Cho 6,5g Zinc vào dung dịch axit HCL, thu được muối và khí hydrogen. Tính khối lượng muối tạo thành và thể tích khí hydrogen ở đkc?
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\(n_{Zn}=\dfrac{26}{65}=0,4\left(mol\right)\)
PTHH :
\(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
0,4 0,8 0,4 0,4
\(a,m_{HCl}=0,8.36,5=29,2\left(g\right)\)
\(b,V_{H_2}=n.22,4=0,4.24,79=9,916\left(l\right)\)
\(c,m_{ZnCl_2}=0,4.136=21,76\left(g\right)\)
`Zn+2HCl->ZnCl_2+H_2↑`
`a,n_(Zn)=26/65=0,4(mol)`
`=>n_(HCl)=2n_(Zn)=2.0,4=0,8(mol)`
`=>m_(HCl)=0,8.36,5=29,2(g)`
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`b,` Từ câu `a,` suy ra `n_(H_2)=0,4(mol)`
`=>V_(H_2(đkc))=n_(H_2).24,79=0,4.24,79=9,913(l)`
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`c,` Từ câu `a,` ta suy ra `n_(ZnCl_2)=0,4(mol)`
`=>m_(ZnCl_2)=0,4.136=21,76(g)`
\(n_{H_2\left(đkc\right)}=\dfrac{2,479}{24,79}=0,1\left(mol\right)\\ 2Al+6HCl\rightarrow2AlCl_3+3H_2\\ n_{Al}=n_{AlCl_3}=\dfrac{2}{3}.n_{H_2}=\dfrac{2}{3}.0,1=\dfrac{1}{15}\left(mol\right)\\ \Rightarrow m_{Al}=27.\dfrac{1}{15}=1,8\left(g\right)\\ m_{AlCl_3}=\dfrac{1}{15}.133,5=8,9\left(g\right)\)
\(n_{H_2}=\dfrac{2,479}{24,79}=0,1\left(mol\right)\)
PTHH: 2Al + 6HCl --> 2AlCl3 + 3H2
\(\dfrac{1}{15}\)<--------------\(\dfrac{1}{15}\)<-----0,1
=> \(m_{Al}=\dfrac{1}{15}.27=1,8\left(g\right)\)
=> \(m_{AlCl_3}=\dfrac{1}{15}.133,5=8,9\left(g\right)\)
a, \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Theo PT: \(n_{ZnCl_2}=n_{H_2}=n_{Zn}=0,2\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,2.24,79=4,958\left(l\right)\)
\(m_{ZnCl_2}=0,2.136=27,2\left(g\right)\)
b, \(n_{HCl}=2n_{Zn}=0,4\left(mol\right)\)
\(\Rightarrow m_{HCl}=0,4.36,5=14,6\left(g\right)\Rightarrow m_{ddHCl}=\dfrac{14,6}{7,3\%}=200\left(g\right)\)
\(n_{Zn}=\dfrac{9,75}{65}=0,15\left(mol\right)\\
pthh:Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)
0,15 0,15 0,15 0,15
\(V_{H_2}=0,15.22,4=3,36L\\
m_{H_2SO_4}=0,15.98=14,7\left(g\right)\\
m_{ZnSO_4}=161.0,15=24,15g\\
\)
\(n_{CuO}=\dfrac{6}{80}=0,075\left(mol\right)\\
pthh:CuO+H_2\underrightarrow{t^o}Cu+H_2O\\
LTL:0,075< 0,15\)
=> H2 dư
\(n_{Cu}=n_{CuO}=0,075\left(mol\right)\\
m_{Cu}=0,075.64=4,8g\)
\(a.Mg+2HCl\rightarrow MgCl_2+H_2\\ b.n_{Mg}=\dfrac{4,8}{24}=0,2mol\\ Mg+2HCl\rightarrow MgCl_2+H_2\)
0,2 0,4 0,2 0,2
\(V_{H_2}=0,2.24,79=4,958l\\ c.m_{MgCl_2}=0,2.95=19g\\ d.C_{M_{HCl}}=\dfrac{0,4}{0,3}=\dfrac{4}{3}M\)
a, \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)
_____0,2____0,4___________0,2 (mol)
\(\Rightarrow m_{HCl}=0,4.36,5=14,6\left(g\right)\)
b, \(V_{H_2}=0,2.24,79=4,958\left(l\right)\)
c, \(Fe_2O_3+3H_2\underrightarrow{t^o}2Fe+3H_2O\)
____________0,2__2/15 (mol)
\(\Rightarrow m_{Fe}=\dfrac{2}{15}.56=\dfrac{112}{15}\left(g\right)\)
Số mol của 13 gam Zn:
\(n_{Zn}=\dfrac{m}{M}=\dfrac{13}{65}=0,2\left(mol\right)\)
PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)
1 : 2 : 1 : 1 (g)
0,2\(\rightarrow\) 0,4 : 0,2 : 0,2 (mol)
a,Khối lượng của 0,4 mol HCl:
\(m_{HCl}=n.M=0,4.36,5=14,6\left(g\right)\)
b, Thể tích khí H2:
\(V_{H_2}=n.24,79=0,2.24,79=4,958\left(l\right)\)
\(3H_2+Fe_2O_3\underrightarrow{t^o}2Fe+3H_2O\)
Khối lượng của \(\dfrac{2}{15}\) mol Fe:
\(n_{Fe}=\dfrac{m}{M}=\dfrac{2}{\dfrac{15}{56}}\approx7,5\left(g\right)\)
\(n_{Zn}=\dfrac{3,25}{65}=0,05\left(mol\right)\)
PTHH: Zn + 2HCl ---> ZnCl2 + H2
0,05-->0,1------>0,05--->0,05
FeO + H2 --to--> Fe + H2O
0,05------>0,05
=> \(\left\{{}\begin{matrix}m_{ZnCl_2}=0,05.136=6,8\left(g\right)\\V_{H_2}=0,05.24,79=1,2395\left(l\right)\\m_{Fe}=0,05.56=2,8\left(g\right)\end{matrix}\right.\)
\(n_{Zn}=\dfrac{3,25}{65}=0,05\left(mol\right)\\
pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\)
0,05 0,05 0,05
\(m_{ZnCl_2}=0,05.136=6,8\left(g\right)\\
V_{H_2}=0,05.24,79=1,2395l\)
\(FeO+H_2\underrightarrow{t^o}Fe+H_2O\)
0,05 0,05 0,05
\(m_{Fe}=0,05.56=2,8g\)
\(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\\ Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{ZnCl_2}=n_{H_2}=n_{Zn}=0,1\left(mol\right)\\ \Rightarrow m_{ZnCl_2}=136.0,1=13,6\left(g\right);V_{H_2\left(đkc\right)}=0,1.22,4=2,479\left(l\right)\)