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Bài 4 :
\(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
a) Pt : \(Zn+2HCl\rightarrow ZnCl_2+H_2|\)
1 2 1 1
0,2 0,4 0,2 0,2
b) \(n_{H2}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
\(V_{H2\left(dktc\right)}=0,2.22,4=4,48\left(l\right)\)
c) \(n_{HCl}=\dfrac{0,2.2}{1}=0,4\left(mol\right)\)
⇒ \(m_{HCl}=0,4.36,5=14,6\left(g\right)\)
\(C_{ddHCl}=\dfrac{14,6.100}{100}=14,6\)0/0
d) \(n_{ZnCl2}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)
⇒ \(m_{ZnCl2}=0,2.136=27,2\left(g\right)\)
\(m_{ddspu}=13+100-\left(0,2.2\right)=112,6\left(g\right)\)
\(C_{ZnCl2}=\dfrac{27,2.100}{112,6}=24,16\)0/0
Chúc bạn học tốt
Bài 3 :
\(n_{Mg}=\dfrac{12}{24}=0,5\left(mol\right)\)
a) Pt : \(Mg+H_2SO_4\rightarrow MgSO_4+H_2|\)
1 1 1 1
0,5 0,5 0,5 0,5
b) \(n_{H2}=\dfrac{0,5.1}{1}=0,5\left(mol\right)\)
\(V_{H2\left(dktc\right)}=0,5.22,4=11,2\left(l\right)\)
c) \(n_{H2SO4}=\dfrac{0,5.1}{1}=0,5\left(mol\right)\)
⇒ \(m_{H2SO4}=0,5.98=49\left(g\right)\)
\(C_{ddH2SO4}=\dfrac{49.100}{200}=24,5\)0/0
d) \(n_{MgSO4}=\dfrac{0,5.1}{1}=0,5\left(mol\right)\)
⇒ \(m_{MgSO4}=0,5.120=60\left(g\right)\)
\(m_{ddspu}=12+200-\left(0,5.2\right)=211\left(g\right)\)
\(C_{MgSO4}=\dfrac{60.100}{211}=28,44\)0/0
Chúc bạn học tốt
Bài 14:
Ta có: \(n_{BaCO_3}=\dfrac{39,4}{197}=0,2\left(mol\right)\)
PT: \(BaCO_3+2HCl\rightarrow BaCl_2+CO_2+H_2O\)
a, \(n_{CO_2}=n_{BaCO_3}=0,2\left(mol\right)\Rightarrow V_{CO_2}=0,2.24,79=4,958\left(l\right)\)
b, Sửa đề: tính khối lượng dung dịch HCl → tính nồng độ % dd HCl.
\(n_{HCl}=2n_{BaCO_3}=0,4\left(mol\right)\Rightarrow m_{ddHCl}=\dfrac{0,4.36,5}{100}.100\%=14,6\%\)
c, \(n_{BaCl_2}=n_{BaCO_3}=0,2\left(mol\right)\)
Ta có: m dd sau pư = 39,4 + 100 - 0,2.44 = 130,6 (g)
\(\Rightarrow C\%_{BaCl_2}=\dfrac{0,2.208}{130,6}.100\%\approx31,85\%\)
Bài 12:
Ta có: \(n_{MgCO_3}=\dfrac{25,2}{84}=0,3\left(mol\right)\)
PT: \(MgCO_3+2HCl\rightarrow MgCl_2+CO_2+H_2O\)
a, Theo PT: \(n_{CO_2}=n_{MgCO_3}=0,3\left(mol\right)\)
\(\Rightarrow V_{CO_2}=0,3.24,79=7,437\left(l\right)\)
