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a) mO2=20,32 gam
b) mO2=23,12 gam
c) mO2=43,04 gam
a)
Cu +1/2O2 -> CuO
2Fe + 3O2 -> Fe2O3
Ba + 1/2O2 -> BaO
-> nO2=1/2nCu +3/2nFe +1/2nBa=0,25.1/2+0,09.3/2+0,75.1/2=0,635 mol -> mO2=0,635.32=20,32 gam
b) nP=7,75/31=0,25 mol; nS=11,2/32=0,35 mol; nC=1,08/12=0,06 mol
4P + 5O2 -> 2P2O5
S + O2 -> SO2
C + O2 -> CO2
-> nO2=5/4nP + nS +nC=0,25.5/4+0,35+0,06=0,7225 mol -> mO2=0,7225.32=23,12 gam
c)
nC2H6=5,6/22,4=0,25 mol
nH2=0,896/22,4=0,04 mol
nC2H4=3,36/22,4=0,15 mol
C2H6 + 3,5O2 -> 2CO2 + 3H2O
2H2 +O2 -> 2H2O
C2H4 + 3O2 -> 2CO2 + 2H2O
-> nO2=3,5nC2H6 +1/2nH2 +3nC2H4=0,25.3,5+0,04.1/2+0,15.3=1,345 gam -> mO2=1,345.32=43,04 gam
Gọi số mol C, S là a, b
=> 12a + 32b = 7,68
PTHH: C + O2 --to--> CO2
_____a--------------->a
S + O2 --to--> SO2
b--------------->b
=> a + b = \(\dfrac{9,856}{22,4}=0,44\)
=> a = 0,32; b = 0,12
=> \(\left\{{}\begin{matrix}\%C=\dfrac{0,32.12}{7,68}.100\%=50\%\\\%S=\dfrac{0,12.32}{7,68}.100\%=50\%\end{matrix}\right.\)
b, \(4P+5O_2\underrightarrow{t^o}2P_2O_5\)
\(n_P=\dfrac{6,2}{31}=0,2mol\\n_{O_2}=\dfrac{0,2.5}{4}=0,25mol \)
\(S+O_2\underrightarrow{t^o}SO_2\)
\(n_S=\dfrac{3,2}{32}=0,1mol\\ n_{O_2}=0,1mol\)
\(C+O_2\underrightarrow{t^o}CO_2\)
\(n_C=\dfrac{2,4}{12}=0,2mol\\ n_{O_2}=0,2mol\\ n_{O_2}\left(tổng\right)=\)
\(0,25+0,1+0,2=0,55mol\\ m_{O_2}\left(trong.hh.B\right)=0,55.32=17,6g\)
a, \(m_{Fe}=0,25.56=14g\)
\(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)
\(\Rightarrow n_{O_2}=\dfrac{0,25.2}{3}=0,16mol\\ m_{O_2}=0,16.32=5,12g\)
\(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)
\(n_{O_2}=\dfrac{0,25.3}{4}=0,1875mol\\ m_{O_2}=0,1875.32=6g\)
\(2Zn+O_2\underrightarrow{t^o}2ZnO\)
\(n_{O_2}=\dfrac{0,5.1}{2}=0,25mol\\ m_{O_2}=0,25.32=8g\)
\(\Rightarrow m_{O_2}\left(trong.hỗn.hợp.A\right)=\) \(5,12+6+8=19,12g\)
\(1,2H_2+O_2\underrightarrow{t}2H_2O\)
\(2Mg+O_2\underrightarrow{t}2MgO\)
\(2Cu+O_2\underrightarrow{t}2CuO\)
\(S+O_2\underrightarrow{t}SO_2\)
\(4Al+3O_2\underrightarrow{t}2Al_2O_3\)
\(C+O_2\underrightarrow{t}CO_2\)
\(4P+5O_2\underrightarrow{t}2P_2O_5\)
\(2,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(a,n_{O_2}=0,2\left(mol\right)\Rightarrow n_{CO_2}=0,2\left(mol\right)\Rightarrow m_{CO_2}=8,8\left(g\right)\)
\(b,n_C=0,3\left(mol\right)\Rightarrow n_{CO_2}=0,3\left(mol\right)\Rightarrow m_{CO_2}=13,2\left(g\right)\)
c, Vì\(\frac{0,3}{1}>\frac{0,2}{1}\)nên C phản ửng dư, O2 phản ứng hết, Bài toán tính theo O2
