\(n_{HCl}=0,1.0,1=0,01\left(mol\right);n_{HCl}=0,3.0,04=0,012\left(mol\right)\)

Dung dịch gồm H+ và Cl-

\(n_{H^+}=0,01+0,012=0,022\left(mol\right)\)

=> \(\left[H^+\right]=\dfrac{0,022}{0,4}=0,055M\)

\(n_{Cl^-}=0,01+0,012=0,022\left(mol\right)\)

=>\(\left[Cl^-\right]=\dfrac{0,022}{0,4}=0,055M\)

Trộn 100ml dung dịch HNO3 0.1M với 400ml dung dịch H2SO4 0.03M

\(n_{HNO_3}=0,1.0,1=0,01\left(mol\right);n_{H_2SO_4}=0,04.0,3=0,012\left(mol\right)\)

Dung dịch sau khi trộn gồm :

\(n_{H^+}=0,01+0,012.2=0,034\left(mol\right)\)

=> \(\left[H^+\right]=\dfrac{0,034}{0,5}=0,068M\)

\(n_{NO_3^-}=0,01\left(mol\right)\)

=>\(\left[NO_3^-\right]=\dfrac{0,01}{0,5}=0,02M\)

\(n_{SO_4^{2-}}=0,012\left(mol\right)\)

=> \(\left[SO_4^{2-}\right]=\dfrac{0,012}{0,5}=0,024M\)

1) \(n_{H^+}=n_{HCl}+2n_{H2SO4}\)

           = 0,0025 + 2.0,0025

           = 0,0075(mol)

 \(\Rightarrow\left[H^+\right]_{sau.khi.trộn}=\dfrac{0,0075}{0,1+0,05}=0,05M\)

 \(\Rightarrow pH=-log\left(0,05\right)\approx1,3\)

 Chúc bạn học tốt

2) \(n_{HCl}=0,5.0,04=0,02\left(mol\right)\)

 \(n_{NaOH}=0,5.0,06=0,03\left(mol\right)\)

 \(H^++OH^-\rightarrow H_2O\)

0,02   0,03

Xét tỉ lệ : \(0,02< 0,03\Rightarrow OH^-dư\)

 \(n_{OH^-\left(dư\right)}=0,03-0,02=0,01\left(mol\right)\)

 \(\Rightarrow\left[OH^-\right]=\dfrac{0,01}{0,04+0,06}=0,1M\) 

\(\Rightarrow pH=14+log\left(0,1\right)=13\)

 Chúc bạn học tốt

Đáp án B

n_OH-= 0,03 mol; n_Ba2+ = 0,01 mol

n_H+ = 0,035 mol; n_SO4(2-) = 0,015 mol

H⁺           + OH^-   → H₂O

0,035    0,03

n_{H+ dư} = 5.10^-3 mol; [H⁺] _dư = 5.10^-3/0,5 = 0,01 suy ra pH = 2

a)

$NaOH  + HCl \to NaCl + H_2O$
$OH^- + H^+ \to H_2O$

b)

$n_{HCl} = 0,1.0,01 = 0,001(mol)$
$n_{NaOH} = 0,2.0,5= 0,1(mol)$

$\Rightarrow$ NaOH dư, HCl hết

$n_{NaOH\ pư} = 0,001 \Rightarrow n_{NaOH\ dư} = 0,1 - 0,001 = 0,099(mol)$

$\Rightarrow [OH^-] = \dfrac{0,099}{0,1 + 0,2} = 0,33M$
$\Rightarrow pOH = -log(0,33) = 0,48 $

$pH = 14 - pOH = 14 - 0,48 = 13,52$

\(n_{KOH}=0.1\cdot1=0.1\left(mol\right)\)

\(n_{HCl}=0.1\cdot0.5=0.05\left(mol\right)\)

\(KOH+HCl\rightarrow KCl+H_2O\)

\(0.05.......0.05.......0.05\)

Dung dịch D : 0.05 (mol) KOH , 0.05 (mol) KCl

\(\left[K^+\right]=\dfrac{0.05+0.05}{0.1+0.1}=0.5\left(M\right)\)

\(\left[Cl^-\right]=\dfrac{0.05}{0.2}=0.25\left(M\right)\)

\(\left[OH^-\right]=\dfrac{0.05}{0.2}=0.25\left(M\right)\)

\(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)

\(0.05.........0.025\)

\(V_{dd_{H_2SO_4}}=\dfrac{0.025}{1}=0.025\left(l\right)\)

1) Ta coi H₂SO₄ điện li mạnh hai nấc.

\(n_{H_2SO_4}=0,03\) mol; \(n_{HCl}=0,16\) mol

\(H_2SO_4\rightarrow2H^++SO_4^-\)

0,03 -----> 0,06 ---> 0,03

\(HCl\rightarrow H^++Cl^-\)

0,16 --> 0,16 --> 0,16

\(\Rightarrow n_{H^+}=2n_{H_2SO_4}+n_{HCl}=2.0,03+0,16=0,22\) mol

+ \(\left[H^+\right]=\dfrac{0,22}{1+4}=0,044\) mol/lít

\(\Rightarrow pH=-lg\left[H^+\right]=-lg0,044=1,36\)

+ \(\left[SO_4^-\right]=\dfrac{0,03}{1+4}=6.10^{-3}\) mol/lít

+ \(\left[Cl^-\right]=\dfrac{0,16}{1+4}=0,032\) mol/lít

2) + \(n_{OH^-}=n_{NaOH}+2n_{Ba\left(OH\right)_2}=0,12\) mol

\(\Rightarrow\left[OH^-\right]=\dfrac{0,12}{5}=0,024\) mol/lít

\(\Rightarrow pOH=-lg\left[OH^-\right]=1,62\)

\(\Rightarrow pH=14-pOH=12,38\)

+ \(n_{Na^+}=n_{NaOH}=0,06\) mol

\(\Rightarrow\left[Na^+\right]=\dfrac{0,06}{5}=0,012\) mol/lít

+ \(n_{Ba^{2+}}=n_{Ba\left(OH\right)_2}=0,03\) mol

\(\Rightarrow\left[Ba^{2+}\right]=\dfrac{0,03}{5}=0,006\) mol/lít

[K+]=[Cl-]=0,25M

[KOH dư]=0,25M

b)   2KCl   +    H₂SO₄    ----------->K₂SO₄   + 2HCl

  0,05(mol)---->0,025(mol)

=>v_H2SO4=\(\frac{0,025}{1}\)=0,025(lít)

c)pH=-log(0,25)=0,602

(câu c mình không chắc chắn lắm nha bạn!!!)

Cho mình hỏi s [K+]=[Cl-]=0,25M đc z. Mình chưa hiểu lắm