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a, \(CuO+2HCl\rightarrow CuCl_2+H_2O\)
b, \(n_{HCl}=0,2.0,5=0,1\left(mol\right)\)
Theo PT: \(n_{CuO}=n_{CuCl_2}=\dfrac{1}{2}n_{HCl}=0,05\left(mol\right)\)
\(\Rightarrow m_{CuO}=0,05.80=4\left(g\right)\)
c, \(C_{M_{CuCl_2}}=\dfrac{0,05}{0,2}=0,25\left(M\right)\)
\(n_{HCl}=0,2.0,5=0,1\left(mol\right)\)
PTHH :
\(CuO+2HCl\rightarrow CuCl_2+H_2O\)
0,05 0,1 0,05
\(b,m_{CuO}=0,05.80=4\left(g\right)\)
\(c,C_{M\left(CuCl_2\right)}=\dfrac{0,05}{0,2}=0,25\left(M\right)\)
\(n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\)
PT: \(CuO+2HCl\rightarrow CuCl_2+H_2O\)
a, \(n_{HCl}=2n_{CuO}=0,2\left(mol\right)\Rightarrow C\%_{HCl}=\dfrac{0,2.36,5}{200}.100\%=3,65\%\)
b, \(n_{CuCl_2}=n_{CuO}=0,1\left(mol\right)\)
\(\Rightarrow C\%_{CuCl_2}=\dfrac{0,1.135}{8+200}.100\%\approx6,49\%\)
PTHH: \(H_2SO_4+2KOH\rightarrow K_2SO+2H_2O\)
Ta có: \(n_{H_2SO_4}=0,2\cdot1=0,2\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{KOH}=0,4\left(mol\right)\\n_{K_2SO_4}=0,2\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{ddKOH}=\dfrac{\dfrac{0,4\cdot56}{6\%}}{1,048}\approx356,2\left(ml\right)\\C_{M_{K_2SO_4}}=\dfrac{0,2}{0,2+0,3562}\approx0,36\left(M\right)\end{matrix}\right.\)
\(n_{H_2SO_4}=1.0,2=0,2\left(mol\right)\\ H_2SO_4+2KOH\rightarrow K_2SO_4+2H_2O\\ 0,2.........0,4........0,2.......0,2\left(mol\right)\\ a.m_{ddKOH}=\dfrac{0,4.56.100}{6}=\dfrac{1120}{3}\left(g\right)\\ V_{ddKOH}=\dfrac{\dfrac{1120}{3}}{1,048}=\dfrac{140000}{393}\left(ml\right)\approx0,356\left(l\right)\)
\(b.C_{MddK_2SO_4}=\dfrac{0,2}{\dfrac{140000}{393}+0,2}\approx0,00056\left(M\right)\)
nHCl=0,3.2=0,6(mol)
a) PTHH: CuO +2 HCl -> CuCl2 + H2O
0,3_______________0,6___0,3(mol)
b) mCuO=0,3.80=24(g)
c) VddCuCl2=VddHCl=0,3(l)
=>CMddCuCl2=0,3/0,3=1(M)
d) m(muối)=0,3.135=40,5(g)
\(n_{CuO}=\dfrac{1.6}{80}=0.02\left(mol\right)\)
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
\(0.02.......0.02.................0.02\)
\(m_{H_2SO_4}=0.02\cdot98=1.96\left(g\right)\)
\(m_{dd_{H_2SO_4}}=\dfrac{1.96}{20\%}=9.8\left(g\right)\)
\(m_{\text{dung dịch sau phản ứng }}=1.6+9.8=11.4\left(g\right)\)
\(C\%_{CuSO_4}=\dfrac{0.02\cdot160}{11.4}=28.07\%\)
a) PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
b) Ta có: \(n_{H_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)
\(\Rightarrow n_{HCl}=0,1mol\) \(\Rightarrow C_{M_{HCl}}=\dfrac{0,1}{0,2}=0,5\left(M\right)\)
c) Theo PTHH: \(n_{Zn}=n_{H_2}=0,05mol\)
\(\Rightarrow m_{Zn}=0,05\cdot65=3,25\left(g\right)\)
\(\Rightarrow\%m_{Zn}=\dfrac{3,25}{8,37}\cdot100\%\approx38,83\%\) \(\Rightarrow\%m_{Cu}=61,17\%\)
nNaOH = 0,2 . 2,5 = 0,5 (mol)
PTHH:
CH3COOH + NaOH -> CH3COONa + H2O
Mol: 0,5 <--- 0,5 ---> 0,5
VddCH3COOH = 0,5/2 = 0,25 (l)
VddCH3COONa = 0,25 + 0,2 = 0,45 (l)
CMddCH3COONa = 0,5/,045 = 1,11M
a: \(n_{H_2SO_4}=0.25\cdot2=0.5\left(mol\right)\)
\(n_{Al_2O_3}=\dfrac{10.2}{27\cdot2+16\cdot3}=0.1\left(mol\right)\)
\(Al_2O_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O\)
0,1 0,5
Vì 0,1/1<0,5/3
nên Al2O3 hết, H2SO4 dư
=>Tính theo Al2O3
b:
\(Al_2O_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O\)
0,1 0,3 0,1
\(m_{H_2SO_4\left(pư\right)}=0.3\cdot98=29.4\left(g\right)\)
\(m_{muối}=0.1\left(54+3\cdot96\right)=34.2\left(g\right)\)
a, \(CuO+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Cu+H_2O\)
b, \(n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\)
Theo PT: \(n_{CH_3COOH}=2n_{CuO}=0,2\left(mol\right)\Rightarrow C_{M_{CH_3COOH}}=\dfrac{0,2}{0,2}=1\left(M\right)\)
c, \(n_{\left(CH_3COO\right)_2Cu}=n_{Cu}=0,1\left(mol\right)\Rightarrow m_{\left(CH_3COO\right)_2Cu}=0,1.182=18,2\left(g\right)\)