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a)
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
PTHH: Zn + 2HCl --> ZnCl2 + H2
0,2--->0,4---->0,2--->0,2
\(V_2=0,2.22,4=4,48\left(l\right)\)
\(V_1=\dfrac{0,4}{0,5}=0,8\left(l\right)\)
b)
\(C_{M\left(ZnCl_2\right)}=\dfrac{0,2}{0,8}=0,25M\)
c)
\(n_{H_2}=0,1\left(mol\right)\); \(n_{CuO}=\dfrac{32}{80}=0,4\left(mol\right)\)
PTHH: CuO + H2 --to--> Cu + H2O
Xét tỉ lệ: \(\dfrac{0,4}{1}>\dfrac{0,1}{1}\) => CuO dư, H2 hết
PTHH: CuO + H2 --to--> Cu + H2O
0,1<--0,1------>0,1
=> m = 32 - 0,1.80 + 0,1.64 = 30,4 (g)
TN1: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
Ta có: \(n_{Fe}=\dfrac{m_1}{56}\left(mol\right)\)
Theo PT: \(n_{H_2}=n_{Fe}=\dfrac{m_1}{56}\left(mol\right)\)
TN2: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)
Ta có: \(n_{Al}=\dfrac{m_2}{27}\left(mol\right)\)
Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}=\dfrac{m_2}{18}\left(mol\right)\)
Mà: \(V_2=1,5V_1\Rightarrow\dfrac{V_1}{V_2}=\dfrac{1}{1,5}=\dfrac{2}{3}\)
\(\Rightarrow\dfrac{n_1}{n_2}=\dfrac{n_{H_2\left(Fe\right)}}{n_{H_2\left(Al\right)}}=\dfrac{2}{3}\) \(\Rightarrow\dfrac{\dfrac{m_1}{56}}{\dfrac{m_2}{18}}=\dfrac{2}{3}\)
\(\Rightarrow\dfrac{m_1}{m_2}=\dfrac{56}{27}\)
\(n_{H_2SO_4}=0.6\left(mol\right)\)
\(4Fe^{\dfrac{+3}{4}}\rightarrow4Fe^{3+}+9e\)
\(x...................\dfrac{9}{4}x\)
\(S^{+6}+2e\rightarrow S^{+4}\)
\(0.6......1.2\)
Bảo toàn e :
\(\dfrac{9}{4}x=1.2\Rightarrow x=\dfrac{8}{15}\)
\(m=\dfrac{8}{15}\cdot232=123.7\left(g\right)\)
a, Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
PT: \(M+H_2SO_4\rightarrow MSO_4+H_2\)
Theo PT: \(n_M=n_{H_2}=0,2\left(mol\right)\)
\(\Rightarrow M_M=\dfrac{11,2}{0,2}=56\left(g/mol\right)\)
→ M là Fe.
b, Theo PT: \(n_{FeSO_4}=n_{H_2SO_4\left(pư\right)}=n_{H_2}=0,2\left(mol\right)\)
⇒ nH2SO4 dư = 0,5.1 - 0,2 = 0,3 (mol)
\(\Rightarrow\left\{{}\begin{matrix}C_{M_{H_2SO_4\left(dư\right)}}=\dfrac{0,3}{0,5}=0,6\left(M\right)\\C_{M_{FeSO_4}}=\dfrac{0,2}{0,5}=0,4\left(M\right)\end{matrix}\right.\)
c, Ta có: \(n_{FeSO_4.7H_2O}=n_{FeSO_4}=0,2\left(mol\right)\)
\(\Rightarrow m_{FeSO_4.7H_2O}=0,2.278=55,6\left(g\right)\)
PTHH: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)
\(FeSO_4+Ba\left(OH\right)_2\rightarrow BaSO_4\downarrow+Fe\left(OH\right)_2\downarrow\)
Ta có: \(n_{H_2SO_4}=0,3\cdot0,5=0,15\left(mol\right)=n_{Fe}=n_{H_2}=n_{Ba\left(OH\right)_2}\)
\(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=0,15\cdot56=8,4\left(g\right)\\V_{H_2}=0,15\cdot22,4=3,36\left(l\right)\\V_{Ba\left(OH\right)_2}=\dfrac{0,15}{1}=0,15\left(l\right)=150\left(ml\right)\end{matrix}\right.\)
*Bạn xem lại đề vì nếu FeSO4 p/ứ hết thì sẽ có nhiều hơn 41,7 gam kết tủa
H2SO4 dư bạn