a) mHCl(ddC)= 9,125+ 5,475= 14,6(g) => nHCl= 0,4(mol)

CMddHCl(ddC)= 0,4/2=0,2(M)

b) Gọi a,b lần lượt là thể thích dd HCl A và dd HCl B. (a,b>0) (lít)

nHCl(ddA)= 0,25(mol); nHCl(ddB)=0,15(mol)

Tổng thể tích ddA và dd B bằng thể tích ddC:

=>a+b=2(1)

Mặt khác: CMddA - CMddB=0,4

<=> 0,25/a - 0,15/b=0,4 (2)

Từ (1), (2) ta giải được: a=0,5 ; b=1,5 

=> CMddA= 0,25/0,5=0,5(M)

CMddB=0,15/1,5=0,1(M)

a,nA=\(\dfrac{18,25}{36,5}\)=0,5(mol)

nB=\(\dfrac{10,95}{36,5}\)=0,3(mol)

→nC=0,3+0,5=0,8(mol)

→CM(C)=\(\dfrac{0,8}{2}\)=0,4M

b,CM(A)=\(\dfrac{0,5}{V1}\)

CM(B)=\(\dfrac{0,3}{V2}\)

→\(\dfrac{0,5}{V1}\)=\(\dfrac{0,3}{V2}\)=0,8

=>V1=0,625  l

=>V2=0,375 l 

=>CmV1=\(\dfrac{0,5}{0,625}\)=0,8M

=>CmV2=\(\dfrac{0,3}{0,375}\)=0,8M

\(a,n_A=\dfrac{18,25}{36,5}=0,5\left(mol\right)\\ n_B=\dfrac{10,95}{36,5}=0,3\left(mol\right)\)

\(\rightarrow n_C=0,3+0,5=0,8\left(mol\right)\\ \rightarrow C_{M\left(C\right)}=\dfrac{0,8}{2}=0,4M\)

\(b,C_{M\left(A\right)}=\dfrac{0,5}{V_1}\\ C_{M\left(B\right)}=\dfrac{0,3}{V_2}\\ \rightarrow\dfrac{0,5}{V_1}:\dfrac{0,3}{V_2}=0,8\\ \rightarrow\dfrac{0,5}{V_1}=\dfrac{0,24}{V_2}=\dfrac{0,5+0,24}{V_1+V_2}=\dfrac{0,74}{2}=0,37\\ \rightarrow\left\{{}\begin{matrix}V_1=\dfrac{0,5}{0,34}=1,4\left(l\right)\\V_2=\dfrac{0,24}{0,34}=0.6\left(l\right)\end{matrix}\right.\\ \rightarrow\left\{{}\begin{matrix}C_{M\left(A\right)}=\dfrac{0,5}{1,4}=0,36M\\C_{M\left(B\right)}=\dfrac{0,5}{0,6}=0,83M\end{matrix}\right.\)

a) \(n_{HCl\left(A\right)}=\dfrac{7,3}{36,5}=0,2\left(mol\right)\)

\(n_{HCl\left(B\right)}=\dfrac{58,4}{36,5}=1,6\left(mol\right)\)

=> \(n_{HCl\left(C\right)}=0,2+1,6=1,8\left(mol\right)\)

=> \(C_{M\left(C\right)}=\dfrac{1,8}{3}=0,6M\)

b) 
\(C_{M\left(A\right)}=\dfrac{0,2}{V_1}M\)

\(C_{M\left(B\right)}=\dfrac{1,6}{V_2}M\)

=> \(\dfrac{1,6}{V_2}-\dfrac{0,2}{V_1}=0,6\)

=> \(\dfrac{1,6}{3-V_1}-\dfrac{0,2}{V_1}=0,6\)

=> \(1,6.V_1-0,2\left(3-V_1\right)=0,6.V_1.\left(3-V_1\right)\)