\(n_{O_2}=0,2\left(mol\right)\Rightarrow n_{CO_2}=0,2\left(mol\right)\Rightarrow m_{CO_2}=8,8\left(g\right)\)
\(3,PTHH:CH_4+2O_2\underrightarrow{t}CO_2+2H_2O\)
\(C_2H_2+\frac{5}{2}O_2\underrightarrow{t}2CO_2+H_2O\)
\(C_2H_6O+3O_2\underrightarrow{t}2CO_2+3H_2O\)
\(4,a,PTHH:4P+5O_2\underrightarrow{t}2P_2O_5\)
\(n_P=1,5\left(mol\right)\Rightarrow n_{O_2}=1,2\left(mol\right)\Rightarrow m_{O_2}=38,4\left(g\right)\)
\(b,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(n_C=2,5\left(mol\right)\Rightarrow n_{O_2}=2,5\left(mol\right)\Rightarrow m_{O_2}=80\left(g\right)\)
\(c,PTHH:4Al+3O_2\underrightarrow{t}2Al_2O_3\)
\(n_{Al}=2,5\left(mol\right)\Rightarrow n_{O_2}=1,875\left(mol\right)\Rightarrow m_{O_2}=60\left(g\right)\)
\(d,PTHH:2H_2+O_2\underrightarrow{t}2H_2O\)
\(TH_1:\left(đktc\right)n_{H_2}=1,5\left(mol\right)\Rightarrow n_{O_2}=0,75\left(mol\right)\Rightarrow m_{O_2}=24\left(g\right)\)
\(TH_2:\left(đkt\right)n_{H_2}=1,4\left(mol\right)\Rightarrow n_{O_2}=0,7\left(mol\right)\Rightarrow m_{O_2}=22,4\left(g\right)\)
\(5,PTHH:S+O_2\underrightarrow{t}SO_2\)
\(n_{O_2}=0,46875\left(mol\right)\)
\(n_{SO_2}=0,3\left(mol\right)\)
Vì\(0,46875>0,3\left(n_{O_2}>n_{SO_2}\right)\)nên S phản ứng hết, bài toán tính theo S.
\(a,\Rightarrow n_S=n_{SO_2}=0,3\left(mol\right)\Rightarrow m_S=9,6\left(g\right)\)
\(n_{O_2}\left(dư\right)=0,16875\left(mol\right)\Rightarrow m_{O_2}\left(dư\right)=5,4\left(g\right)\)
\(6,a,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_C=1,5\left(mol\right)\Rightarrow m_C=18\left(g\right)\)
\(b,PTHH:2H_2+O_2\underrightarrow{t}2H_2O\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_{H_2}=0,75\left(mol\right)\Rightarrow m_{H_2}=1,5\left(g\right)\)
\(c,PTHH:S+O_2\underrightarrow{t}SO_2\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_S=1,5\left(mol\right)\Rightarrow m_S=48\left(g\right)\)
\(d,PTHH:4P+5O_2\underrightarrow{t}2P_2O_5\)
\(n_{O_2}=1,5\left(mol\right)\Rightarrow n_P=1,2\left(mol\right)\Rightarrow m_P=37,2\left(g\right)\)
\(7,n_{O_2}=5\left(mol\right)\Rightarrow V_{O_2}=112\left(l\right)\left(đktc\right)\);\(V_{O_2}=120\left(l\right)\left(đkt\right)\)
\(8,PTHH:C+O_2\underrightarrow{t}CO_2\)
\(m_C=0,96\left(kg\right)\Rightarrow n_C=0,08\left(kmol\right)=80\left(mol\right)\Rightarrow n_{O_2}=80\left(mol\right)\Rightarrow V_{O_2}=1792\left(l\right)\)
\(9,n_p=0,2\left(mol\right);n_{O_2}=0,3\left(mol\right)\)
\(PTHH:4P+5O_2\underrightarrow{t}2P_2O_5\)
Vì\(\frac{0,2}{4}< \frac{0,3}{5}\)nên P hết O2 dư, bài toán tính theo P.
