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\(a,PTHH:S+O_2\underrightarrow{t^o}SO_2\left(1\right)\)
\(n_S=\dfrac{m}{M}=\dfrac{9,6}{32}=0,3\left(mol\right)\)
\(Theo.PTHH\left(1\right):n_O=n_S=0,3\left(mol\right)\)
\(PTHH:2KClO_3\underrightarrow{t^o}2KCl+3O_2\\ Theo.PTHH\left(2\right):n_{KClO_3}=\dfrac{2}{3}.n_{O_2}=\dfrac{2}{3}.0,3=0,2\left(mol\right)\\ m_{KClO_3}=n.M=0,2.122,5=24,5\left(g\right)\)
\(b,V_{O_2\left(đktc\right)}=n.22,4=0,2.22,4=4,48\left(l\right)\\ \Rightarrow V_{kk\left(đktc\right)}=5.V_{O_2}=5.4,48=22,4\left(l\right)\)
a.b.\(n_{Mg}=\dfrac{m}{M}=\dfrac{6,4}{24}=\dfrac{4}{15}mol\)
\(2Mg+O_2\rightarrow\left(t^o\right)2MgO\)
4/15 2/15 ( mol )
\(V_{O_2}=n.22,4=\dfrac{2}{15}.22,4=\dfrac{224}{75}l\)
c.\(2KMnO_4\rightarrow\left(t^o\right)K_2MnO_4+MnO_2+O_2\)
4/15 2/15 ( mol )
\(m_{KMnO_4}=n.M=\dfrac{4}{15}.158=\dfrac{632}{15}g\)
nMg = 6,4 : 24= 0,26(mol)
pthh : 2Mg+O2 -t--> 2MgO
0,26 --> 0,13 (mol )
=> VO2(đktc) = 0,13.22,4=2,912(l)
pthh : 2KMnO4-t--> K2MnO4 + MnO2+ O2
0,26<------------------------------0,13(mol)
=> mKMnO4 = 0,26.158= 41,08(g)
nAl=16,2/27= 0,6(mol)
a) PTHH: 4 Al +3 O2 -to-> 2 Al2O3
nO2= 3/4 . nAl=3/4 . 0,6= 0,45(mol)
=> V(O2,đktc)=0,45 x 22,4=10,08(l)
b) nAl2O3= nAl/2=0,6/2=0,3(mol)
=>mAl2O3=102. 0,3= 30,6(g)
c) 2KMnO4 -to-> K2MnO4 + MnO2 + O2
nKMnO4= 2.nO2=2. 0,45=0,9(mol)
=>mKMnO4= 158 x 0,9= 142,2(g)
a, PT: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b, Ta có: \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)
Theo PT: \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=\dfrac{1}{30}\left(mol\right)\Rightarrow m_{Fe_3O_4}=\dfrac{1}{30}.232\approx7,733\left(g\right)\)
c, Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=\dfrac{1}{15}\left(mol\right)\)
PT: \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
\(n_{KMnO_4\left(LT\right)}=2n_{O_2}=\dfrac{2}{15}\left(mol\right)\)
\(\Rightarrow m_{KMnO_4\left(LT\right)}=\dfrac{2}{15}.158=\dfrac{316}{15}\left(g\right)\)
Mà: H% = 85%
\(\Rightarrow m_{KMnO_4\left(TT\right)}=\dfrac{\dfrac{316}{15}}{85\%}\approx24,78\left(g\right)\)
nP = 3,1 : 31 = 0,1 (mol)
pthh : 4P + 5O2 -t--> 2P2O5 (1)
0,1--> 0,125 (mol)
=> VO2 = 0,125 .22,4 = 2,8(l)
pthh : 2KMnO4 -t--> K2MnO4 + MnO2 +O2 (2)
0,25<--------------------------- 0,125(mol)
=> mKMnO4 = 0,25 .158 = 39,5(g)
d ) (1) là Phản ứng hóa hợp
(2) là phản ứng phân hủy
nP = 3,1/31 = 0,1 (mol)
PTHH: 4P + 5O2 -> (t°) 2P2O5 (phản ứng hóa hợp)
Mol: 0,1 ---> 0,125
VO2 = 0,125 . 22,4 = 2,8 (l)
PTHH: 2KMnO4 -> (t°) K2MnO4 + MnO2 + O2 (phản ứng phân hủy)
nKMnO4 = 0,125 . 2 = 0,25 (mol)
mKMnO4 = 0,25 . 158 = 39,5 (g)
a, \(2Zn+O_2\underrightarrow{t^o}2ZnO\)
b, \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
Theo PT: \(n_{O_2}=\dfrac{1}{2}n_{Zn}=0,1\left(mol\right)\Rightarrow V_{O_2}=0,1.22,4=2,24\left(l\right)\)
\(\Rightarrow V_{kk}=5V_{O_2}=11,2\left(l\right)\)
c, \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
Theo PT: \(n_{KMnO_4}=2n_{O_2}=0,2\left(mol\right)\Rightarrow m_{KMnO_4}=0,2.158=31,6\left(g\right)\)
a, PT: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
b, Ta có: \(n_{O_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Theo PT: \(n_{Fe_3O_4}=\dfrac{1}{2}n_{O_2}=0,1\left(mol\right)\)
\(\Rightarrow m_{Fe_3O_4}=0,1.232=23,2\left(g\right)\)
c, PT: \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
Có: O2 hao hụt 40% → H% = 100 - 40 = 60%
Theo PT: \(n_{KMnO_4}=2n_{O_2}=0,4\left(mol\right)\)
\(\Rightarrow n_{KMnO_4\left(TT\right)}=\dfrac{0,4}{60\%}=\dfrac{2}{3}\left(mol\right)\)
\(\Rightarrow m_{KMnO_4}=\dfrac{2}{3}.158\approx105,3\left(g\right)\)
a.b.c.\(n_{Mg}=\dfrac{m_{Mg}}{M_{Mg}}\dfrac{4,8}{24}=0,2mol\)
\(2Mg+O_2\rightarrow\left(t^o\right)2MgO\)
0,2 0,1 0,2 ( mol )
\(V_{O_2}=n_{O_2}.22,4=0,1.22,4=2,24l\)
\(m_{MgO}=n_{MgO}.M_{MgO}=0,2.40=8g\)
d. Sửa đề: tính khối lượng KMnO4
\(2KMnO_4\rightarrow\left(t^o\right)K_2MnO_4+MnO_2+O_2\)
0,2 0,1 ( mol )
\(m_{KMnO_4}=n_{KMnO_4}.M_{KMnO_4}=0,2.158=31,6g\)
Ta có: \(n_S=\dfrac{6,4}{32}=0,2\left(mol\right)\)
PT: \(S+O_2\underrightarrow{t^o}SO_2\)
___0,2___0,2 (mol)
\(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
____0,4________________________0,2 (mol)
\(\Rightarrow m_{KMnO_4}=0,4.158=63,2\left(g\right)\)
\(n_S=\dfrac{6,4}{32}=0,2\left(m\right)\)
\(PTHH:S+O_2\underrightarrow{t^o}SO_2\)
tỉ lệ :1 1 1
số mol :0,2 0,2 0,2
\(PTHH:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)
tỉ lệ :2 1 1 1
số mol :0,4 0,2 0,2 0,2
\(m_{KMnO_4}=0,4.158=63,2\left(g\right)\)