b, Ta có: m dd sau pư = 25,2 + 200 - 0,3.44 = 212 (g)
Theo PT: \(n_{MgCl_2}=n_{MgCO_3}=0,3\left(mol\right)\)
\(\Rightarrow C\%_{MgCl_2}=\dfrac{0,3.95}{212}.100\%\approx13,44\%\)
Bài 13:
Ta có: \(n_{CaCO_3}=\dfrac{10}{100}=0,1\left(mol\right)\)
PT: \(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)
1. \(n_{CO_2}=n_{CaCO_3}=0,1\left(mol\right)\) \(\Rightarrow V_{CO_2}=0,1.24,79=2,479\left(l\right)\)
2. \(n_{HCl}=2n_{CaCO_3}=0,2\left(mol\right)\Rightarrow m_{ddHCl}=\dfrac{0,2.36,5}{7,3\%}=100\left(g\right)\)
3. Ta có: m dd sau pư = 10 + 100 - 0,1.44 = 105,6 (g)
Theo PT: \(n_{CaCl_2}=n_{CaCO_3}=0,1\left(mol\right)\)
\(\Rightarrow C\%_{CaCl_2}=\dfrac{0,1.111}{105,6}.100\%\approx10,51\%\)
Ta có: \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
a. PTHH: Zn + H2SO4 ---> ZnSO4 + H2
b. Theo PT: \(n_{H_2}=n_{Zn}=0,1\left(mol\right)\)
=> \(V_{H_2}=0,1.22,4=2,24\left(lít\right)\)
c. Theo PT: \(n_{H_2SO_4}=n_{Zn}=0,1\left(mol\right)\)
=> \(m_{H_2SO_4}=0,1.98=9,8\left(g\right)\)
Ta có: \(C_{M_{H_2SO_4}}=\dfrac{9,8}{m_{dd_{H_2SO_4}}}.100\%=25\%\)
=> \(m_{dd_{H_2SO_4}}=39,2\left(g\right)\)
Ta có: \(m_{H_2}=0,1.2=0,2\left(g\right)\)
=> \(m_{dd_{ZnSO_4}}=6,5+39,2-0,2=45,5\left(g\right)\)
Theo PT: \(n_{ZnSO_4}=n_{Zn}=0,1\left(mol\right)\)
=> \(m_{ZnSO_4}=0,1.161=16,1\left(g\right)\)
=> \(C_{\%_{ZnSO_4}}=\dfrac{16,1}{45,5}.100\%=35,4\%\)
a) \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)
\(m_{H_2SO_4}=147.10\%=14,7\left(g\right)\Rightarrow n_{H_2SO_4}=\dfrac{14,7}{98}=0,15\left(mol\right)\)
PTHH: Zn + H2SO4 → ZnSO4 + H2
Mol: 0,1 0,1 0,1 0,1
Ta có: \(\dfrac{0,1}{1}< \dfrac{0,15}{1}\) ⇒ Zn hết, H2SO4 dư
b) \(V_{H_2}=0,1.22,4=2,24\left(l\right)\)
c) mdd sau pứ = 6,5 + 147 - 0,1.2 = 153,3 (g)
\(C\%_{ddZnSO_4}=\dfrac{0,1.161.100\%}{153,3}=10,502\%\)
\(C\%_{ddH_2SO_4dư}=\dfrac{\left(0,15-0,1\right).98.100\%}{153,3}=3,196\%\)
\(n_{Al}=\dfrac{10,8}{27}=0,4(mol)\\ a,2Al+3H_2SO_4\to Al_2(SO_4)_3+3H_2\\ \Rightarrow n_{H_2}=n_{H_2SO_4}=0,6(mol);n_{Al_2(SO_4)_3}=0,2(mol)\\ b,V_{H_2}=0,6.22,4=13,44(l)\\ c,m_{dd_{H_2SO_4}}=\dfrac{0,6.98}{9,8\%}=600(g)\\ \Rightarrow C\%_{Al_2(SO_4)_3}=\dfrac{0,2.342}{10,8+600-0,6.2}.100\%=11,22\%\)
