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a) \(n_{NaOH}=\dfrac{20}{40}=0,5\left(mol\right)\)
\(CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl\)
Lập tỉ lệ : \(\dfrac{0,2}{1}< \dfrac{0,5}{2}\)=> Sau phản ứng NaOH dư
\(n_{Cu\left(OH\right)_2}=n_{CuCl_2}=0,2\left(mol\right)\)
Dung dịch nước lọc gồm NaCl (0,4_mol); NaOH dư ( 0,1 mol)
\(Cu\left(OH\right)_2-^{t^o}\rightarrow CuO+H_2O\)
\(n_{CuO}=n_{Cu\left(OH\right)_2}=0,2\left(mol\right)\)
\(a=m_{CuO}=0,2.80=16\left(g\right)\)
b) \(m_{NaCl}=0,4.58,5=23,4\left(g\right);m_{NaOH}=0,1.40=4\left(g\right)\)
BTKL
mX + mdd HNO3 = mdd X + mH2O + m↑
=> mdd X = 11,6 + 87,5 – 30 . 0,1 – 46 . 0,15 = 89,2g
=> C%Fe(NO3)3 = 13,565%
\(\left\{{}\begin{matrix}n_{Fe}=a\left(mol\right)\\n_{Cu}=b\left(mol\right)\\n_{Fe_2O_3}=c\left(mol\right)\\n_{CuO}=d\left(mol\right)\end{matrix}\right.\)⇒ 56a + 64b + 160c + 80d = 12,4(1)
BT e : \(2n_{SO_2} = 3n_{Fe} + 2n_{Cu}\)
⇒ 3a + 2b = \(2. \dfrac{2,8}{22,4} = 0,25\) ⇔ 8(3a + 2b) = 0,25.8 ⇔ 24a + 16b = 2(2)
Lấy (1) + (2),ta có :
80a + 80b + 160c + 80d = 12,4 + 2 = 14,4
Bảo toàn nguyên tố với Fe,Cu
2Fe → Fe2O3
a..............0,5a.........(mol)
Cu → CuO
b............b...............(mol)
Fe2O3 → Fe2O3
c....................c...............(mol)
CuO → CuO
d...................d................(mol)
Vậy :
\(m_Z = m_{Fe_2O_3} + m_{CuO} = 160(0,5a + c) + 80(b+d)\\ = 80a + 80b + 160c + 80d \\= 14,4(gam)\)
a.CuCl2 + 2NaOH -> Cu(OH)2 + 2NaCl
0.15 0.3 0.15 0.3
Cu(OH)2 -> CuO + H2O
0.15 0.15
nNaOH = 0.3 mol
\(CM_{CuCl2}=\dfrac{0.15}{2}=0.075M\)
b.Vdd sau phản ứng = 0.2 + 0.15 = 0.35l
\(CM_{NaCl}=\dfrac{0.3}{0.35}=0.86M\)
c.mCuO = \(0.15\times80=12g\)
a) mNaOH= 200.20%= 40(g)
=>nNaOH=1(mol)
PTHH: 2 NaOH + CuCl2 -> 2 NaCl + Cu(OH)2
Dung dịch sau khi lọc kết tủa có NaCl.
nNaCl=nNaOH= 1(mol)
nCuCl2=nCu(OH)2=nNaOH/2=1/2=0,5(mol)
mNaCl=1.58,5=58,5(g)
mCuCl2=0,5.135=67,5(g)
=> mddCuCl2=(67,5.100)/10=675(g)
mCu(OH)2=0,5.98=49(g)
=>mddNaCl=mddNaOH+ mddCuCl2 - mCu(OH)2= 200+675 - 98=777(g)
=> \(C\%ddNaCl=\dfrac{58,5}{777}.100\approx7,529\%\)
b) PTHH: Cu(OH)2 -to-> CuO + H2O
0,5__________________0,5(mol)
m(rắn)=mCuO=0,5.80=4(g)
Pt:
Fe3O4 + 4H2SO4 → FeSO4 + Fe2(SO4)3 + 4H2O
0,1 → 0,4 0,1 0,1
Cu + Fe2(SO4)3 → CuSO4 + 2FeSO4
0,1 ←0,1 → 0,1 0,2
Rắn B là 0,1 mol Cu → x = 6,4 (g)
\(a,PTHH:K_2O+H_2O\rightarrow2KOH\\ n_{K_2O}=\dfrac{18,8}{94}=0,2\left(mol\right)\\ \Rightarrow n_{KOH}=0,4\left(mol\right)\\ \Rightarrow C_{M_{KOH}}=\dfrac{0,4}{1}=0,4M\\ b,PTHH:2KOH+H_2SO_4\rightarrow K_2SO_4+H_2O\\ n_{KOH}=\dfrac{1}{2}\cdot0,4=0,2\left(mol\right)\\ \Rightarrow n_{H_2SO_4}=\dfrac{1}{2}n_{KOH}=0,1\left(mol\right)\\ \Rightarrow m_{CT_{H_2SO_4}}=0,1\cdot98=9,8\left(g\right)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{9,8\cdot100\%}{20\%}=49\left(g\right)\)
\(c,PTHH:2KOH+CuCl_2\rightarrow Cu\left(OH\right)_2\downarrow+2KCl\\ Cu\left(OH\right)_2\rightarrow^{t^o}CuO+H_2O\\ \Rightarrow n_{CuO}=n_{Cu\left(OH\right)_2}=\dfrac{1}{2}n_{KOH}=0,1\left(mol\right)\\ \Rightarrow a=m_{CuO}=0,1\cdot80=8\left(g\right)\)