Vì m_{hh KL} giảm = 6,5g và H₂SO₄ dư nên  ta chắc chắn 1 KL PƯ hết và 1 KL còn "nguyên xi"

OK vì KL hóa trị 2 nên n_x=n_H2=0,1 mol

suy ra M_x=6,5 ÷ 0,1 = 65 => kẽm Zn OK

tương tự m_y=m_{hh KL dư} = 66,6-66,5 = 0,16 gam

n_y=n_SO2=0,16÷64 mol

ok vậy M_y=0,16÷(0,16÷64)= 64 => Đồng Cu ok nhá

\(n_{H_2}=\dfrac{2,464}{22,4}=0,11mol\)

\(\left\{{}\begin{matrix}Al:x\left(mol\right)\\Fe:y\left(mol\right)\end{matrix}\right.\Rightarrow Muối\left\{{}\begin{matrix}Al_2\left(SO_4\right)_3\\FeSO_4\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}BTe:3x+2y=2n_{H_2}=0,22\\\dfrac{x}{2}\cdot342+y\cdot152=14,44\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}x=0,04mol\\y=0,05mol\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{Al}=0,04\cdot27=1,08g\\m_{Fe}=0,05\cdot56=2,8g\end{matrix}\right.\)

\(Al_2\left(SO_4\right)_3+3BaCl_2\rightarrow2AlCl_3+3BaSO_4\downarrow\)

0,02                                                   0,06

\(FeSO_4+BaCl_2\rightarrow BaSO_4\downarrow+FeCl_2\)

0,05                          0,05

\(\Rightarrow\Sigma n_{\downarrow}=0,06+0,05=0,11\Rightarrow m_{BaSO_4}=x=25,63g\)

H₂ bay ra từ H₂SO₄

do đó n_H2SO4 = n_{H2 =} 0,1 mol

m_{dd_H2SO4} = 0,1.98÷10% = 98 gam

OK bảo toàn kL:

m_{dd sau PƯ}= m_{dd_H2SO4} + m_{hh_KL} - m_H2 = 98+3,68-0,1×2= 101,48

ok 101,48

\(Đặt:nMg=a\left(mol\right),n_{MgCO_3}=b\left(mol\right)\)

\(n_{khí}=\dfrac{6.72}{22.4}=0.3\left(mol\right)\)

\(Mg+2HCl\rightarrow MgCl_2+H_2\)

\(a................a.......a\)

\(MgCO_3+2HCl\rightarrow MgCl_2+CO_2+H_2O\)

\(b....................b........b\)

\(m_X=24a+84b=13.2\left(g\right)\left(1\right)\)

\(n_{khí}=a+b=0.3\left(mol\right)\left(2\right)\)

\(\left(1\right),\left(2\right):a=0.2,b=0.1\)

\(m_{Mg}=0.2\cdot24=4.8\left(g\right),m_{MgCO_3}=0.1\cdot84=8.4\left(g\right)\)

\(m_{ddB}=13.2+200-0.2\cdot2-0.1\cdot44=208.4\left(g\right)\)

\(m_{MgCl_2}=0.3\cdot95=28.5\left(g\right)\)

\(C\%MgCl_2=\dfrac{28.5}{208.4}\cdot100\%=13.67\%\)

Gọi n Fe = a (mol )

       n Mg = b (mol )  (a,b > 0)

--> 56a+24b = 13,2 

\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)

a            2a           a           a

\(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)

b             2b             b            b

----> a+b=0,35 

Ta có hệ Pt :

\(\left\{{}\begin{matrix}56a+24b=13,2\\a+b=0,35\end{matrix}\right.\)

Giải hệ PT , ta có : 

a= 0,15 

b = 0,2 (mol )

\(V_{HClđủ}=\left(0,15.2+0,2.2\right):0,5=1,4\left(l\right)\)

\(a,m_{Fe}=0,15.56=8,4\left(g\right)\)

\(m_{Mg}=0,2.24=4,8\left(g\right)\)

\(\%m_{Fe}=\dfrac{8,4}{13,2}.100\%\approx63,64\%\)

\(\%m_{Mg}=\dfrac{4,8}{13,2}.100\%\approx36,36\%\)

\(b,m_{FeCl_2}=0,15.127=19,05\left(g\right)\)

\(m_{MgCl_2}=0,2.95=19\left(g\right)\)

\(c,HCl+NaOH\rightarrow NaCl+H_2O\)

    0,2        0,2 

\(m_{NaOH}=\dfrac{100.8}{100}=8\left(g\right)\)

\(n_{NaOH}=\dfrac{8}{40}=0,2\left(mol\right)\)

\(V_{HCldư}=\dfrac{n}{C_M}=\dfrac{0,2}{0,5}=0,4\left(l\right)\)

\(V_{HCl}=V_{HClđủ}+V_{HCldư}=1,4+0,4=1,8\left(l\right)\)