\(n_{CaCO_3}=\dfrac{6}{100}=0,06mol\)
\(n_{CH_3COOH}=\dfrac{200}{60}=3,33mol\)
\(2CH_3COOH+CaCO_3\rightarrow\left(CH_3COO\right)_2Ca+CO_2+H_2O\)
3,33 > 0,06 ( mol )
0,06 0,06 0,06 ( mol )
\(V_{CO_2}=0,06.22,4=1,344l\)
\(m_{\left(CH_3COO\right)_2Ca}=0,06.158=9,48g\)
\(m_{ddspứ}=200+6-0,06.12=205,28g\)
\(C\%_{\left(CH_3COO\right)_2Ca}=\dfrac{9,48}{205,28}.100=4,61\%\)
\(n_{CaCO_3}=\dfrac{6}{100}=0,06\left(mol\right)\\
n_{CH_3C\text{OO}H}=\dfrac{200}{60}=3,3\left(G\right)\\
pthh:CaCO_3+2CH_3C\text{OO}H\rightarrow Ca\left(CH_3C\text{OO}\right)_2+H_2O+CO_2\)
LTL : \(\dfrac{0,06}{1}< \dfrac{3,3}{2}\)
=> CaCO3 hết
theo pthh : \(n_{CO_2}=n_{CaCO_3}=0,06\left(mol\right)\)
\(\Rightarrow V_{CO_2}=0,06.22,4=1,344\left(l\right)\)
\(\Rightarrow C\%=\dfrac{6}{200}.100\%=3\%\dfrac{\dfrac{ }{ }C\dfrac{ }{ }\dfrac{ }{ }\dfrac{ }{ }\dfrac{ }{ }}{ }\%\)
Ta có: \(n_{Na_2SO_3}=\dfrac{12,6}{126}=0,1\left(mol\right)\)
a. PTHH: Na2SO3 + 2HCl ---> 2NaCl + SO2 + H2O
Theo PT: \(n_{SO_2}=n_{Na_2CO_3}=0,1\left(mol\right)\)
=> \(V_{SO_2}=0,1.22,4=2,24\left(lít\right)\)
b. Theo PT: \(n_{HCl}=2.n_{SO_2}=2.0,1=0,2\left(mol\right)\)
=> \(m_{HCl}=0,2.36,5=7,3\left(g\right)\)
=> \(C_{\%_{HCl}}=\dfrac{7,3}{150}.100\%=4,87\%\)
c. Ta có: \(m_{dd_{NaCl}}=n_{Na_2SO_{3_{PỨ}}}=50\left(g\right)\)
Theo PT: \(n_{NaCl}=n_{HCl}=0,2\left(mol\right)\)
=> \(m_{NaCl}=0,2.58,5=11,7\left(g\right)\)
=> \(C_{\%_{NaCl}}=\dfrac{11,7}{50}.100\%=23,4\%\)
a) $n_{Na_2SO_3} = \dfrac{37,8}{126} = 0,3(mol)$
$n_{H_2SO_4} = \dfrac{200.19,6\%}{98} = 0,4(mol)$
$Na_2SO_3 + H_2SO_4 \to Na_2SO_4 + SO_2 + H_2O$
Ta thấy $n_{Na_2SO_3} : 1 < n_{H_2SO_4} :1$ nên $H_2SO_4$ dư
$n_{SO_2} = n_{Na_2SO_3} = 0,3(mol) \Rightarrow V_{SO_2} = 0,3.22,4 = 6,72(lít)$
b) $m_{dd\ sau\ pư} = 37,8 +200 - 0,3.64 = 218,6(gam)$
$n_{Na_2SO_4} = n_{H_2SO_4\ pư} = 0,3(mol) \Rightarrow n_{H_2SO_4\ dư} = 0,4 - 0,3 = 0,1(mol)$
$C\%_{Na_2SO_4} = \dfrac{0,3.142}{218,6}.100\% = 19,49\%$
$C\%_{H_2SO_4} = \dfrac{0,1.98}{218,6}.100\% = 4,48\%$