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Bài 2:
\(a,n_{H_2}=\dfrac{1,12}{22,4}=0,05(mol)\\ PTHH:Mg+2HCl\to MgCl_2+H_2\\ MgO+2HCl\to MgCl_2+H_2O\\ \Rightarrow n_{Mg}=0,05(mol)\\ \Rightarrow m_{Mg}=24.0,05=1,2(g)\\ \Rightarrow m_{MgO}=9,2-1,2=8(g) b,\%_{Mg}=\dfrac{1,2}{9,2}.100\%=13,04\%\\ \Rightarrow \%_{MgO}=100\%-13,04\%=86,96\%\\ c,n_{MgO}=\dfrac{8}{40}=0,2(mol)\\ \Rightarrow \Sigma n_{HCl}=2n_{Mg}+2n_{MgO}=0,5(mol)\\ \Rightarrow \Sigma m_{HCl}=0,5.36,5=18,25(g)\\ \Rightarrow m_{dd_{HCl}}=\dfrac{18,25}{14,6\%}=125(g)\)
Câu 1:
a, - Tác dụng với HCl:
\(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(CuO+2HCl\rightarrow CuCl_2+H_2O\)
\(Al_2O_3+6HCl\rightarrow2AlCl_3+3H_2O\)
\(2Fe\left(OH\right)_3+6HCl\rightarrow2FeCl_3+3H_2O\)
- Tác dụng với H2SO4 loãng:
\(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
\(Al_2O_3+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O\)
\(2Fe\left(OH\right)_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+6H_2O\)
\(BaCl_2+H_2SO_4\rightarrow2HCl+BaSO_{4\downarrow}\)
b, - Chất sinh ra khí nhẹ hơn không khí và cháy được trong kk: Mg
- Chất sinh ra dd màu xanh lam: CuO.
- Chất sinh ra dd màu vàng nâu: Fe(OH)3.
- Chất sinh ra dd không màu: Al2O3.
- Chất sinh ra kết tủa trắng không tan trong nước và axit: BaCl2.
Bạn tham khảo nhé!
nSO3=8/80=0,1(mol)
pthh: SO3 + H2O -> H2SO4
nH2SO4=nSO3=0,1(mol) => mH2SO4(tạo sau)= 0,1.98=9,8(g)
mH2SO4(tổng)= 100.9,8% + 9,8=19,6(g)
mddH2SO4(sau)=8+100=108(g)
=>C%ddH2SO4(sau)= (19,6/108).100=18,148%
Câu 7:
a, \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)
\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)
b, \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)
Theo PT: \(n_{Fe}=n_{H_2}=0,1\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,1.56}{10}.100\%=56\%\\\%m_{CuO}=44\%\end{matrix}\right.\)
c, \(n_{CuO}=\dfrac{10-0,1.56}{80}=0,055\left(mol\right)\)
Theo PT: \(n_{H_2SO_4}=n_{Fe}+n_{CuO}=0,155\left(mol\right)\)
\(\Rightarrow C\%_{H_2SO_4}=\dfrac{0,155.98}{100}.100\%=15,19\%\)
d, Theo PT: \(\left\{{}\begin{matrix}n_{FeSO_4}=n_{Fe}=0,1\left(mol\right)\\n_{CuSO_4}=n_{CuO}=0,055\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{FeSO_4}=0,1.152=15,2\left(g\right)\\m_{CuSO_4}=0,055.160=8,8\left(g\right)\end{matrix}\right.\)
Câu 8:
a, \(CuCO_3+2HCl\rightarrow CuCl_2+CO_2+H_2O\)
b, \(n_{CO_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)
Theo PT: \(n_{CuCO_3}=n_{CO_2}=0,15\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{CuCO_3}=\dfrac{0,15.124}{20}.100\%=93\%\\\%m_{CuCl_2}=7\%\end{matrix}\right.\)
