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\(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(MgO+2HCl\rightarrow MgCl_2+H_2O\)
\(n_{Mg}=n_{H_2}=\dfrac{1.12}{22.4}=0.05\left(mol\right)\)
\(m_{Mg}=0.05\cdot24=1.2g\)
\(m_{MgO}=9.2-1.2=8\left(g\right)\)
nH2=0,1(mol)
PTHH: Mg + 2 HCl -> MgCl2 + H2
0,1__________0,2___________0,1(mol)
MgO + 2 HCl -> MgCl2 + H2O
0,05____0,1___0,05(mol)
mMg=0,1. 24= 2,4(g) -> mMgO=4,4-2,4= 2(g) -> nMgO=0,05((mol)
b) %mMg= (2,4/4,4).100=54,545%
=> %mMgO=45,455%
c) nHCl=0,3(mol) -> mHCl=0,3.36,5=10,95(g)
=> mddHCl=(10,95.100)/7,3=150(g)
\(n_{FeO}=a\left(mol\right),n_{CuO}=b\left(mol\right)\)
\(m_{hh}=72a+80b=19.2\left(g\right)\left(1\right)\)
\(FeO+H_2SO_4\rightarrow FeSO_4+H_2O\)
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
\(n_{H_2SO_4}=a+b=0.25\left(mol\right)\left(2\right)\)
\(\left(1\right),\left(2\right):a=0.1,b=0.15\)
\(m_{FeO}=0.1\cdot72=7.2\left(g\right)\)
\(m_{CuO}=12\left(g\right)\)
\(C_{M_{FeSO_4}}=\dfrac{0.1}{0.25}=0.4\left(M\right)\)
\(C_{M_{CuSO_4}}=\dfrac{0.15}{0.25}=0.6\left(M\right)\)
a) Fe + 2HCl --> FeCl2 + H2
b) \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
_____0,15<-0,3<----0,15<---0,15
\(\left\{{}\begin{matrix}\%Fe=\dfrac{0,15.56}{12}.100\%=70\%\%\\\%Cu=100\%-70\%=30\%\end{matrix}\right.\)
c) mHCl = 0,3.36,5 = 10,95 (g)
=> \(m_{dd}=\dfrac{10,95.100}{10}=109,5\left(g\right)\)
d) mdd = 12 + 109,5 - 0,15.2 = 121,2 (g)
\(C\%\left(FeCl_2\right)=\dfrac{0,15.127}{121,2}.100\%=15,718\%\)
\(a/ZnO+2HCl\rightarrow ZnCl_2+H_2O\\ Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\\ b/n_{HCl}=\dfrac{250.7,3}{100}:36,5=0,5mol\\ n_{ZnO}=a;n_{Fe_2O_3}=b\\ \Rightarrow\left\{{}\begin{matrix}81a+160b=16,1\\2a+6b=0,5\end{matrix}\right.\\ \Rightarrow a=b=0,1mol\\ \%m_{ZnO}=\dfrac{0,1.81}{16,1}\cdot100=50,3\%\\ \%m_{Fe_2O_3}=100-50,3=49,7\%\\ c/C_{\%ZnCl_2}=\dfrac{136.0,1}{16,1+250}\cdot100=5\%\\ C_{\%FeCl_3}=\dfrac{0,1.2.162,5}{16,1+250}=12\%\)
a)
$Zn + 2HCl \to ZnCl_2 + H_2$
$ZnO + 2HCl \to ZnCl_2 + H_2O$
b)
$n_{Zn} = n_{H_2} = \dfrac{2,24}{22,4} = 0,1(mol)$
$m_{Zn} = 0,1.65 = 6,5(gam)$
$m_{ZnO} = 14,6 - 6,5 = 8,1(gam)$
c)
$n_{ZnO} = \dfrac{8,1}{81} = 0,1(mol)$
$n_{HCl} = 2n_{Zn} + 2n_{ZnO} = 0,4(mol)$
$\Rightarrow V_{dd\ HCl} = \dfrac{0,4}{C_{M_{HCl}}}$
a) nH2=0,2(mol)
PTHH: Mg + 2 HCl -> MgCl2 + H2
0,2______0,4_______0,2_____0,2(mol)
PTHH: MgO +2 HCl -> MgCl2 + H2O
b) mMgO= 8,8 - 0,2.24=4(g)
%mMgO= (4/8,8).100= 45,455%
=>%Mg=54,545%
c) nHCl(tổng)= 2. nMg + 2. nMgO= 2. 0,2+ 0,1.2=0,6(mol)
=> mHCl= 0,6.36,5=21,9(g)
=>mddHCl=(21,9.100)/7,3=300(g)
d) mddMgCl2= mddHCl + m(hỗn hợp ban đầu) - mH2
<=>mddHCl= 300+ 8,8- 0,2.2= 308,4(g)
nMgCl2=0,3(mol) => mMgCl2= 0,3.95=28,5(g)
=>C%ddMgCl2= (28,5/308,4).100=9,241%
\(n_{H2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
a) \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
\(Al_2O_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O\)
b) \(n_{Fe}=n_{H2}=n_{H2SO4}=0,1\left(mol\right)\Rightarrow m_{Fe}=0,1.56=5,6\left(g\right)\)
\(\Rightarrow m_{Al2O3}=15,8-5,6=10,2\left(g\right)\)
c) Ta có : \(n_{Al2O3}=\dfrac{10,2}{102}=0,1\left(mol\right)\Rightarrow n_{H2SO4}=3n_{Al2O3}=0,3\left(mol\right)\)
\(C_{MddH2SO4}=\dfrac{0,1+0,3}{0,2}=2M\)
a, PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
\(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)
b, Ta có: \(n_{H_2}=0,15\left(mol\right)\)
Theo PT: \(n_{Al}=\dfrac{2}{3}n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow m_{Al}=0,1.27=2,7\left(g\right)\)
\(\Rightarrow m_{Al_2O_3}=7,8-2,7=5,1\left(g\right)\)
c, Có: \(n_{Al_2O_3}=\dfrac{5,1}{102}=0,05\left(mol\right)\)
Theo PT: \(n_{HCl}=3n_{Al}+6n_{Al_2O_3}=0,6\left(mol\right)\)
\(n_{AlCl_3}=n_{Al}+2n_{Al_2O_3}=0,2\left(mol\right)\)
\(\Rightarrow m_{HCl}=0,6.36,5=21,9\left(g\right)\Rightarrow m_{ddHCl}=\dfrac{21,9}{10\%}=219\left(g\right)\)
⇒ m dd sau pư = 7,8 + 219 - 0,15.2 = 226,5 (g)
\(\Rightarrow C\%_{AlCl_3}=\dfrac{0,2.133,5}{226,5}.100\%\approx11,79\%\)
Bạn tham khảo nhé!