\(a,n_{O_2}\left(dư\right)=0,05\left(mol\right)\Rightarrow m_{O_2}\left(dư\right)=1,6\left(g\right)\)
\(b,n_{P_2O_5}=0,1\left(mol\right)\Rightarrow m_{P_2O_5}=14,2\left(g\right)\)
\(n_{hhkhí}=\dfrac{16,8}{22,4}=0,75\left(mol\right)\)
Gọi \(n_{SO_2}=a\left(mol\right)\left(0< a< 0,75\right)\)
\(\rightarrow n_{O_2\left(dư\right)}=0,75-b\left(mol\right)\)
Ta có: \(\dfrac{64a+32\left(0,75-a\right)}{0,75}=\dfrac{33,6}{1}=33,6\left(\dfrac{g}{mol}\right)\)
\(\rightarrow a=0,0375\left(mol\right)\)
\(\rightarrow\left\{{}\begin{matrix}\%V_{SO_2}=\dfrac{0,0375}{0,75}=5\%\\\%V_{O_2\left(dư\right)}=100\%-5\%=95\%\end{matrix}\right.\)
$n_{CO_2} = \dfrac{8,8}{44} = 0,2(mol)$
\(2CO+O_2\xrightarrow[]{t^o}2CO_2\)
0,2 0,1 0,2 (mol)
$n_{O_2} = \dfrac{9,6}{32} = 0,3(mol)$
\(2H_2+O_2\xrightarrow[]{t^o}2H_2O\)
0,4 0,2 0,2 (mol)
\(\%m_{CO}=\dfrac{0,2.44}{0,2.44+0,4.2}.100\%=91,67\%\\ \%m_{H_2}=100\%-91,67\%=8,33\%\)
\(\%n_{CO}=\dfrac{0,2}{0,2+0,4}.100\%=33,33\%\\ \%n_{H_2}=100\%-33,33\%=66,67\%\)
a)
Cu +1/2O2 \(\rightarrow\)CuO
2Fe + 3O2\(\rightarrow\)Fe2O3
Ba + \(\frac{1}{2}\)O2 \(\rightarrow\) BaO
\(\rightarrow\)nO2=\(\frac{1}{2}\)nCu +\(\frac{3}{2}\)nFe +\(\frac{1}{2}\)nBa
=0,25.\(\frac{1}{2}\)+0,09.\(\frac{3}{2}\)+0,75.\(\frac{1}{2}\)=0,635 mol
\(\rightarrow\)mO2=0,635.32=20,32 gam
b) nP=\(\frac{7,75}{31}\)=0,25 mol; nS=\(\frac{11,2}{32}\)=0,35 mol; nC=\(\frac{1,08}{12}\)=0,06 mol
4P + 5O2 \(\rightarrow\)2P2O5
S + O2 \(\rightarrow\) SO2
C + O2 \(\rightarrow\) CO2
\(\rightarrow\) nO2=\(\frac{5}{4}\)nP + nS +nC=0,25.\(\frac{5}{4}\)+0,35+0,06=0,7225 mol
\(\rightarrow\) mO2=0,7225.32=23,12 gam
c)
nC2H6=\(\frac{22,4}{56}\)=0,25 mol
nH2=\(\frac{0,896}{22,4}\)=0,04 mol
nC2H4=\(\frac{3,36}{22,4}\)=0,15 mol
C2H6 + 3,5O2 \(\rightarrow\)2CO2 + 3H2O
2H2 +O2\(\rightarrow\) 2H2O
C2H4 + 3O2\(\rightarrow\) 2CO2 + 2H2O
\(\rightarrow\) nO2=3,5nC2H6 +\(\frac{1}{2}\)nH2 +3nC2H4
=0,25.3,5+0,04.\(\frac{1}{2}\)+0,15.3=1,345 gam
\(\rightarrow\)mO2=1,345.32=43,04 gam
sai r