c, \(n_{HCl}=2n_{CO_2}=0,3\left(mol\right)\)
\(\Rightarrow C_{M_{HCl}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\)
Bài 11:
\(PTHH:2A+Cl_2\rightarrow2ACl\\TheoĐLBTKL:\\ m_A+m_{Cl_2}=m_{ACl}\\ \Leftrightarrow 9,2+m_{Cl_2}=23,4\\ \Rightarrow m_{Cl_2}=23,4-9,2=14,2\left(g\right)\\ n_{Cl_2}=\dfrac{14,2}{71}=0,2\left(mol\right)\\ n_A=2.0,2=0,4\left(mol\right)\\ M_A=\dfrac{9,2}{0,4}=23\left(\dfrac{g}{mol}\right)\\ \Rightarrow A\left(I\right):Natri\left(Na=23\right)\)
Câu 92:
\(a,PTHH:Zn+2HCl\to ZnCl_2+H_2\\ ZnO+2HCl\to ZnCl_2+H_2O\\ n_{H_2}=\dfrac{2,24}{22,4}=0,1(mol)\\ \Rightarrow n_{Zn}=0,1(mol)\\ \Rightarrow m_{Zn}=0,1.65=6,5(g)\\ \Rightarrow \%_{Zn}=\dfrac{6,5}{14,6}.100\%\approx44,52\%\\ \Rightarrow \%_{ZnO}=100\%-44,52\%=55,48\%\\ b,m_{ZnO}=14,6-6,5=8,1(g)\\ \Rightarrow n_{ZnO}=\dfrac{8,1}{81}=0,1(mol)\\ \Rightarrow \Sigma n_{HCl}=2n_{Zn}+2n_{ZnO}=0,4(mol)\\ \Rightarrow V_{dd_{HCl}}=\dfrac{0,4}{0,5}=0,8(mol)\)
Câu 93:
\(n_{H_2}=\dfrac{16,8}{22,4}=0,75(mol)\\ PTHH:Fe+H_2SO_4\to FeSO_4+H_2\\ \Rightarrow n_{Fe}=n_{H_2}=0,75(mol)\\ \Rightarrow m_{Fe}=0,75.56=42(g)\\ b,n_{H_2SO_4}=n_{H_2}=0,75(mol)\\ \Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,75}{0,25}=3M\\ c,n_{FeSO_4}=0,75(mol)\\ \Rightarrow m_{CT_{FeSO_4}}=0,75.152=114(g)\\ V_{dd_{FeSO_4}}=V_{dd_{H_2SO_4}}=250(ml)\\ \Rightarrow m_{dd_{FeSO_4}}=250.1,1=275(g)\\ \Rightarrow C\%_{FeSO_4}=\dfrac{114}{275}.100\%\approx41,45\%\)
\(d,m_{FeSO_4.5H_2O}=242.0,75=181,5(g)\)
Câu 6:
Gọi kim loại đó là \(R\)
\(\rightarrow Oxit:R_2O_3\)
Giả sử dd \(H_2SO_4\) phản ứng \(a\left(mol\right)\)
\(PTHH:R_2O_3+3H_2SO_4\rightarrow R_2\left(SO_4\right)_3+3H_2O\)
\(\left(mol\right)\) \(\dfrac{a}{3}\) \(a\) \(\dfrac{a}{3}\)
\(m_{ddH_2SO_4}=\dfrac{98a.100}{10}=980a\left(g\right)\)
\(C\%_{ddspu}=12,9\left(\%\right)\Leftrightarrow\dfrac{\left(2R+288\right).\dfrac{a}{3}}{\left(2R+48\right).\dfrac{a}{3}+980a}.100=12,9\\ \Leftrightarrow\dfrac{\dfrac{\left(2R+288\right)}{3}}{\dfrac{\left(2R+48\right)}{3}+980}.100=12,9\\ \Leftrightarrow R=56\left(Fe\right)\\ \rightarrow Oxit:Fe_2O_3\)
Câu 7:
\(a.n_{NaOH}=\dfrac{60.10\%}{40}=0,15\left(mol\right)\)
Đặt \(C\%_{HCl}=a\left(\%\right)\Rightarrow n_{HCl}=\dfrac{40a}{100.36,5}=\dfrac{4a}{365}\left(mol\right)\)
\(C\%_{NaCl}=5,85\%\Leftrightarrow\dfrac{m_{NaCl}}{60+40}.100=5,85\Leftrightarrow m_{NaCl}=5,85\left(g\right)\Leftrightarrow n_{NaCl}=0,1\left(mol\right)\)
\(PTHH:NaOH+HCl\rightarrow NaCl+H_2O\)
(mol) 0,1 0,1 0,1
Lúc này ta có: \(n_{HCl}=\dfrac{4a}{365}=0,1\Leftrightarrow a=9,125\left(\%\right)\)
Câu b làm tương tự!!!