_{O\left(lay.di\right)}\)
=> \(m_{O\left(lay.di\right)}=32-26,88=5,12\left(g\right)\)
=> \(n_{O\left(lay.di\right)}=\frac{5,12}{16}=0,32\left(mol\right)\)
Theo pthh (3) : \(n_{H_2\left(pứ\right)}=n_{O\left(lay.di\right)}=0,32\left(mol\right)\)
=> \(tổng.n_{H_2}=\frac{0,32}{80}\cdot100=0,4\left(mol\right)\)
Đặt \(\hept{\begin{cases}n_{Al}=a\left(mol\right)\\n_{Fe}=b\left(mol\right)\end{cases}}\) => \(27a+56b=11\left(I\right)\)
Theo pthh (1) và (2) : \(n_{H_2\left(1\right)}=\frac{3}{2}n_{Al}=\frac{3}{2}a\left(mol\right)\)
\(n_{H_2\left(2\right)}=n_{Fe}=b\left(mol\right)\)
=> \(\frac{3}{2}a+b=0,4\left(II\right)\)
Từ (I) và (II) => \(\hept{\begin{cases}a=0,2\\b=0,1\end{cases}}\)
=> \(\hept{\begin{cases}m_{Al}=27\cdot0,2=5,4\left(g\right)\\m_{Fe}=56\cdot0,1=5,6\left(g\right)\end{cases}}\)
a, \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
b, \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Zn}=0,2\left(mol\right)\Rightarrow V_{H_2}=0,2.22,4=4,48\left(l\right)\)
c, \(n_{Fe_3O_4}=\dfrac{18,56}{232}=0,08\left(mol\right)\)
PT: \(Fe_3O_4+4H_2\underrightarrow{t^o}3Fe+4H_2O\)
Xét tỉ lệ: \(\dfrac{0,08}{1}>\dfrac{0,2}{4}\), ta được Fe3O4 dư.
Theo PT: \(n_{Fe}=\dfrac{3}{4}n_{H_2}=0,15\left(mol\right)\Rightarrow m_{Fe}=0,15.56=8,4\left(g\right)\)
2Al+6HCl->2AlCl3+3H2
1,2------------------0,6 mol
H2+CuO->Cu+H2O
0,4----0,4
m HCl=43,8=>n HCl=\(\dfrac{43,8}{36,5}\)=1,2 mol
=>VH2=0,6.22,4=13,44l
b)n CuO=\(\dfrac{32}{80}\)=0,4 mol
=>H2 dư
=>m=m Cu=0,4.64=25,6g
=>%mCu=100%
`Zn+H_2SO_4->ZnSO_4+H_2`(to)
0,45-------------------0,45------0,45mol
`n_(Zn)=(29,25)/65=0,45mol`
`m_(ZnSO_4)=0,45.161=72,45g`
`V_(H_2)=0,45.22,4=10,08l`
c) `H_2+CuO->Cu+H_2O`(to)
0,45--------0,45 mol
`n_(Cu)=40/80=0,5 mol`
=>Cu dư , 0,05 mol
`m_(chất rắn)=0,45.64+0,05.80=32,8g`
\(n_{Zn}=\dfrac{m}{M}=\dfrac{29,25}{65}=0,45\left(mol\right)\)
a) \(PTHH:Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
1 1 1 1
0,45 0,45 0,45 0,45
b) \(m_{ZnSO_4}=n.M=0,45.\left(65+32+16.4\right)=51,03\left(g\right)\\ V_{H_2}=n.24,79=0,45.24,79=11,1555\left(l\right)\)
c) \(n_{CuO}=\dfrac{m}{M}=\dfrac{40}{\left(64+16\right)}=0,5\left(mol\right)\)
\(PTHH:CuO+H_2\rightarrow Cu+H_2O\)
1 1 1 1
0,5 0,5 0,5 0,5
\(m_{Cu}=0,5.64=32\left(g\right).\)
nZn = 13/65 = 0,2 (mol)
PTHH: Zn + H2SO4 -> ZnSO4 + H2
Mol: 0,2 ---> 0,2 ---> 0,2 ---> 0,2
VH2 = 0,2 . 22,4 = 4,48 (l)
nCuO = 32/80 = 0,4 (mol)
PTHH: CuO + H2 -> (r°) Cu + H2O
LTL: 0,4 > 0,2 => CuO dư
nCuO (p/ư) = nCu = 0,2 (mol)
mCuO (dư) = (0,4 - 0,2) . 80 = 16 (g)
mCu = 0,2 . 64 = 12,8 (g)
%mCuO = 16/(16 + 12,8) = 55,55%
%mCu = 100% - 55,55 = 45,45%
\(a.Fe+H_2SO_4\rightarrow FeSO_4+H_2\\b. n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\\ n_{H_2SO_4}=n_{Fe}=0,4\left(mol\right)\\ \Rightarrow m_{H_2SO_4}=0,4.98=39,2\\ c.n_{H_2}=n_{Fe}=0,4\left(mol\right)\\ \Rightarrow V_{H_2}=0,4.22,4=8,96\left(l\right)\\ d.H_2+CuO-^{t^o}\rightarrow Cu+H_2O\\ n_{Cu}=n_{H_2}=0,4\left(mol\right)\\ \Rightarrow m_{Cu}=0,4.64=25,6\left(g\right)\)
d) PTHH: H2+CuO---to---> H2O+Cu
0,4 0,4
mCuO=n.M=0,4x80=32g