=> \(1,6.V_1-0,6+0,2.V_1=1,8.V_1-0,6.V_1^2\)

=> \(0,6.V_1^2=0,6\)

=> V₁ = 1 (l)

=> V₂ = 2 (l)

\(C_{M\left(A\right)}=\dfrac{0,2}{1}=0,2M\)

\(C_{M\left(B\right)}=\dfrac{1,6}{2}=0,8M\)

n_HCl = V₁ mol

n _NaOH = 2V₂ mol

Trường hợp 1: Dung dịch X chứa HCl dư

HCl + NaOH → NaCl + H₂O

2V₂<----2V₂

3HCl + Al(OH)₃ → AlCl₃ + 3H₂O

3a<-------a

=> n_HCl  = 2V­₂ + 3a = V₁

Trường hợp 2: Dung dịch X chứa NaOH

HCl + NaOH → NaCl + H₂O

V₁------>V₁

Al(OH)₃ + NaOH → NaAlO₂ + 2H₂O

a------------> a

n _NaOH = V₁ + a = 2V₂

TN1: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

Ta có: \(n_{Fe}=\dfrac{m_1}{56}\left(mol\right)\)

Theo PT: \(n_{H_2}=n_{Fe}=\dfrac{m_1}{56}\left(mol\right)\)

TN2: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\)

Ta có: \(n_{Al}=\dfrac{m_2}{27}\left(mol\right)\)

Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}=\dfrac{m_2}{18}\left(mol\right)\)

Mà: \(V_2=1,5V_1\Rightarrow\dfrac{V_1}{V_2}=\dfrac{1}{1,5}=\dfrac{2}{3}\)

\(\Rightarrow\dfrac{n_1}{n_2}=\dfrac{n_{H_2\left(Fe\right)}}{n_{H_2\left(Al\right)}}=\dfrac{2}{3}\) \(\Rightarrow\dfrac{\dfrac{m_1}{56}}{\dfrac{m_2}{18}}=\dfrac{2}{3}\)

\(\Rightarrow\dfrac{m_1}{m_2}=\dfrac{56}{27}\)

a)

\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)

PTHH: Zn + 2HCl --> ZnCl₂ + H₂

            0,2--->0,4---->0,2--->0,2

\(V_2=0,2.22,4=4,48\left(l\right)\)

\(V_1=\dfrac{0,4}{0,5}=0,8\left(l\right)\)

b)

\(C_{M\left(ZnCl_2\right)}=\dfrac{0,2}{0,8}=0,25M\)

c)

\(n_{H_2}=0,1\left(mol\right)\); \(n_{CuO}=\dfrac{32}{80}=0,4\left(mol\right)\)

PTHH: CuO + H₂ --t^o--> Cu + H₂O

Xét tỉ lệ: \(\dfrac{0,4}{1}>\dfrac{0,1}{1}\) => CuO dư, H₂ hết

PTHH: CuO + H₂ --t^o--> Cu + H₂O

              0,1<--0,1------>0,1

=> m = 32 - 0,1.80 + 0,1.64 = 30,4 (g)

PTHH: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)

            \(FeSO_4+Ba\left(OH\right)_2\rightarrow BaSO_4\downarrow+Fe\left(OH\right)_2\downarrow\)

Ta có: \(n_{H_2SO_4}=0,3\cdot0,5=0,15\left(mol\right)=n_{Fe}=n_{H_2}=n_{Ba\left(OH\right)_2}\)

\(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=0,15\cdot56=8,4\left(g\right)\\V_{H_2}=0,15\cdot22,4=3,36\left(l\right)\\V_{Ba\left(OH\right)_2}=\dfrac{0,15}{1}=0,15\left(l\right)=150\left(ml\right)\end{matrix}\right.\)

*Bạn xem lại đề vì nếu FeSO₄ p/ứ hết thì sẽ có nhiều hơn 41,7 gam kết tủa

H2SO4 dư bạn